ChemicalBook >> CAS DataBase List >>2,5-Thiophenedicarboxylic acid

2,5-Thiophenedicarboxylic acid

CAS No.
4282-31-9
Chemical Name:
2,5-Thiophenedicarboxylic acid
Synonyms
THIOPHENE-2,5-DICARBOXYLIC ACID;TH-2COOH;RARECHEM AL BE 0623;2,5-Thiophenedicarbo;OTAVA-BB BB7013911425;2,5-DICARBOXYTHIOPHENE;2,5-THIOPHENEDICARBOXYLIC;thiophene-2,5-dicarboxylate;Thiophene-2,5-Dicarboxyl Acid;2,5-THIOPHENEDICARBOXYLIC ACID
CBNumber:
CB9224515
Molecular Formula:
C6H4O4S
Molecular Weight:
172.16
MDL Number:
MFCD00016896
MOL File:
4282-31-9.mol
MSDS File:
SDS
Last updated:2023-09-14 18:57:21

2,5-Thiophenedicarboxylic acid Properties

Melting point >300 °C (lit.)
Boiling point 272.46°C (rough estimate)
Density 1.473 (estimate)
refractive index 1.5500 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form solid
pka 2.76±0.10(Predicted)
color White to Light yellow
Water Solubility Very soluble in water.
BRN 136781
CAS DataBase Reference 4282-31-9(CAS DataBase Reference)
FDA UNII 5Q8A2G9Y8A
EPA Substance Registry System 2,5-Thiophenedicarboxylic acid (4282-31-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
TSCA  Yes
HazardClass  IRRITANT
HS Code  29349990
NFPA 704
0
2 0

2,5-Thiophenedicarboxylic acid price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 405191 2,5-Thiophenedicarboxylic acid 99% 4282-31-9 5g $26 2024-03-01 Buy
Sigma-Aldrich 405191 2,5-Thiophenedicarboxylic acid 99% 4282-31-9 25g $36.4 2024-03-01 Buy
TCI Chemical T2347 2,5-Thiophenedicarboxylic Acid >98.0%(GC)(T) 4282-31-9 5g $46 2024-03-01 Buy
TCI Chemical T2347 2,5-Thiophenedicarboxylic Acid >98.0%(GC)(T) 4282-31-9 25g $139 2024-03-01 Buy
Alfa Aesar L10293 Thiophene-2,5-dicarboxylic acid 97% 4282-31-9 1g $21.65 2024-03-01 Buy
Product number Packaging Price Buy
405191 5g $26 Buy
405191 25g $36.4 Buy
T2347 5g $46 Buy
T2347 25g $139 Buy
L10293 1g $21.65 Buy

2,5-Thiophenedicarboxylic acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powder

Uses

2,5-Thiophenedicarboxylic acid may be used as a thiophene based linker in the preparation of magnesium coordination networks. It may also be used as a precursor in the synthesis of 2,5-bis-benzoxazoyl-thiophene (EBF).
It may be used in the synthesis of the following:

  • new cobalt(II) thiophenedicarboxylate coordination polymer
  • novel mesogenic thiophene based supramolecular liquid crystals
  • two novel coordination polymers with the formula {[Ln2(2,5-tdc)3(dmso)2]H2O}n (Ln = Tb(III) and Dy(III)), (2,5-tdc2 = 2,5-thiophenedicarboxylate and dmso = dimethylsulfoxide)

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 2109, 1950 DOI: 10.1021/ja01161a065

General Description

2,5-Thiophenedicarboxylic acid (2,5-TDCA, H2TDC) is an important building block in the preparation of fluorescent brightening agent, fungicides and anti-cancer drug. It has been generated by chlorination of adipic acid using thionyl chloride. Due to its diverse coordination modes, it is an excellent choice as an aromatic linker to generate coordination networks. The enthalpies of combustion and sublimation of 2,5-thiophenedicarboxylic acid have been evaluated by rotary-bomb combustion calorimetry.

124-04-9
4282-31-9
Synthesis of 2,5-Thiophenedicarboxylic acid from Adipic acid
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View Lastest Price from 2,5-Thiophenedicarboxylic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,5-Thiophenedicarboxylic acid pictures 2023-09-14 2,5-Thiophenedicarboxylic acid
4282-31-9
US $0.00 / kg 1kg 99% 20tons Hebei Yanxi Chemical Co., Ltd.
2, 5-Thiophenedicarboxylic Acid pictures 2023-09-12 2, 5-Thiophenedicarboxylic Acid
4282-31-9
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
2,5-Thiophenedicarboxylic acid pictures 2022-10-20 2,5-Thiophenedicarboxylic acid
4282-31-9
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
2,5-Thiophenedicarbo Thiophene -2,5- twocarboxylic acid 2,5-Thiophenedicarboxylic Acid, 97+% 2,5-Thiophenedicarboxylic acid 99% 2,5-Thiophenedicarboxylic acid,96% 2,5-DICARBOXYTHIOPHENE 2,5-THIOPHENEDICARBOXYLIC ACID RARECHEM AL BE 0623 OTAVA-BB BB7013911425 Thiophene-2,5-Dicarboxyl Acid Thiophene-2,5-dicarboxylicacid,97% 2,5-THIOPHENEDICARBOXYLIC Thiophene-,'-dicarboxylic acid TH-2COOH 2,5-Thiophenedicarboxylic Acid,>98% 2,5-Thiophenedicarboxylic acid ISO 9001:2015 REACH THIOPHENE-2,5-DICARBOXYLIC ACID thiophene-2,5-dicarboxylate 4282-31-9 CH4O4S C6H4O4S C4H2SCOOH2 C6H2O4S Building Blocks Thiophenes Heterocyclic Building Blocks Functional Materials Reagents for Conducting Polymer Research Thiophene Derivatives (for Conduting Polymer Research) Thiophen Building Blocks Heterocyclic Building Blocks Heterocyclic Compounds Thiophens FINE Chemical & INTERMEDIATES Thiophenes Heterocycles Thiophene&Benzothiophene Organic acids