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ChemicalBook >> CAS DataBase List >>5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Structure
5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER structure
CAS No.
6942-37-6
Chemical Name:
5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER
Synonyms
NSC 57463;Methyl 5-aMino-2-broMobenzoate;Methyl 5-amino-2-bromobenzoate 98%;2-broMo-5-aMinobenzoic acid Methyl ester;5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER;Benzoic acid, 5-amino-2-bromo-, methyl ester
CBNumber:
CB9283637
Molecular Formula:
C8H8BrNO2
Molecular Weight:
230.06
MDL Number:
MFCD00085568
MOL File:
6942-37-6.mol
Last updated:2025-09-25 17:15:13
Product description Number Pack Size Price
methyl5-amino-2-bromobenzoate M286590 250mg $140
methyl5-amino-2-bromobenzoate M286590 1g $295
Methyl5-amino-2-bromobenzoate 98% OR55136 25g $427
Methyl 5-amino-2-bromobenzoate 98% 4658-9-26 25g $471
METHYL-5-AMINO-2-BROMOBENZOATE 95.00% HCH0107896 1G $629.53
Request For Quotation

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Properties

Boiling point 313.2±22.0 °C(Predicted)
Density 1.578±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 2.75±0.10(Predicted)
form liquid
color Clear, brown to very dark red

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H301-H315-H319-H335
Precautionary statements  P260-P280
Hazard Codes  T
Risk Statements  25
Safety Statements  45
RIDADR  UN 2811 6.1 / PGIII
HazardClass  6.1
PackingGroup  Ⅲ
HS Code  2922498590
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M286590 methyl5-amino-2-bromobenzoate 6942-37-6 250mg $140 2021-12-16 Buy
TRC M286590 methyl5-amino-2-bromobenzoate 6942-37-6 1g $295 2021-12-16 Buy
Apolloscientific OR55136 Methyl5-amino-2-bromobenzoate 98% 6942-37-6 25g $427 2021-12-16 Buy
SynQuest Laboratories 4658-9-26 Methyl 5-amino-2-bromobenzoate 98% 6942-37-6 25g $471 2021-12-16 Buy
American Custom Chemicals Corporation HCH0107896 METHYL-5-AMINO-2-BROMOBENZOATE 95.00% 6942-37-6 1G $629.53 2021-12-16 Buy
Product number Packaging Price Buy
M286590 250mg $140 Buy
M286590 1g $295 Buy
OR55136 25g $427 Buy
4658-9-26 25g $471 Buy
HCH0107896 1G $629.53 Buy

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Chemical Properties,Uses,Production

Synthesis

Methyl 2-bromo-5-nitrobenzoate

6942-36-5

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER

6942-37-6

General procedure for the synthesis of methyl 5-amino-2-bromobenzoate from methyl 2-bromo-5-nitrobenzoate: Methyl 2-bromo-5-nitrobenzoate (25.3 g, 97.3 mmol) was dissolved in anhydrous methanol (500 mL), followed by addition of stannous (II) chloride (93.3 g, 487 mmol). The reaction mixture was heated to reflux for 2 hours. Upon completion of the reaction, the mixture was cooled, ethyl acetate (500 mL) and water (100 mL) were added, and the reaction mixture was neutralized with 4N aqueous sodium hydroxide solution, followed by filtration through diatomaceous earth. The filtrate was concentrated under reduced pressure, ethyl acetate (200 mL) was added, and washed sequentially with saturated aqueous sodium bicarbonate (200 mL, 2 times), water (200 mL), and saturated brine (200 mL). The organic layer was dried with anhydrous magnesium sulfate and the solvent was removed under reduced pressure to afford the title compound methyl 5-amino-2-bromobenzoate (21.0 g) as a pale yellow oil in 94% yield.1H-NMR (400 MHz, DMSO-d6) δ 3.80 (s, 3H), 5.55 (s, 2H), 6.63 (dd, J = 8.8, 2.8 Hz, 1H), 6.94 (d, J = 2.8 Hz, 1H), 7.29 (d, J = 8.8 Hz, 1H).

References

[1] Patent: US2010/297073, 2010, A1. Location in patent: Page/Page column 20
[2] Journal of Organic Chemistry, 2017, vol. 82, # 15, p. 8296 - 8303
[3] Tetrahedron Letters, 2012, vol. 53, # 46, p. 6245 - 6249,5
[4] Patent: EP1995242, 2008, A1. Location in patent: Page/Page column 33
[5] Patent: EP2151436, 2010, A1. Location in patent: Page/Page column 17

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

3-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Methyl 2-bromo-5-nitrobenzoate METHYL 3-AMINOBENZOATE Methanol 5-AMINO-2-BROMOBENZOIC ACID
Methyl 3-amino-4-bromobenzoate Sodium hydroxide Water Ethyl acetate

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Preparation Products

Methyl 5-amino-2-cyanobenzoate

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Suppliers

Global( 84)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd 		+8615350571055 Sibel@chuanghaibio.com China 8753 58
Henan Bao Enluo International TradeCo.，LTD 		+86-17331933971 deasea125996@gmail.com China 2472 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 13620 58
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Shenzhen Nexconn Pharmatechs Ltd 		+86-755-89396905 +86-15013857715 admin@nexconn.com China 10405 58
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 21193 58
Fuxin Pharmaceutical 		+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 9999 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Win-Win chemical CO., Limited 		+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14358 58
Changzhou Anxuan Chemical Co., Ltd 		+86-0519-89882563 +86-18961279162 andy@anxuanchem.com China 4327 58
Supplier Advantage
Hebei Chuanghai Biotechnology Co., Ltd 		58
Henan Bao Enluo International TradeCo.，LTD 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
Changzhou Ansciep Chemical Co., Ltd. 		58
Shenzhen Nexconn Pharmatechs Ltd 		58
Accela ChemBio Inc. 		58
Fuxin Pharmaceutical 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Win-Win chemical CO., Limited 		58
Changzhou Anxuan Chemical Co., Ltd 		58

View Lastest Price from 5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER pictures 2026-01-05 5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER
6942-37-6
 US $10.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
Methyl 5-amino-2-bromobenzoate pictures 2024-04-23 Methyl 5-amino-2-bromobenzoate
6942-37-6
 US $100.00-30.00 / kg 1kg 99.93% 1000kg per week Ouhuang Engineering Materials (Hubei) Co., Ltd
5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER pictures 2023-08-08 5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER
6942-37-6
 US $50.00 / kg 1kg 99.9% 10000MT Henan Bao Enluo International TradeCo.，LTD

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER Spectrum

5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER(6942-37-6)1HNMR5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER(6942-37-6)FT-IR

6942-37-6(5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER)Related Search:

5-AMino-4-broMo-2-chloro-benzoic acid Methyl ester methyl 5-bromo-2-methoxybenzoate methyl 5-chloro-2-formylbenzoate methyl 5-formyl-2-nitrobenzoate Methyl 5-broMo-2-fluoro-3-nitrobenzoate
5-BroMo-2,4-difluoro-benzoic acid Methyl ester Methyl 4-hydroxy-2-methylbenzoate METHYL 5-BROMO-2-IODOBENZOATE Methyl 5-nitro-2-(trifluoromethyl)benzoate Methyl 5-aMino-2-iodobenzoate
methyl 5-amino-2-(trifluoromethyl)benzoate methyl 4-bromo-2-formylbenzoate Methyl 4-bromo-2,6-dichlorobenzoate METHYL 4-FORMYL-3-HYDROXYBENZOATE 5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester
methyl 5-amino-2-bromophenylacetate Methyl-5-amino-2-chlorobenzoate 5-AMino-2-chloro-4-fluoro-benzoic acid Methyl ester

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NSC 57463 5-AMINO-2-BROMO-BENZOIC ACID METHYL ESTER 2-broMo-5-aMinobenzoic acid Methyl ester Methyl 5-aMino-2-broMobenzoate Methyl 5-amino-2-bromobenzoate 98% Benzoic acid, 5-amino-2-bromo-, methyl ester 6942-37-6