Tert-Butyl 4-Vinylphenyl Carbonate
- CAS No.
- 87188-51-0
- Chemical Name:
- Tert-Butyl 4-Vinylphenyl Carbonate
- Synonyms
- tbsm;c-1566;4-boc-styrene;p-tert-Butoxycarbonyloxystyrene;4-(tert-Butoxycarbonyloxy)styrene;TERT-BUTYL 4-VINYLPHENYL CARBONATE;tert-Butyl p-vinylphenyl carbonate;p-tert-butoxycarbonyloxystyrenemonomer;TERT-BUTYL 4-VINYLPHENYL CARBONATE 98%;1,1-dimethylethyl4-ethenylphenylcarbonate
- CBNumber:
- CB9223114
- Molecular Formula:
- C13H16O3
- Molecular Weight:
- 220.26
- MDL Number:
- MFCD00145182
- MOL File:
- 87188-51-0.mol
| Melting point | 27-29 °C(lit.) |
|---|---|
| Boiling point | 187 °C(lit.) |
| Density | 1.1101 (rough estimate) |
| refractive index | 1.5090 (estimate) |
| Flash point | >230 °F |
| InChI | InChI=1S/C13H16O3/c1-5-10-6-8-11(9-7-10)15-12(14)16-13(2,3)4/h5-9H,1H2,2-4H3 |
| InChIKey | GJWMYLFHBXEWNZ-UHFFFAOYSA-N |
| SMILES | C(OC1=CC=C(C=C)C=C1)(=O)OC(C)(C)C |
| EPA Substance Registry System | Carbonic acid, 1,1-dimethylethyl 4-ethenylphenyl ester (87188-51-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 |
| WGK Germany | 2 |
| RTECS | FG0460000 |
Tert-Butyl 4-Vinylphenyl Carbonate Chemical Properties,Uses,Production
Uses
Used as an intermediate in organic synthesis.
Application
Tert-Butyl 4-Vinylphenyl Carbonate (tBVPC) could be used to synthesize a terpolymer, which is a novel chemically amplified positive photoresist with methyl methacrylate (MMA)triphenylsulfonium salt methacrylate (TPSMA). In addition, Lithographic performance of a PAG-bound polymer resist based on tert-butyl 4-vinyl phenyl carbonate, n-[p-(t-butyloxycarbonyloxy) phenyl]maleimide terpolymers as a novel chemically amplified resist exhibited a positive working behavior. They showed 0.18 μm line pattern at electron beam lithography to indicate that the polymer bounded PAG resists have a potential to fabricate nanostructures[1].
Hazard
Moderately toxic by skin contact. A mild skin irritant.
Synthesis
Tert-Butyl 4-Vinylphenyl Carbonate was prepared by reacting 4-Hydroxystyrene with Di-tert-butyl dicarbonate in prestence of Tetramethylammonium hydroxide in water.
References
[1] Jae Beom Yoo . “Triphenylsulfonium salt methacrylate bound polymer resist for electron beam lithography.” Polymer 55 16 (2014): Pages 3599-3604.
Tert-Butyl 4-Vinylphenyl Carbonate Preparation Products And Raw materials
Raw materials
Preparation Products
Tert-Butyl 4-Vinylphenyl Carbonate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan Huahan Dingcheng New Material Technology Co., Ltd | +undefined-027-81388558 +undefined086-1878077615 | huahandingcheng@sina.com | China | 342 | 58 |
| Shanghai Z&T Chemical Co., Ltd | +86-21-33561011 13818804961 | Sales@ztchemical.com.cn | China | 402 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15371 | 58 |
| BOC Sciences | +1-631-485-4226 | inquiry@bocsci.com | United States | 19553 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12439 | 58 |
| Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
| Yurui (Shanghai) Chemical Co., Ltd. | +86-021-50456736 +8615000292053 | sales209@riyngroup.com | China | 942 | 58 |
| Shanghai Qyubiotech Co., Ltd. | +86-086-021-37596619 +8618019359838 | info@qyubiotech.com | China | 299 | 58 |
| SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 | sales@senfeida.com | China | 5100 | 58 |
| Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; | sales@catsyn.com | China | 6116 | 58 |
View Lastest Price from Tert-Butyl 4-Vinylphenyl Carbonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-18 | p-(tert-Butoxycarbonyloxy)styrene
87188-51-0
|
US $0.00-0.00 / g | 10g | 97%+ | 100000kgs per Month | Shanghai Qyubiotech Co., Ltd. | |
 |
2023-01-06 | Tert-Butyl 4-Vinylphenyl Carbonate
87188-51-0
|
US $1.00 / KG | 1KG | 98% | 500KG | Wuhan Huahan Dingcheng New Material Technology Co., Ltd | |
 |
2022-12-08 | TERT-BUTYL 4-VINYLPHENYL CARBONATE
87188-51-0
|
US $1.00 / KG | 1KG | 98% | 500KG | Wuhan Huahan Dingcheng New Material Technology Co., Ltd |
-
- p-(tert-Butoxycarbonyloxy)styrene
87188-51-0
- US $0.00-0.00 / g
- 97%+
- Shanghai Qyubiotech Co., Ltd.
-
- Tert-Butyl 4-Vinylphenyl Carbonate
87188-51-0
- US $1.00 / KG
- 98%
- Wuhan Huahan Dingcheng New Material Technology Co., Ltd
-
- TERT-BUTYL 4-VINYLPHENYL CARBONATE
87188-51-0
- US $1.00 / KG
- 98%
- Wuhan Huahan Dingcheng New Material Technology Co., Ltd