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(R)-(-)-Benzyl glycidyl ether

(R)-(-)-Benzyl glycidyl ether structure

CAS No.: 14618-80-5

Chemical Name:: (R)-(-)-Benzyl glycidyl ether

Synonyms: tert-butyl 3-oxoazepane-1-carboxylate;azepan-3-one;dicyclopropylmethanamine;tert-butyl 3-hydroxyazepane-1-carboxylate;2-(trimethylsilyl)ethanamine;benzyl piperidin-3-ylcarbamate;(2R)-2-(Benzyloxymethyl)oxirane;benzyl 3-hydroxypiperidine-1-carboxylate;tert-butyl 4-hydroxyazepane-1-carboxylate;5-TMP,2Na

CBNumber:: CB9320637

Molecular Formula:: C10H12O2

Molecular Weight:: 164.2

MDL Number:: MFCD00068409

MOL File:: 14618-80-5.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(R)-(-)-Benzyl glycidyl ether Properties

Melting point	88-93°C
alpha	-5.4 º (c=5 in toluene)
Boiling point	130 °C (0.1 mmHg)
Density	1.077 g/mL at 25 °C(lit.)
refractive index	n20/D 1.517(lit.)
Flash point	>230 °F
storage temp.	2-8°C
form	paste (yellow)
Specific Gravity	1.077
color	Colorless to Almost colorless
optical activity	[α]20/D 5.4°, c = 5 in toluene
Water Solubility	Soluble in water.
BRN	3588399
CAS DataBase Reference	14618-80-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-37/39

RIDADR

NA 1993 / PGIII

WGK Germany

RTECS

TX2860020

HS Code

29109000

Toxicity

mic-sat 660 nmol/plate MUREAV 298,197,1993

NFPA 704

	0
2		0

(R)-(-)-Benzyl glycidyl ether price More Price(44)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	791547	Titania paste, transparent	14618-80-5	10G	$225	2024-03-01	Buy
Sigma-Aldrich	791547	Titania paste, transparent	14618-80-5	20G	$326	2024-03-01	Buy
Sigma-Aldrich	720429	1H-Pyrazol-3-ylboronic acid hydrate	14618-80-5	1g	$251	2023-06-20	Buy
Sigma-Aldrich	363529	(R)-(?)-Glycidyl benzyl ether 99%	14618-80-5	1g	$42.4	2023-06-20	Buy
TCI Chemical	B2238	Benzyl (R)-(-)-Glycidyl Ether >98.0%(GC)	14618-80-5	1g	$19	2024-03-01	Buy

Product number	Packaging	Price	Buy
791547	10G	$225	Buy
791547	20G	$326	Buy
720429	1g	$251	Buy
363529	1g	$42.4	Buy
B2238	1g	$19	Buy

(R)-(-)-Benzyl glycidyl ether Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin.

Synthesis Reference(s)

Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6

General Description

1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Sodium hydride (S)-Oxiranemethanol N,N-Dimethylformamide Benzyl bromide Ethyl acetate

PETROLEUM ETHER

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Preparation Products

(S)-1-(benzylaMino)-3-(benzyloxy)propan-2-ol 2-Propanol, 1-[(2-broMo-5-fluoro-4-nitrophenyl)aMino]-3-(phenylMethoxy)-, (2R)-

(R)-(-)-Benzyl glycidyl ether Suppliers

Global( 312)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	906	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	6992	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88299272	info@edengenechem.com	China	2169	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Shanghai Arbor Chemical Co., Ltd.	58
Jinan Carbotang Biotech Co.,Ltd.	58
Accela ChemBio Inc.	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58

View Lastest Price from (R)-(-)-Benzyl glycidyl ether manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-03-17	(R)-(-)-Benzyl glycidyl ether 14618-80-5	US $51.00 / kg	1kg	99%	1000kg	Hebei Duling International Trade Co. LTD
2021-07-02	(R)-()-Glycidyl benzyl ether 14618-80-5	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2020-01-13	(R)-(-)-Benzyl glycidyl ether 14618-80-5	US $9.80 / KG	1g	≥99%	100kg	Career Henan Chemical Co

(R)-(-)-Benzyl glycidyl ether
14618-80-5
US $51.00 / kg
99%
Hebei Duling International Trade Co. LTD

(R)-()-Glycidyl benzyl ether
14618-80-5
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(R)-(-)-Benzyl glycidyl ether
14618-80-5
US $9.80 / KG
≥99%
Career Henan Chemical Co

(R)-(-)-Benzyl glycidyl ether Spectrum

(R)-(-)-Benzyl glycidyl ether(14618-80-5)IR (R)-(-)-Benzyl glycidyl ether(14618-80-5)Raman (R)-(-)-Benzyl glycidyl ether(14618-80-5)FT-IR

14618-80-5((R)-(-)-Benzyl glycidyl ether)Related Search:

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VERPROSIDE (R)-(+)-Trityl glycidyl ether Diethyl ether

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(R)-(-)-BENZYL GLYCIDYL ETHER (R)-BENZYL GLYCIDYL ETHER (R)-BENZYLOXYMETHYL-OXIRANE RARECHEM AK HZ 0049 (R)-(-)-2-(BENZYLOXYMETHYL)OXIRANE (R)-(-)-1-BENZYLOXY-2,3-EPOXYPROPANE (R)-1-BENZYLOXY-2,3-EPOXYPROPANE (r)-o-benzylglycidol 2,2'-(5-methyl-1,3-phenylene)diethanamine 2-bromo-2-p-tolylacetic acid benzyl 3-aminoazepane-1-carboxylate benzyl 3-hydroxyazepane-1-carboxylate benzyl 3-oxoazepane-1-carboxylate benzyl 4-aminoazepane-1-carboxylate benzyl 4-hydroxyazepane-1-carboxylate benzyl 4-oxoazepane-1-carboxylate benzyl azepan-4-ylcarbamate (S)-Morpholine-3-carboxylic acid AldrichCPR [Ir(dtbbpy)(ppy)2][PF6] AldrichCPR [Ir{dF(CF3)ppy}2(dtbpy)]PF6 AldrichCPR 1-(2,2,2-trifluoroethyl)piperazine AldrichCPR 1-(Tetrahydro-2H-pyran-2-yl)-3-pyrazole boronic acid MIDA ester 97% 1H-Pyrazol-3-ylboronic acid hydrate 2-Hexyl-4-pentynoic acid AldrichCPR 3-(2-thienyl)pyrazole AldrichCPR 3-(TrifluoroMethyl)-1,2,4-triazolo[4,3-a]piperazine hydrochloride AldrichCPR 4'-(1H-1,2,4-triazol-1-yl)phenol AldrichCPR 4-(2-Chlorophenoxy)piperidine hydrochloride AldrichCPR 4-(DiphenylaMino)phenylboronic acid pinacol ester 95% Azide-fluor 488 >=90% (HPLC) BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct May contain up to 1 Mole equivalent of MTBE, 97% CdSeS/ZnS alloyed quantuM dots COOH functionalized, fluorescence laMbdaeM 525 nM, 6 nM diaMeter, 1 Mg/ML in H2O CdSeS/ZnS alloyed quantuM dots COOH functionalized, fluorescence laMbdaeM 575 nM, 6 nM diaMeter, 1 Mg/ML in H2O Dibenzocyclooctyne-acid storage teMp.: -20C, 95% Graphene oxide 2 Mg/ML, dispersion in H2O Graphene oxide sheets Isoflurane AldrichCPR N,N-bis(2-hydroxyethyl)-1,4-phenylenediaMine sulfate AldrichCPR PCy3 Pd G2 95% PlatinuM on graphitized carbon extent of labeling: 20 wt. % loading R-95 RhaMnolipid 95%, AldrichCPR SodiuM undecylenate AldrichCPR SYLGARD(R) 184 5 g clip-pack spiro[4.5]-decan-1-one 2-AMINO-3-HYDROXY-3-METHYLPROPANENITRILE 2-AMINO-3-HYDROXY-4-METHYLPROPANENITRILE 3-epoxy-1-(benzyloxy)-(r)-propan 3-epoxy-1-(benzyloxy)-(s)-propan (-)-BENZYL (R)-GLYCIDYL ETHER BENZYL (R)-(-)-GLYCIDYL ETHER BENZYL (R)-GLYCIDYL ETHER Z-DL-Gln-OH 2'O-Me-rC(tac) CPG500 DL-Arg(NO2)-OBzl.TosOH 1-(4-isopropoxyphenyl)piperazine 5-TMP,2Na (S)-tert-butyl 2-propylazetidine-1-carboxylate 1-p-tolylcyclobutanecarbonitrile