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Camphene

CAS No.
79-92-5
Chemical Name:
Camphene
Synonyms
CAMPHENE 90;CAMPHENE 46;D,L-CAMPHENE;Camphene(DOT);Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-;FEMA 2229;2,2-Dimethyl-3-methylene-bicyclo[2.2.1]heptane;NA 9011;CAMPHENE;78.0%(GC)
CBNumber:
CB9303627
Molecular Formula:
C10H16
Molecular Weight:
136.23
MDL Number:
MFCD00066603
MOL File:
79-92-5.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:30

Camphene Properties

Melting point 48-52 °C (lit.)
Boiling point 159-160 °C (lit.)
Density 0.85 g/mL at 25 °C (lit.)
vapor pressure 3.99 hPa (20 °C)
refractive index 1.4551
FEMA 2229 | CAMPHENE
Flash point 94 °F
storage temp. 2-8°C
solubility 0.0042g/l
form Crystalline Low Melting Solid
color White
Specific Gravity 0.85
PH 5.5 (H2O, 22℃)(saturated aqueous solution)
Odor at 10.00 % in dipropylene glycol. woody herbal fir needle camphor terpenic
Odor Type woody
Odor Threshold 0.88ppm
Water Solubility practically insoluble
Merck 14,1730
JECFA Number 1323
Dielectric constant 2.7(20℃)
InChIKey CRPUJAZIXJMDBK-DTWKUNHWSA-N
LogP 4.22 at 20℃
Substances Added to Food (formerly EAFUS) CAMPHENE
FDA 21 CFR 172.515
CAS DataBase Reference 79-92-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII G3VG94Z26E
NIST Chemistry Reference Camphene(79-92-5)
EPA Substance Registry System Camphene (79-92-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS09
Signal word  Danger
Hazard statements  H228-H319-H410
Precautionary statements  P210-P240-P241-P264-P273-P305+P351+P338
Hazard Codes  F,N
Risk Statements  11-10-50/53-36
Safety Statements  16-33-61-60-26
RIDADR  UN 1325 4.1/PG 2
WGK Germany  2
RTECS  EX1055000
Autoignition Temperature 265 °C
HS Code  2902 19 00
HazardClass  4.1
PackingGroup  III
NFPA 704
3
2 1

Camphene price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20254 (+)-Camphene forsynthesis 79-92-5 100g $40.9 2024-03-01 Buy
Sigma-Aldrich 8.20254 (+)-Camphene forsynthesis 79-92-5 1kg $172 2024-03-01 Buy
Sigma-Aldrich 456055 Camphene 95% 79-92-5 1kg $221 2024-03-01 Buy
Sigma-Aldrich 442505 Camphene analytical standard 79-92-5 1000mg $27.8 2024-03-01 Buy
Sigma-Aldrich 01410590 Camphene primary reference standard 79-92-5 100mg $369 2024-03-01 Buy
Product number Packaging Price Buy
8.20254 100g $40.9 Buy
8.20254 1kg $172 Buy
456055 1kg $221 Buy
442505 1000mg $27.8 Buy
01410590 100mg $369 Buy

Camphene Chemical Properties,Uses,Production

Description

Camphene is a colorless to white crystallinesolid with camphor-like odor. It may be shipped as a liquid.Freezing/Melting point=50℃. Molecular weight=136.24;Boiling point=159℃; Melting point=37℃; Flashpoint=42℃ (oc); 33℃ (cc). Hazard Identification (basedon NFPA-704 M Rating System): Health 2, Flammability 3,Reactivity 0. Insoluble in water.

Chemical Properties

Camphene is a colorless to white crystalline solid, Camphor, or turpentine odor. It may be shipped as a liquid. Freezing/Melting point 5 50C.

Chemical Properties

WHITE CRYSTALLINE LOW MELTING SOLID

Chemical Properties

Camphene has a terpene, camphoraceous taste.

Occurrence

Reported found in carrot, dill, fennel, marjoram, nutmeg, parsley, pepper, tarragon and thyme.

Uses

Camphene is used in the preparation of fragrances and as a food additive for flavoring.

Uses

Manufacture of synthetic camphor, camphor substitute.

Preparation

From pinene by catalytic isomerization or from bornyl chloride by heating with alkali in the presence of abietenesulfonic acid.

Definition

ChEBI: A monoterpene with a bicyclic skeleton that is bicyclo[2.2.1]heptane substituted by geminal methyl groups at position 2 and a methylidene group at position 3. It is a widespread natural product found in many essential oils.

Aroma threshold values

Detection at 10%: camphoraceous, cooling, piney woody with terphy nuances. It has citrus and green minty and green spicy notes.

Taste threshold values

Taste characteristics at 50–100 ppm: camphoraceous, cooling, minty, with citrus and green spicy nuances.

General Description

A colorless to white crystalline solid with an insipid camphor-like odor. Dust and crystals are irritants to the eyes, nose and throat. Emits flammable vapors when heated. Emits acrid smoke and irritating fumes at high temperature. Used for the manufacture of synthetic camphor.

Reactivity Profile

Camphene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.

Hazard

Toxic by ingestion.

Health Hazard

Inhalation causes irritation of nose and throat. Contact with eyes or skin causes irritation.

Flammability and Explosibility

Flammable

Pharmacology

Oral administration of camphene (260 mmols/kg) to rats increased bile flow by 50% 4 hr after administration (M?rsdorf, 1966). Development of atheromatosis of the aorta in rabbits fed 1 g cholesterol/day for 3 months was considerably inhibited by simultaneous administration of a mixture of terpenes including camphene, injected sc in a dose of 1 ml every other day for 6 wk and then given orally in doses of 2 ml/day (Benk?, Macher, Szarvas & Tiboldi, 1961). The effect of 1 g cholesterol/day for 8 wk in the diet of rabbits in increasing the number and volume of mast cells in the aortic adventitia and increasing the total lipid content of the aortic wall was slightly enhanced by the simultaneous addition of 11 g camphene/day (Lesznyak, Benko, Szabo & Muller, 1972). This camphene treatment also decreased the lipid accumulation in the liver, but had no effect on the cholesterol-induced atheromatosis of the aorta (Benko, Szabo, Muller & Lesznyak, 1972).

Anticancer Research

This was tested against melanoma cells in a syngeneic model, and there was promisingantitumor activity (Ma et al. 2016).

Safety Profile

Mutation data reported. Combustible; yields flammable vapors when heated and can react with oxidizing materials. To fight fire, use water spray, foam, fog, CO2. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

Camphene is used to manufacture synthetic camphor; for making moth-proofing and in the cosmetics, perfume, and food flavoring industries.

First aid

f this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at leastCamphene 54715 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—Red: Flammability Hazard: Storein a flammable liquid storage area or approved cabinetaway from ignition sources and corrosive and reactivematerials. Prior to working with camphene you shouldbe trained on its proper handling and storage. Camphenemust be stored to avoid contact with strong oxidizers(such as chlorine, bromine, and fluorine) since violentreactions occur. Store in tightly closed containers in acool, well-ventilated area. Sources of ignition, such assmoking and open flames, are prohibited where Campheneis used, handled, or stored in a manner that could create apotential fire or explosion hazard. Use only nonsparkingtools and equipment, especially when opening and closingcontainers of camphene.

Shipping

UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN2319 Terpene hydrocarbons, n.o.s., Hazard Class: 3; Labels: 3- Flammable liquid

Incompatibilities

Forms explosive mixture with air. Emulsions in xylene may violently decompose on contact with iron or aluminum above 70C. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause exothermic reaction, releasing flammable hydrogen gas

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

50-00-0
177698-19-0
79-92-5
128-50-7
Synthesis of Camphene from Formaldehyde and Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, radical ion(1+), (1S)- (9CI)

Camphene Preparation Products And Raw materials

Global( 291)Suppliers
Supplier Tel Email Country ProdList Advantage
Anhui Royal Chemical Co., Ltd.
+86-25-86655873 +8613962173137 marketing@royal-chem.com China 142 55
Gansu Jinyuantai New Material Co., Ltd.
+86-025-86618065 +86-13914714331 sales@jinyuantaichem.com China 73 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Yancheng Green Chemicals Co.,Ltd
+undefined-86-25-86655873 info@royal-chem.com China 114 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Shaanxi Pioneer Biotech Co., Ltd .
+8613259417953 sales@pioneerbiotech.com China 3000 58

View Lastest Price from Camphene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Camphene pictures 2023-09-06 Camphene
79-92-5
US $0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Camphene pictures 2023-08-16 Camphene
79-92-5
US $1.00 / KG 1KG >99% 1000T Weijer International Trade (Hebei) Co., Ltd
Camphene pictures 2023-05-10 Camphene
79-92-5
US $56.00 / kg 1kg 0.99 5000 tons Hebei Duling International Trade Co. LTD
  • Camphene pictures
  • Camphene
    79-92-5
  • US $0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  • Camphene pictures
  • Camphene
    79-92-5
  • US $1.00 / KG
  • >99%
  • Weijer International Trade (Hebei) Co., Ltd
  • Camphene pictures
  • Camphene
    79-92-5
  • US $56.00 / kg
  • 0.99
  • Hebei Duling International Trade Co. LTD
camphene(2,2-dimethyl-3-methylene-norbornane) NA 9011 (+)-Camphene for synthesis (n)-camphene Camphene, 75%, remainder mainly alpha-fenchene DL-CAMPHENE, TECH 2-Dimethyl-3-methylenenorbornane CaMphene, reMainder Mainly alpha-fenchene, 75% 1LT CAMPHENE WITH GC (+/-)-Camphene (contains ca. 20% Tricyclene) (+/-)-CAMPHENE CAMPHENE AKOS NCG1-0107 2,2-DIMETHYL-3-METHYLENENORBORNANE 3,3-DIMETHYL-2-METHYLENENORCAMPHANE CAMPHENE P&F FCC CAMPHENE, 1000MG, NEAT Camphene,~80% Camphene, remainder mainly alpha-fenchene, 75% camphene,2,2-dimethyl-3-methylene-bicyclo[2.2.1]heptane;2,2-dimethyl-3-methylenenorborane D.L-CaMphene 0 2-Dimethyl-3-methylenenorbornane 3,3-Dimethyl-2-methylenenorcamphane 2,2-dimethyl-3-methylene-bicyclo(2.2.1)heptan 2,2-dimethyl-3-methylene-bicyclo[2.2.1]heptan 3,3-Dimethyl-2-methylenenorbornane 3,3-dimethyl-2-methylenenorcamphene JACS-79-92-5 (+/-)-Camphene (contains ca. 20% Tricyclene)> DL-Camphene (contains up to 20% tricyclene) 78.0%(GC) (+)-CAMPHENE FOR SYNTHESIS 1 KG (+)-CAMPHENE FOR SYNTHESIS 100 G (+/-)-Camphene (1S,4S)-3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- Camphene(DOT) D,L-CAMPHENE CAMPHENE 90 CAMPHENE 46 FEMA 2229 2,2-Dimethyl-3-methylene-bicyclo[2.2.1]heptane 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane (camphene) 79-92-5 Bicyclic Monoterpenes Terpenes Acyclic Alkenes Building Blocks Organic Building Blocks Pharmaceutical Intermediates Bicyclic Monoterpenes Biochemistry Terpenes Alpha Sort C CA - CG CAlphabetic Volatiles/ Semivolatiles