(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole)

CAS No.
56197-32-1
Chemical Name:
(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole)
Synonyms
Gardmultine;(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole);Dispiro[13,8b,10-ethanylylidene-11H-pyrido[2',3':5,6]oxepino[2,3-b]oxazolo[3,2-a]indole-2(3H),9'-[3,7]methanoindolizine-1'(5'H),3''-[3H]indol]-2''(1''H)-one, 6'-ethylidene-2',3',6',7',8',8'a,9,9a,12,13,13a,14-dodecahydro-4'',5,6'',7,7'',8-hexamethoxy-12-(2-methoxyethylidene)-, stereoisomer (9CI)
CBNumber:
CB92298680
Molecular Formula:
C45H54N4O10
Molecular Weight:
810.95
MDL Number:
MOL File:
56197-32-1.mol

(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole) Properties

Density 1.44±0.1 g/cm3(Predicted)
pka 11.39±0.20(Predicted)

(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole) Chemical Properties,Uses,Production

Description

A dimeric alkaloid, gardmultine also occurs in Gardneria multiflora. Its structure has likewise been established from chemical analysis and spectroscopic investigations, primarily from the NMR and mass spectra.

References

Sakai et al., Tetrahedron Lett., 719 (1975)

(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole) Preparation Products And Raw materials

Raw materials

Preparation Products

(2R,19'E)-18'-Demethoxy-2-deoxo-17,17'-dideoxy-2,16':2,17-bisoxy-1,17'-bi(gardneramine oxindole) Gardmultine Dispiro[13,8b,10-ethanylylidene-11H-pyrido[2',3':5,6]oxepino[2,3-b]oxazolo[3,2-a]indole-2(3H),9'-[3,7]methanoindolizine-1'(5'H),3''-[3H]indol]-2''(1''H)-one, 6'-ethylidene-2',3',6',7',8',8'a,9,9a,12,13,13a,14-dodecahydro-4'',5,6'',7,7'',8-hexamethoxy-12-(2-methoxyethylidene)-, stereoisomer (9CI) 56197-32-1