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Carboxin

CAS No.
5234-68-4
Chemical Name:
Carboxin
Synonyms
v4x;d735;Dmoc;f735;DCMO;d-735;f 735;d 735;Kisvax;OXATIN
CBNumber:
CB9267538
Molecular Formula:
C12H13NO2S
Molecular Weight:
235.3
MDL Number:
MFCD00055403
MOL File:
5234-68-4.mol
Last updated:2024-04-10 09:58:56

Carboxin Properties

Melting point 91.1-91.7°C
Boiling point 420.6±45.0 °C(Predicted)
Density 1.45
vapor pressure 2.5 x 10-5 Pa (25 °C)
refractive index 1.6000 (estimate)
Flash point 100 °C
storage temp. Sealed in dry,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka 14.31±0.70(Predicted)
form Crystals
color White
Water Solubility 10.095 g/100 mL
Merck 13,1837
BRN 983249
LogP 2.140
EWG's Food Scores 1
FDA UNII 5A8K850HDE
NIST Chemistry Reference Carboxin(5234-68-4)
EPA Substance Registry System Carboxin (5234-68-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08,GHS09
Signal word  Warning
Hazard statements  H302-H317-H373-H410
Precautionary statements  P260-P273-P280-P301+P312-P302+P352-P314
Hazard Codes  Xi,Xn
Risk Statements  21/22-36/37/38-20/21/22
Safety Statements  36-26
RIDADR  UN2588 (Pesticide, solid, poisonous, n.o.s.); UN2902 (Pesticide, liquid, poisonous, n.o.s.)
WGK Germany  3
RTECS  RP4550000
HS Code  29349990
Toxicity LD50 in rats, mice (mg/kg): 430, 3200 orally (Dyadicheva)
NFPA 704
0
2 0

Carboxin price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45371 Carboxine PESTANAL 5234-68-4 250mg $32.4 2024-03-01 Buy
TCI Chemical C3482 Carboxin 5234-68-4 5G $230 2024-03-01 Buy
TCI Chemical C3482 Carboxin 5234-68-4 25G $793 2024-03-01 Buy
TRC C177730 Carboxine 5234-68-4 25g $645 2021-12-16 Buy
American Custom Chemicals Corporation PST0000018 CARBOXIN 95.00% 5234-68-4 1G $679.14 2021-12-16 Buy
Product number Packaging Price Buy
45371 250mg $32.4 Buy
C3482 5G $230 Buy
C3482 25G $793 Buy
C177730 25g $645 Buy
PST0000018 1G $679.14 Buy

Carboxin Chemical Properties,Uses,Production

Description

Carboxin is a white crystalline solid.Molecular weight=235.32; Freezing/Meltingpoint=91.5-95℃ (depending on crystal structure); Vaporpressure=1.78 x 10 2 7 mmHg. Practically insoluble inwater; solubility=25 mg/L; 0.15 g/L at 20℃.

Chemical Properties

Carboxin is a white crystalline solid

Uses

Carboxin is used as a seed treatment for cereals and as a seedling treatment on many cereals, beans, and vegetable crops and cotton. It is also used for the treatment of turf.

Uses

Systemic plant fungicide.

Uses

Carboxine is an fungicide used for the control of fruit rot of custard apple.

Definition

ChEBI: An anilide obtained by formal condensation of the amino group of aniline with the carboxy group of 2-methyl-5,6-dihydro-1,4-oxathiine-3-carboxylic acid. A fungicide for control of bunts and smuts normally that is normally used as a seed treatment.

General Description

Off-white crystals. Systemic fungicide and seed protectant.

Agricultural Uses

Fungicide: Carboxin is a General Use Pesticide (GUP) and is used as a seed protectant. It is often used in combination with other fungicides such as thiram or captan. Carboxin is a systemic anilide fungicide. It is used as a seed treatment for control of smut, rot, and blight on barley, oats, rice, cotton, vegetables, corn and wheat. It is also used to control fairy rings on turf grass. Carboxin may be used to prevent the formation of these diseases or may be used to cure existing plant diseases. Also used as a wood preservative.

Trade name

CADAN®; CARBOXIN OXATHION PESTICIDE®; CASWELL No. 165 A®; D-735®; F-735®; FLO PRO V SEED PROTECTANT®[C]; KEMIKAR®; OXALIN®; PADAN®; SANVEX®; THIOBEL®; VEGETOX®; VITAFLO®; VITAVAX® 200FF; V 4X®

Safety Profile

Poison by ingestion. Moderately toxic by skin contact and possibly other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx.

Potential Exposure

A potential danger to those involved in the production, Formulation and application of this systemic fungicide, seed protectant and wood preservative

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. The sulfoxidation of carboxin to carboxin sulfoxide by the fungus Ustilago maydis was reported by Bollag and Liu (1990).
Soil. Carboxin oxidized in soil forming carboxin sulfoxide. The half-life in soil was reported to be 24 hours (Worthing and Hance, 1991).
Plant. In plants (barley, cotton and wheat) and water, carboxin oxidizes to the corresponding sulfoxide (Worthing and Hance, 1991).

Metabolic pathway

Carboxin is a systemic fungicide which is very stable to hydrolysis but is readily oxidised at sulfur to a sulfoxide and a sulfone. The latter, oxycarboxin, is itself a commercial fungicide. Metabolism is mainly by oxidation at sulfur in soil, plants and animals but hydroxylation of the phenyl ring is also important in animals. Hydrolysis has been convincingly demonstrated only in plants (peanut).

storage

Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with carboxin youshould be trained on its proper handling and storage. Storein tightly closed containers in a cool, well-ventilated area

Shipping

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Degradation

Carboxin is stable to hydrolysis (25 °C) at pH 5,7 and 9. Measurable rates are seen only at higher pH and occur by nucleophilic attack by hydroxyl ion at carbonyl. The half-life in 0.5 N NaOH is 107 days. Thus chemical hydrolysis is not expected to be significant under environmental conditions (El-Dib and Aly, 1976).
The compound is very labile to aqueous photolysis with a DT50 of <3 hours (PM).

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Avoid heat and humidity. Thermal decomposition products may include cyanide gas and cyanide salts.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

67980-06-7
5234-68-4
Synthesis of Carboxin from 1,3-Oxathiolane-2-acetamide, 2-methyl-N-phenyl-
Global( 254)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Liskon Biological Technology Co., Ltd
025-52110956 +8613814852963 sales@liskonchem.com China 7 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
career henan chemical co
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Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58
Longyan Tianhua Biological Technology Co., Ltd
0086 18039857276 18039857276 CHINA 2783 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58

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View Lastest Price from Carboxin manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Carboxin pictures 2020-11-18 Carboxin
5234-68-4
US $185.00 / KG 1KG 99 1000KG Longyan Tianhua Biological Technology Co., Ltd
Carboxin pictures 2020-03-24 Carboxin
5234-68-4
US $0.00-0.00 / Kg/Bag 25KG 98% 100tons Nanjing Liskon Biological Technology Co., Ltd
Vitavax pictures 2019-07-06 Vitavax
5234-68-4
US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co
  • Carboxin pictures
  • Carboxin
    5234-68-4
  • US $185.00 / KG
  • 99
  • Longyan Tianhua Biological Technology Co., Ltd
  • Carboxin pictures
  • Carboxin
    5234-68-4
  • US $0.00-0.00 / Kg/Bag
  • 98%
  • Nanjing Liskon Biological Technology Co., Ltd
  • Vitavax pictures
  • Vitavax
    5234-68-4
  • US $1.00 / kg
  • 99%
  • Career Henan Chemical Co

Carboxin Spectrum

1,4-Oxathiin, 2,3-dihydro-5-carboxanilido-6-methyl- 1,4-Oxathiin-3-carboxamide, 5,6-dihydro-2-methyl-N-phenyl- 1,4-oxathiin-3-carboxamide,5,6-dihydro-2-methyl-n-phenyl 1,4-Oxathiin-3-carboxanilide, 5,6-dihydro-2-methyl- 1,4-oxathiin-3-carboxanilide,5,6-dihydro-2-methyl- 2,3-Dihydro-5-carboxanilido-6-methyl-1,4-oxathiin d735 d-735 Dmoc dualmurganicrpb enhance enhanceplus f 735 f735 Flo pro v seed protectant floprovseedprotectant germateplus Kisvax mist-o-maticmurganic murganic pro-gro rtvvitavax v4x Vitaflo 250 vitaflo250 vitaflow Vitavax 100 Vitavax 735d Vitavax 75w vitavax100 vitavax-200 vitavax-300 vitavax30-c. VITAVAX(R) Vitavax(Uniroyal) CARBOXIN PESTANAL (5,6-DIHYDRO- 2-METHYL CARBOXIN, 1GM, NEAT CARBOXIN (5,6-DIHYDRO-2-METHYL-N-PHENYL-1,4-OXATHIIN-3-CARBOXAMIDE) 5,6-Dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-caboxamide carbathiine carboxin (bsi,iso,ansi) 5,6-dihydro-2-methyl-1,4-oxathiin- 3-carbonic acid, anilide 2,3-DIHYDRO-5-CARBOXANILINO-6-METHYL-1,4-OXATHIIN VITAVAXEC200 1,4-OXANTHIIN-3-CARBOXAMIDE,5,6-DIHYDRO-2-METHYL-N-PHENYL- Fenoxan Carboxin Standard 6-methyl-N-phenyl-2,3-dihydro-1,4-oxathiine-5-carboxamide Carboxin 1g [5234-68-4] Carboxine Standard 2,3-dihydro-5-carboxanilido-6-methyl-4-oxathiin 2,3-Dihydro-6-methyl-1,4-oxathiin-5-carboxanilide 2,3-dihydro-6-methyl-1,4-oxathiine-5-carboxylicacidanilide 2,3-dihydro-6-methyl-5-phenylcarbamoyl-1,4-oxathiin 2-Methyl-N-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide 5,6-Dihydro-2-methyl-3-carboxanilido-1,4-oxathiin 5,6-dihydro-2-methyl-4-oxathiin-3-carboxanilide 5,6-dihydro-2-methyl-n-phenyl-4-oxathiin-3-carboxamide