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Trifluoromethanesulfonimide

CAS No.
82113-65-3
Chemical Name:
Trifluoromethanesulfonimide
Synonyms
Bis(trifluoromethanesulfonyl)imide;bis(Trifluoromethanesulphonyl)imide;bis(trifluoromethanesulfonyl)amide;BISTRIFLUOROMETHANESULFONIMIDE;BIS(TRIFLUOROMETHANESULFONYL)AMINE;Bis[(trifluoroMethyl)sulphonyl]aMine;SKL1549;TRIFLUOROMETHANSULFONAMIDE;Trifluoromethansulfonimide;TRIFLUOROMETHANESULFONIMIDE
CBNumber:
CB9355545
Molecular Formula:
C2HF6NO4S2
Molecular Weight:
281.15
MDL Number:
MFCD00214154
MOL File:
82113-65-3.mol
MSDS File:
SDS
Last updated:2024-03-14 09:35:58

Trifluoromethanesulfonimide Properties

Melting point 52-56 °C
Boiling point 90-91 °C(lit.)
Density 1.36
storage temp. 2-8°C
solubility 800g/l Risk of violent reaction.
form Crystals
pka -10.42±0.40(Predicted)
color Colorless to brownish
PH 0.8 (100g/l, H2O, 20℃)Risk of violent reaction.
BRN 4754101
Stability Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
InChIKey ZXMGHDIOOHOAAE-UHFFFAOYSA-N
LogP -0.771 at 25.5℃ and pH6.7
CAS DataBase Reference 82113-65-3(CAS DataBase Reference)
FDA UNII C7R849VM9L
EPA Substance Registry System Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Signal word  Danger
Hazard statements  H301-H318-H412
Hazard statements  H301-H318-H412
Precautionary statements  P273-P280-P301+P310+P330-P305+P351+P338+P310
Precautionary statements  P273-P280-P301+P310+P330-P305+P351+P338+P310
Hazard Codes  C
Risk Statements  34-40-14-67-37
Safety Statements  26-36/37/39-45-8
RIDADR  UN 3265 8/PG 2
WGK Germany  3
3-10-21
Hazard Note  Corrosive
HazardClass  8
PackingGroup  I
HS Code  29350090
NFPA 704
1
3 2
W

Trifluoromethanesulfonimide price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 15220 Bis(trifluoromethane)sulfonimide purum, ≥95.0% (19F-NMR) 82113-65-3 5g $172 2024-03-01 Buy
Sigma-Aldrich 15220 Bis(trifluoromethane)sulfonimide purum, ≥95.0% (19F-NMR) 82113-65-3 25g $283 2024-03-01 Buy
TCI Chemical B2541 Bis(trifluoromethanesulfonyl)imide >99.0%(T) 82113-65-3 5g $48 2024-03-01 Buy
TCI Chemical B2541 Bis(trifluoromethanesulfonyl)imide >99.0%(T) 82113-65-3 25g $141 2024-03-01 Buy
Sigma-Aldrich 464635 Trifluoromethanesulfonimide ≥95.0% (19F-NMR) 82113-65-3 5g $109 2024-03-01 Buy
Product number Packaging Price Buy
15220 5g $172 Buy
15220 25g $283 Buy
B2541 5g $48 Buy
B2541 25g $141 Buy
464635 5g $109 Buy

Trifluoromethanesulfonimide Chemical Properties,Uses,Production

Chemical Properties

light yellow to brown liquid

Uses

Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.

Uses

Trifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.

Uses

1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes.

Application

Trifluoromethanesulfonimide may be used in the following studies:
As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
As a component of solid polymer electrolytes.

General Description

Bis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.

35034-08-3
82113-65-3
Synthesis of Trifluoromethanesulfonimide from Methanesulfonamide, 1,1,1-trifluoro-N-(phenylmethyl)-N-[(trifluoromethyl)sulfonyl]-

Trifluoromethanesulfonimide Preparation Products And Raw materials

Global( 291)Suppliers
Supplier Tel Email Country ProdList Advantage
JIANGXI TIME PHARMACEUTICAL CO.,LTD
+86-0794-7183888 +86-13155888520 sales@groupchem.com China 27 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
LY Global chemicals co.,ltd .
+8618939937369 info@lychems.cn China 969 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 6710 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15932 58
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9346 55
Fluoropharm Co., Ltd.
+86-0571-85586753; +8613336034509 sales@fluoropharm.com China 1377 60
Zjartschem
+86-571-8723 8903 jocelynpan@zjarts.com jocelynpan@zjarts.com CHINA 993 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58

View Lastest Price from Trifluoromethanesulfonimide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(trifluoromethane)sulfonimide pictures 2024-02-23 Bis(trifluoromethane)sulfonimide
82113-65-3
US $24.00-327.00 / g 25g 0.98 100kg Shanghai UCHEM Inc.
TRIFLUOROMETHANESULFONIMIDE pictures 2023-10-09 TRIFLUOROMETHANESULFONIMIDE
82113-65-3
US $25.00-5.00 / kgkg 1kgkg 0.99 20tons Hebei Yanxi Chemical Co., Ltd.
TRIFLUOROMETHANESULFONIMIDE pictures 2023-09-06 TRIFLUOROMETHANESULFONIMIDE
82113-65-3
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.

Trifluoromethanesulfonimide Spectrum

TRIFLUOROMETHANESULFONIMIDE Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine Bis(trifluoromethane)sulfonimide,Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine Trifluoromethanesulfonimide,Bis(trifluoromethanesulfonyl)amine Trifluoromethansulfonimide BISTRIFLUOROMETHANESULFONIMIDE SOL., ~0. 5 M IN DICHLOROM. N,N-Bis(trifluoromethylsulfonyl)amine bis(trifluoromethane)sulfonimide solution Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)- N,N-Bis-(trifluoromethylsulfonyl)-imide TRIFLUOROMETHANSULFONAMIDE Bis(trifluoromethanesulfonyl)imide,99% bis(trifluroMethanesulfonyl) iMide Bis(trifluoroMethanesulfonyl)iMide, 99% 5GR TrifluoroMethanesulfoniMide 95% Bis(trifluoromethylsulfonyl)imide for synthesis 1,1,1-Trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide BIS(TRIFLUOROMETHYLSULFONYL)AMINE BIS(TRIFLUOROMETHANE)SULFONAMIDE bistrifluoromethanesulfonimidesol. 1,1,1-TRIFLUORO-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE Bis(trifluoroMethane)sulfoniMide puruM, >=95.0% (19F-NMR) N,N-BIS(TRIFLUOROMETHYLSULPHONYL)AMINE N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE ACID TRIFLUOROMETHANESULFONIMIDE 82113-65-3 Bis(trifluoromethane)sulfonimide Bis(trifluoromethane)sulfonimide in stock Factory N,N-Bis(trifluoromethanesulfonyl)imide, 20mM in nitromethane SKL1549 bis(Trifluoromethanesulphonyl)imide Bis[(trifluoroMethyl)sulphonyl]aMine Bis(trifluoromethanesulfonyl)imide BIS(TRIFLUOROMETHANESULFONYL)AMINE BISTRIFLUOROMETHANESULFONIMIDE bis(trifluoromethanesulfonyl)amide 82113-65-3 822113-65-3 CF3SO22NH C2HF6NO4S2 Synthetic Reagents Sulfonimides/Sulfinimides Building Blocks Organic Building Blocks Fluorination C-X Bond Formation (Halogen) Sulfur Compounds Trifluoromethylation Chemical Synthesis Fluorination Fluorination Reagents Synthetic Reagents Building Blocks Organic Building Blocks Sulfonimides/Sulfinimides Sulfur Compounds