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Guanidine nitrate

Guanidine Salt Physical and Chemical Properties Category Toxicological Information Applications Synthesis Handling and Storage Flammability Hazard Fire Fighting Measures Explosives hazard
Guanidine nitrate
Guanidine nitrate structure
CAS No.
506-93-4
Chemical Name:
Guanidine nitrate
Synonyms
GUN;Guanidinnitrat;Uraminenitrate;GUANIDINENITRATE;Iminoureamitrate;GUANIDINE NITRATE;Carbamidinenitrate;GUANIDINIUM NITRATE;GuanidineNitratePure;Guanidine nitrate,98%
CBNumber:
CB9150870
Molecular Formula:
CH6N4O3
Formula Weight:
122.08
MOL File:
506-93-4.mol

Guanidine nitrate Properties

Melting point:
213-215 °C(lit.)
Boiling point:
227.45°C (rough estimate)
Density 
1.44
refractive index 
1.4164 (estimate)
storage temp. 
Store below +30°C.
solubility 
water: soluble50mg/mL, clear to very slightly hazy, colorless
PH
4.9 (165g/l, H2O, 25℃)
Water Solubility 
130 g/L (20 ºC)
Merck 
14,4562
BRN 
3596600
Stability:
May explode if heated. May be shock sensitive.
CAS DataBase Reference
506-93-4(CAS DataBase Reference)
EPA Substance Registry System
Guanidine, mononitrate(506-93-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  O,Xn,Xi
Risk Statements  8-22-36/37/38-5
Safety Statements  17-26-36-15
RIDADR  UN 1467 5.1/PG 3
WGK Germany  1
RTECS  MF4350000
TSCA  Yes
HazardClass  5.1
PackingGroup  III
HS Code  29252000
Hazardous Substances Data 506-93-4(Hazardous Substances Data)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
P210, P220, P221P280, P370+P378,P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard Category 3
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P220 Keep/Store away from clothing/…/combustible materials.
P221 Take any precaution to avoid mixing with combustibles/…
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Guanidine nitrate price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 234249 Guanidine nitrate 98% 506-93-4 100g $22.4 2018-11-13 Buy
Sigma-Aldrich 234249 Guanidine nitrate 98% 506-93-4 1kg $80.4 2018-11-13 Buy
Alfa Aesar L09643 Guanidine nitrate, 98% 506-93-4 250g $24.8 2018-11-13 Buy
Alfa Aesar L09643 Guanidine nitrate, 98% 506-93-4 1000g $73.4 2018-11-13 Buy

Guanidine nitrate Chemical Properties,Uses,Production

Guanidine Salt

Nitrate guanidine, guanidine hydrochloride, guanidine carbonate and guanidine phosphate are four common kinds of guanidine salts, can be used to produce sulfamidine, sulfadiazine sulfonamides and nitroguanidine, guanidine carbonate, and also used for photography materials and disinfectants. Industrial preparation of guanidine nitrate is through the reaction of dicyandiamide and ammonium nitrate.
Guanidine nitrate, also known as guanidine mononitrate, is colorless leave-like crystal when crystallized from water. It has moderate toxicity, Its molecular formula is H2NC (NH) NH2HNO3. It is white granules soluble in water and ethanol, slightly soluble in acetone. It has explosion decomposition at high temperatures. Its melting point is between 214 and 216 ° C. When it is rammed or exposed to high heat or fire, there is a risk of combustion explosion. And when mixed with sulfur, phosphorus and other reducing agents, it brings the danger of the formation of explosive mixtures. The mixtures of guanidine nitrate with nitro compounds, chlorates or strong acids are sensitive to vibration and friction and likely to cause explosion. It should be stored in shady and cool places and free from high temperature. Guanidine nitrate should be isolated from flammables, organic compounds, nitro compounds, chlorates or acids. The loading and unloading of guanidine nitrate should be carried out carefully and lightly with reinforcement pad to prevent knock and friction. And spilled guanidine nitrate should be immediately cleaned. Its fire extinguisher can be sand, foam, carbon dioxide and mist water.
Its United Nations No. (UN No.): 1467/5041-1,5.1 class, classified as oxidant.
Molecular structure of guanidine nitrate
Image 1: Molecular structure of guanidine nitrate

Physical and Chemical Properties

White crystalline powder or granules. Soluble in water and alcohol but  insoluble in acetone, benzene and ether.

Category

Oxidant

Toxicological Information

Toxicity Grading: moderate toxicity (WHO Class II)
Acute Toxicity:Oral-Rat LD50: 730 mg/kg; Oral-mouse LD50: 1028 mg/kg
Stimulation : Skin-Rabbit 500 mg ,Severe; Eyes-Rabbit 92 mg, Mild

Applications

Guanidine nitrate is not only used as the raw materials of imidacloprid (a pesticide) to prepare the next intermediate, nitroguanidine, it can also be used as the intermediates of a variety of sulfonylurea herbicides, such as bensulfuron-methyl, pyrazosulfuron-ethyl, chlorimuron-ethyl, etc. In addition, it is also used for the synthesis of sulfonamides medicine, explosives, photographic materials and disinfectants.In addition, it is also used to test guanidine salt in the complex acid.

Synthesis

The reaction of dicyandiamide and ammonium nitrate:
The condensation reaction dicyandiamide and ammonium nitrate in the ratio of 1: 2 is carried out at 120~210 ° C. The reaction product is crystallized, sliced to obtain finished product.
It also can be prepared by the reaction between calcium cyanamide and nitric acid.

Handling and Storage

It should be stored in low-temperature ventilated depot.
The loading and unloading of guanidine nitrate should be carried out carefully and lightly.
Always keep guanidine nitrate from organic materials, reducing agents, sulfur, phosphorus and flammables

Flammability Hazard

It is flammable at high temperature, and its combustion produces toxic nitrogen oxide fumes.

Fire Fighting Measures

Extinguishing Media:
Sand, carbon dioxide and mist water.

Explosives hazard

Explosive when rammed or exposed to high heat or fire.
Explosive when mixed with sulfur, phosphorus and other reducing agents.

Chemical Properties

solid

Uses

Guanidine nitrate is the salt formed from guanidine and nitric acid and has been used as a high energy fuel used in gas generators and propellant applications.

Hazard

Strong oxidant, may ignite organic materials on contact, may explode by shock or heat.

Guanidine nitrate Preparation Products And Raw materials

Raw materials

Preparation Products


Guanidine nitrate Suppliers

Global( 172)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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Mainchem Co., Ltd.
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Chemwill Asia Co.,Ltd.
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
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Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30168 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24560 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 qq:2355568890
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Energy Chemical 021-58432009 / 400-005-6266
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Guanidine nitrate Spectrum


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