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Tricyclohexyl phosphine

Tricyclohexyl phosphine
Tricyclohexyl phosphine structure
CAS No.
2622-14-2
Chemical Name:
Tricyclohexyl phosphine
Synonyms
TCHP;PCY3;TricycL;NSC 158657;Protein TCHP;Tricyclohexyl phosph;tricyclohexylphospine;Tricyclohexyphosphine;TRICYCLOHEXYLPHOSPHINE;tricyclohexyl-phosphin
CBNumber:
CB9251553
Molecular Formula:
C18H33P
Formula Weight:
280.43
MOL File:
2622-14-2.mol

Tricyclohexyl phosphine Properties

Melting point:
81-83 °C (lit.)
Boiling point:
110°C
Density 
0.909 g/mL at 25 °C
Flash point:
48 °F
storage temp. 
Inert atmosphere,2-8°C
form 
Solution
Specific Gravity
0.9
color 
White to off-white
Water Solubility 
Soluble in most organic solvents. Insoluble in water.
Sensitive 
Air Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
957171
InChIKey
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
CAS DataBase Reference
2622-14-2(CAS DataBase Reference)
NIST Chemistry Reference
Phosphine, tricyclohexyl-(2622-14-2)
EPA Substance Registry System
Phosphine, tricyclohexyl- (2622-14-2)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H304-H315-H319-H335-H336-H361d-H373-H335+H336-H302
Precautionary statements  P210-P261-P281-P301+P310-P305+P351+P338-P331-P280a-P304+P340-P405-P501a
Hazard Codes  Xi,Xn,F
Risk Statements  36/37/38-22-37/38-36-19-11-67-65-63-48/20-40
Safety Statements  26-36/37-62-37/39-36-33-29-16
RIDADR  UN 2056 3/PG 2
WGK Germany  3
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29319090
NFPA 704
1
2 1

Tricyclohexyl phosphine price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 261971 Tricyclohexylphosphine 2622-14-2 1g $48.1 2020-08-18 Buy
Sigma-Aldrich 261971 Tricyclohexylphosphine 97% 2622-14-2 5g $69.2 2020-08-18 Buy
Alfa Aesar 030386 Tricyclohexylphosphine 96% 2622-14-2 5g $67 2020-06-24 Buy
Alfa Aesar 030386 Tricyclohexylphosphine 96% 2622-14-2 1g $19.7 2020-06-24 Buy
Strem Chemicals 15-6150 Tricyclohexylphosphine, 97% 2622-14-2 5g $58 2021-03-22 Buy

Tricyclohexyl phosphine Chemical Properties,Uses,Production

Chemical Properties

clear colorless to pale yellow solution

Uses

  1. Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry.
  2. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.
  3. suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.
  4. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
  5. As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations.
  6. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions.
  7. Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

Purification Methods

It recrystallises from EtOH [Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 IV 947.]

Tricyclohexyl phosphine Preparation Products And Raw materials

Raw materials

Preparation Products


Tricyclohexyl phosphine Suppliers

Global( 333)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Wuhan Pengo Technology.,Ltd.
+86-27-81330736 +86-13628634921
+86-27-81330735 sunny.w@boronicgroup.com CHINA 171 58
XINXIANG RUNYU MATERIAL CO., LTD.
+8613592593621
0373-7759608 13592593621@163.com China 129 58
Springchem New Material Technology Co.,Limited
+8613917661608 +86-021-62885108
info@spring-chem.com China 2065 57
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 21022 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com CHINA 8882 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 26734 60
AB PharmaTech,LLC
323-480-4688
323-480-4688 sales01@abpharmatechusa.com United States 989 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29959 58
Changzhou Ansciep Chemical Co., Ltd.
+86 519 86305871
+86 519 86305879 sales@ansciepchem.com CHINA 4242 58

View Lastest Price from Tricyclohexyl phosphine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-10-27 Tricyclohexyl phosphine
2622-14-2
US $100.00 / KG/Tin 1KG 99% 10Tons Hebei Senko Biotechnology Co., Ltd.
2021-07-13 Tricyclohexyl phosphine
2622-14-2
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10 Tricyclohexyl phosphine
2622-14-2
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

Tricyclohexyl phosphine Spectrum


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