Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
- CAS No.
- 16090-14-5
- Chemical Name:
- Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
- Synonyms
- PSVE;PERFLUORO(4-METHYL-3,6-DIOXAOCT-7-ENE)SULPHONYL FLUORIDE;FS 141;Perfluoro(sulfonylvinyl)ether;Perfluoro(4-methyl-3,6-dioxaoc;2,2-tetrafluoro-etrafluoroethoxy]-1;PERFLUORO-2-(2-FLUOROSULPHONYLETHOXY)PROPYLVINYLETHER;PERFLUORO-2-(2-FLUOROSULFONYLETHOXY)PROPYL VINYL ETHER;PERFLUORO(4-METHYL-3,6-DIOXAOCT-7-ENE)SULFONYL FLUORIDE;Perfluoro-3,6-dioxa-4-methyloct-7-enesulphonyl fluoride
- CBNumber:
- CB9191460
- Molecular Formula:
- C7F14O4S
- Molecular Weight:
- 446.12
- MDL Number:
- MFCD00798138
- MOL File:
- 16090-14-5.mol
- MSDS File:
- SDS
Boiling point | 135°C |
---|---|
Density | 1,7 g/cm3 |
storage temp. | Refrigerator, under inert atmosphere |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Oil |
color | Colourless |
FDA UNII | M51955B972 |
EPA Substance Registry System | Ethanesulfonyl fluoride, 2-[1-[difluoro[(trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoro- (16090-14-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H315-H319-H335 |
Precautionary statements | P280-P261-P271 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36/37/39 |
RIDADR | 2810 |
Hazard Note | Irritant |
TSCA | T |
HazardClass | TOXIC |
HS Code | 2930909899 |
Toxicity | LD50 skin in rabbit: > 17gm/kg |
Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride price More Price(14)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | P286545 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonylFluoride | 16090-14-5 | 1g | $80 | 2021-12-16 | Buy |
SynQuest Laboratories | 6362-2-01 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride 97% | 16090-14-5 | 5G | $105 | 2021-12-16 | Buy |
Matrix Scientific | 001082 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)-sulfonyl fluoride 95% | 16090-14-5 | 5g | $140 | 2021-12-16 | Buy |
Apolloscientific | PC7831 | Perfluoro-3,6-dioxa-4-methyloct-7-enesulphonylfluoride | 16090-14-5 | 5g | $205 | 2021-12-16 | Buy |
SynQuest Laboratories | 6362-2-01 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride 97% | 16090-14-5 | 25g | $425 | 2021-12-16 | Buy |
Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride Chemical Properties,Uses,Production
Uses
Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl Fluoride is used as a reagent in the synthesis of novel perfluorinated vinyl ether containing sulfonimide functionality which can be copolymered with tetrafluoroethylene to yield a novel perfluorinated copolymer.
Uses
Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.
Synthesis
(1) Intermediate synthesis In a 1L reactor, add 100ml of dimethylacetamide, 8g of potassium fluoride, and 200g (1.11mol) of tetrafluoroethane-|?-sultone,Subsequently, 500g (3mol) of hexafluoropropylene oxide was introduced at a flow rate of 0.3kg/h for addition reaction, and the reaction temperature was controlled at 20??C.The reaction pressure is controlled at 0.4MPa. After the introduction of hexafluoropropylene oxide is completed, the reaction is continued for 1 hour. After the reaction is completed,The reaction liquid was rectified to obtain 528g (1.03mol) of intermediate, with a yield of 92% and a purity of 99.1%;(2) PSVE synthesis In a moving bed reactor (volume 2L, material 316L, produced by Tianjin Qixi Technology Co., Ltd.),A mixture of 500g (0.97mol) of the intermediate obtained in step (1) and 600g of potassium carbonate (4.34mol) was passed through the salt formation zone and decarboxylation zone of the moving bed reactor in turn (the salt formation temperature was set to 150??C,The decarboxylation temperature is set to 360??C) to carry out the salt formation reaction and the decarboxylation reaction, and the contact time of the salt formation reaction is 10 min by controlling the material feed rate.The contact time of the decarboxylation reaction is 25min, and the decarboxylation reaction product is collected by condensation to obtain a crude product.The crude product is rectified to obtain the product perfluoro-3,6-dioxa-4-methyl-7-octenesulfonyl fluoride with a purity of 98.5% and a yield of 85%.
Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 6645 | 58 |
Henan Fengda Chemical Co., Ltd | +8613613820652 | info@fdachem.com | China | 5505 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 14936 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21700 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9354 | 55 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
Related articles
- Application of Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride in electrolyte membrane material
- Perfluoro(8-cyano-5-methyl-3,6-dioxaoct-1-ene), 2,2,3,3,4,4,5,5,6,6-decafluoro-6-[(1,2,2-trifluoroethenyl)oxy] hexanenitrile M....
- Feb 26,2020
View Lastest Price from Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-02-23 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
16090-14-5
|
US $44.00-207.00 / g | 5g | 0.99 | 25kg | Shanghai UCHEM Inc. | ||
2024-01-14 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
16090-14-5
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2022-10-09 | Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
16090-14-5
|
US $0.00-0.00 / KG | 1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
- Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
16090-14-5
- US $44.00-207.00 / g
- 0.99
- Shanghai UCHEM Inc.
- Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
16090-14-5
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- Perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride
16090-14-5
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.