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Lithium dihydrogen phosphate

CAS No.
13453-80-0
Chemical Name:
Lithium dihydrogen phosphate
Synonyms
monolithiumphosphate;LITHIUM DIHYDROGEN P;lithiumdihydrophosphate;lithiumphosphate(lih2po4);Lithium hydrogen phosphate;LITHIUM PHOSPHATE MONOBASIC;LITHIUM DIHYDROGEN PHOSPHATE;LithiuM Dihydroxide Phosphate;Lithiumdihydrogenphosphate,97%;lithiumdihydrogenorthophosphate
CBNumber:
CB9150683
Molecular Formula:
H4LiO4P
Molecular Weight:
105.94
MDL Number:
MFCD00016188
MOL File:
13453-80-0.mol
MSDS File:
SDS
Last updated:2024-03-26 13:32:57

Lithium dihydrogen phosphate Properties

Melting point >100°C
Density 2.5 g/mL at 25 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
Specific Gravity 2.461
color white
Water Solubility Slightly soluble in water.
Stability Stable. Incompatible with strong oxidizing agents.
InChI InChI=1S/Li.H3O4P.H/c;1-5(2,3)4;/h;(H3,1,2,3,4);
InChIKey AZOORWHXDYIBGH-UHFFFAOYSA-N
SMILES P(O)(O)(O)=O.[LiH]
CAS DataBase Reference 13453-80-0(CAS DataBase Reference)
EPA Substance Registry System Phosphoric acid, monolithium salt (13453-80-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P264-P270-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  TC6593950
TSCA  Yes
HS Code  28352990
Toxicity mouse,LD50,oral,910mg/kg (910mg/kg),"Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 28, 1978.
NFPA 704
1
1 2

Lithium dihydrogen phosphate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 563161 Lithium phosphate monobasic ≥99.99% 13453-80-0 25g $107 2024-03-01 Buy
Sigma-Aldrich 442682 Lithium phosphate monobasic 99% 13453-80-0 500g $148 2024-03-01 Buy
Alfa Aesar A16987 Lithium dihydrogen phosphate, 97% 13453-80-0 250g $91.7 2024-03-01 Buy
Strem Chemicals 93-0383 Lithium dihydrogen phosphate, 97% 13453-80-0 100g $69 2024-03-01 Buy
Strem Chemicals 93-0383 Lithium dihydrogen phosphate, 97% 13453-80-0 500g $274 2024-03-01 Buy
Product number Packaging Price Buy
563161 25g $107 Buy
442682 500g $148 Buy
A16987 250g $91.7 Buy
93-0383 100g $69 Buy
93-0383 500g $274 Buy

Lithium dihydrogen phosphate Chemical Properties,Uses,Production

Description

Lithium dihydrogen phosphate, also known as LDP, is a White crystalline powder with the formula LiH2PO4. It is soluble in water. LiH2PO4 is usually prepared by a stoichiometric reaction of Li2СO3 and 85% orthophosphoric acid[1]. It is often used as a raw material for the preparation of cathode materials for lithium batteries or as phosphate in chemical reactions.

Chemical Properties

White crystalline powder

Uses

Precursor for LiMX2O7 (M = Fe, V; x =P, As) cathode materials.1

Uses

Lithium Dihydrogen Phosphate is used in preparation method of lithium hydroxide from lithium-containing low-magnesium brine in lithium phosphate manner.

General Description

This product has been enhanced for energy efficiency.

Solubility in water

At 0°C, the solubility of lithium dihydrogen phosphate in water is about 55.8wt % (126.2 g of LiH2PO4 /100 g of water)[1]. At 22°C, the solubility of lithium dihydrogen phosphate corresponds to ~ 153.8 g of LiH2PO4/100 g of water. At 25°C, it doesn't dissolve in water[2].

References

[1] A.P. Voronov, G.N. Babenko, V.M. Puzikov, A.N. Iurchenko, Growth of LiH2PO4 single crystals from phosphate solutions, Journal of Crystal Growth, 2013, 374, 49–52. [2] R. W. Berg, A. V. Nikiforov, N. J. Bjerrum, Vapor pressure and specific electrical conductivity in the H2O–LiH2PO4–LiPO3 system—a novel electrolyte for water electrolysis at elevated temperature.Ionics, 2021, 27, 703–719.

Lithium dihydrogen phosphate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 215)Suppliers
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Shanghai Huaran Industrial Co.,Ltd
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Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9320 58

View Lastest Price from Lithium dihydrogen phosphate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Lithium dihydrogen phosphate pictures 2023-09-23 Lithium dihydrogen phosphate
13453-80-0
US $20.00-2.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
Lithium dihydrogen phosphate pictures 2023-09-06 Lithium dihydrogen phosphate
13453-80-0
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Lithium dihydrogen phosphate pictures 2020-01-03 Lithium dihydrogen phosphate
13453-80-0
US $7.00 / KG 1KG 99% 100kg Career Henan Chemical Co
LithiuM Dihydroxide Phosphate Lithium phosphate monobasic >=99.99% Lithium phosphate monobasic 99% Lithium dihydrogenphosphate Phosphoric acid monolithium salt lithiumdihydrogenorthophosphate lithiumdihydrophosphate lithiumphosphate(lih2po4) monolithiumphosphate LITHIUM PHOSPHATE MONOBASIC LITHIUM DIHYDROGEN PHOSPHATE PHOSPHORIC ACID MONOLITHIUM SALT LITHIUM DIHYDROGENPHOSPHATE 99.99+% Lithiumdihydrogenphosphate,97% Lithium dihydrogen phosphate, Phosphoric acid mono Phosphoric acid dihydrogen lithium salt LITHIUM DIHYDROGEN P Lithium dihydrogen phosphate anhydrous Phosphoric acid,lithium salt (1:1) LITHIUM PHOSPHATE, MONOBASICLITHIUM PHOSPHATE, MONOBASICLITHIUM PHOSPHATE, MONOBASICLITHIUM PHOSPHATE, MONOBASIC Lithium dihydrogen phosphate ISO 9001:2015 REACH Lithium hydrogen phosphate Lithium dihydrogen phosphate, 99.9% metal basis 13453-80-0 13483-80-0 LiH2PO4 H2LiO4P LiH2O4P Synthetic Reagents Lithium Inorganic Salts Inorganic Salts Lithium Lithium-Ion Batteries Materials Science Synthetic Reagents Alternative Energy Battery Electrolyte Materials Chemical Synthesis Electrolyte Materials Electrolytes metal phosphate compound