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Methyltris(methylisobutylketoxime)silane

CAS No.
37859-57-7
Chemical Name:
Methyltris(methylisobutylketoxime)silane
Synonyms
Vinyl tris(methylisobutylketoximino) silane;METHYL TRIS (METHYL ISOBUTYL KETOXIME) SILANE;Methyl tris-(methyl isobutyl ketoximino) silane;methyltris(methylsobutyldetoximo)silane,tech-95;METHYLTRIS(METHYLISOBUTYLKETOXIMINO)SILANE, tech-95;2-Pentanone, 4-methyl-, 2,2',2''-[O,O',O''-(methylsilylidyne)trioxime];Methyl tris (MIBKO) silane. Methyl tris-(methyl isobutyl ketoximino) silane;(2E,2'E,2''E)-O,O',O''-(methylsilanetriyl)tris(4-methyl-4-methylpentan-2-one oxime)
CBNumber:
CB9158876
Molecular Formula:
C19H39N3O3Si
Molecular Weight:
385.62
MDL Number:
MFCD28901352
MOL File:
37859-57-7.mol
MSDS File:
SDS
Last updated:2023-05-04 15:12:44

Methyltris(methylisobutylketoxime)silane Properties

Boiling point 403.3±28.0 °C(Predicted)
Density 0.92-0.94
refractive index 1.4513
Specific Gravity 0.93
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
EPA Substance Registry System 2-Pentanone, 4-methyl-, 2,2',2''-[O,O',O''-(methylsilylidyne)trioxime] (37859-57-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS08
Signal word  Warning
Hazard statements  H373-H413
Precautionary statements  P260-P314-P501

Methyltris(methylisobutylketoxime)silane Chemical Properties,Uses,Production

Background

There has been a long felt need in the industry for tetrafunctional oximino silanes which do not require organic solvents or mixing with trifunctional oximino silanes. We have surprisingly discovered that the novel tetrakis oximino silane, e.g. tetrakis-(methyl isobutyl ketoximino) silane is liquid and thus do not suffer with the same problems as their solid counterparts. These new silanes offer the ability to employ solvent-free formulations, if not significantly decrease solvent content in the composition. In addition, there is added flexibility and simplification when formulating room temperature moisture-curable silicone compositions. Because the new silanes are liquid tetrafunctional oximino silanes, one can add more of these silanes to increase the cure rate of the composition. The amount of other tetrafunctional oximino silanes which can be used in this type of silicone composition is limited by their solubility in the solvent.
In addition to the novel liquid tetrafunctional oximino silanes, we have also found that when these novel oximino silanes (tetra-oximino, tris-oximino or bis-oximino) are formulated with hydroxyl terminated polydimethylsiloxane (HTPDMS), an optically clear silicone rubber results.

Background

There has been a long felt need in the industry for tetrafunctional oximino silanes which do not require organic solvents or mixing with trifunctional oximino silanes. As the novel tetrakis oximino silane, e.g. tetrakis-(methyl isobutyl ketoximino) silane is liquid and thus do not suffer with the same problems as their solid counterparts. These new silanes offer the ability to employ solvent-free formulations, if not significantly decrease solvent content in the composition. In addition, there is added flexibility and simplification when formulating room temperature moisture-curable silicone compositions. Because the new silanes are liquid tetrafunctional oximino silanes, one can add more of these silanes to increase the cure rate of the composition. The amount of other tetrafunctional oximino silanes which can be used in this type of silicone composition is limited by their solubility in the solvent.
In addition to the novel liquid tetrafunctional oximino silanes, it is found that when these novel oximino silanes (tetra-oximino, tris-oximino or bis-oximino) are formulated with hydroxyl terminated polydimethylsiloxane (HTPDMS), an optically clear silicone rubber results.

Uses

Methyltris(methylisobutylketoxime)silane is used as a novel neutal curing agent in silicone sealant formulations.

Chemical Properties

Colorless or yellowish transparent liquid

Methyltris(methylisobutylketoxime)silane Preparation Products And Raw materials

Raw materials

Preparation Products

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methyltris(methylsobutyldetoximo)silane,tech-95 METHYLTRIS(METHYLISOBUTYLKETOXIMINO)SILANE, tech-95 METHYL TRIS (METHYL ISOBUTYL KETOXIME) SILANE Methyl tris-(methyl isobutyl ketoximino) silane Methyl tris (MIBKO) silane. Methyl tris-(methyl isobutyl ketoximino) silane 2-Pentanone, 4-methyl-, 2,2',2''-[O,O',O''-(methylsilylidyne)trioxime] Vinyl tris(methylisobutylketoximino) silane (2E,2'E,2''E)-O,O',O''-(methylsilanetriyl)tris(4-methyl-4-methylpentan-2-one oxime) 37859-57-7 C19H39N3O3Si Crosslinkers Crosslinking Agents Oximino Silanes