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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)

CAS No.
12131-44-1
Chemical Name:
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
Synonyms
Cinnamylpalladium chloride dimer;PalladiuM(II)(π-cinnaMyl) Chloride DiMer;adium(π-cinnamyL;Palladium(π-cinnamyl;Di-mu-chlorobis[(1,2,3-η;BIS[CINNAMYL PALLADIUM(II) CHLORIDE];Palladium(pi-cinnamyl) chloride dimer;Palladium(II)(2-cinnamyl) Chloride Dimer;PalladiuM(pi-cinnaMyl) chloride diMer 97%;PalladiuM(II)(pi-cinnaMyl) Chloride DiMer
CBNumber:
CB92521021
Molecular Formula:
C18H12Cl2Pd2
Molecular Weight:
512.03
MDL Number:
MFCD16621470
MOL File:
12131-44-1.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Properties

Melting point 218-220°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color yellow
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H315-H318-H331-H334
Precautionary statements  P261-P280-P284-P304+P340+P312-P305+P351+P338+P310-P403+P233
Hazard Codes  T
Risk Statements  23-43
Safety Statements  36/37-45
RIDADR  UN 2811 6.1 / PGIII
WGK Germany  3
HS Code  2843909000

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 720526 Palladium(π-cinnamyl) chloride dimer 97% 12131-44-1 1g $158 2024-03-01 Buy
TCI Chemical P2017 Palladium(II)(π-cinnamyl) Chloride Dimer >97.0%(T) 12131-44-1 200mg $73 2024-03-01 Buy
Strem Chemicals 46-0295 Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(II), 98% 12131-44-1 500mg $74 2024-03-01 Buy
Strem Chemicals 46-0295 Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(II), 98% 12131-44-1 2g $224 2024-03-01 Buy
TRC D438900 Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium 12131-44-1 100mg $70 2021-12-16 Buy
Product number Packaging Price Buy
720526 1g $158 Buy
P2017 200mg $73 Buy
46-0295 500mg $74 Buy
46-0295 2g $224 Buy
D438900 100mg $70 Buy

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Chemical Properties,Uses,Production

Application

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(ii) is an important organic regant for the use of transition-metal-mediated organic syntheses. It can be used as a catalyst for the ammonia cross-coupling reactions to synthesize arylamines and conversion of aryl triflates to fluorides.

Reaction

  1. Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
  2. Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.
  3. Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.
  4. Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .
Reactions of 12131-44-1

Uses

Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:

  • Ammonia cross-coupling reactions to synthesize arylamines.
  • Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 122)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Yunbio Tech Co.,Ltd.
+86-010-60605551 +86-18046518538 yunbiochem@126.com China 321 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5601 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
Longyan Tianhua Biological Technology Co., Ltd
0086 18039857276 18039857276 CHINA 2783 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58

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View Lastest Price from Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) pictures 2023-01-17 Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
12131-44-1
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
	Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) pictures 2022-09-24 Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
12131-44-1
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) pictures 2020-11-16 Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
12131-44-1
US $20.00 / KG 1KG 99% 10000KG Longyan Tianhua Biological Technology Co., Ltd
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II), 98% Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladiuM(II),98% PalladiuM(II)(pi-cinnaMyl) Chloride DiMer PalladiuM(pi-cinnaMyl) chloride diMer 97% Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(Ⅱ) Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium BIS[CINNAMYL PALLADIUM(II) CHLORIDE] )-1-phenyl-2-propenyl]dipalladium(II), 98% Di-mu-chlorobis[(1,2,3-η Palladium(II)(pi-cinnamyl)ChlorideDimer> adium(π-cinnamyL Palladium(pi-cinnamyl) chloride dimer Cinnamylpalladium chloride dimer PalladiuM(II)(π-cinnaMyl) Chloride DiMer Di( μ -chloro)bis(η 3- cinnamyl)dipalladium(II) Palladium(II)(2-cinnamyl) Chloride Dimer Palladium(π-cinnamyl 12131-44-1 C18H18Cl2Pd2 C9H9ClPd2 Pd