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Trifluoromethanesulfonimide

Trifluoromethanesulfonimide Structure
Trifluoromethanesulfonimide structure
CAS No.
82113-65-3
Chemical Name:
Trifluoromethanesulfonimide
Synonyms
Bis(trifluoromethanesulfonyl)imide;bis(Trifluoromethanesulphonyl)imide;bis(trifluoromethanesulfonyl)amide;BISTRIFLUOROMETHANESULFONIMIDE;BIS(TRIFLUOROMETHANESULFONYL)AMINE;Bis[(trifluoroMethyl)sulphonyl]aMine;TFSI;Tf2NH;HNTF2;SKL1549
CBNumber:
CB9355545
Molecular Formula:
C2HF6NO4S2
Molecular Weight:
281.15
MDL Number:
MFCD00214154
MOL File:
82113-65-3.mol
MSDS File:
SDS
Last updated:2025-10-21 10:17:20
Product description Number Pack Size Price
Bis(trifluoromethane)sulfonimide purum, ≥95.0% (19F-NMR) 15220 5g $177
Bis(trifluoromethane)sulfonimide purum, ≥95.0% (19F-NMR) 15220 25g $292
Bis(trifluoromethanesulfonyl)imide >99.0%(T) B2541 5g $48
Bis(trifluoromethanesulfonyl)imide >99.0%(T) B2541 25g $141
Trifluoromethanesulfonimide ≥95.0% (19F-NMR) 464635 5g $112
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Trifluoromethanesulfonimide Properties

Melting point 52-56 °C
Boiling point 90-91 °C(lit.)
Density 1.36
storage temp. 2-8°C
solubility 800g/l Risk of violent reaction.
form Crystals
pka -10.42±0.40(Predicted)
color Colorless to brownish
PH 0.8 (100g/l, H2O, 20℃)Risk of violent reaction.
BRN 4754101
Stability Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
InChIKey ZXMGHDIOOHOAAE-UHFFFAOYSA-N
LogP -0.771 at 25.5℃ and pH6.7
CAS DataBase Reference 82113-65-3(CAS DataBase Reference)
FDA UNII C7R849VM9L
EPA Substance Registry System Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3)
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Signal word  Danger
Hazard statements  H301-H318-H412
Hazard statements  H301-H318-H412
Precautionary statements  P273-P280-P301+P310+P330-P305+P351+P338+P310
Precautionary statements  P273-P280-P301+P310+P330-P305+P351+P338+P310
Hazard Codes  C
Risk Statements  34-40-14-67-37
Safety Statements  26-36/37/39-45-8
RIDADR  UN 3265 8/PG 2
WGK Germany  3
F  3-10-21
Hazard Note  Corrosive
HazardClass  8
PackingGroup  I
HS Code  29350090
Excepted Quantities Not Permitted as Excepted Quantity
NFPA 704
1
3 2
W

Trifluoromethanesulfonimide price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 15220 Bis(trifluoromethane)sulfonimide purum, ≥95.0% (19F-NMR) 82113-65-3 5g $177 2025-07-31 Buy
Sigma-Aldrich 15220 Bis(trifluoromethane)sulfonimide purum, ≥95.0% (19F-NMR) 82113-65-3 25g $292 2025-07-31 Buy
TCI Chemical B2541 Bis(trifluoromethanesulfonyl)imide >99.0%(T) 82113-65-3 5g $48 2025-07-31 Buy
TCI Chemical B2541 Bis(trifluoromethanesulfonyl)imide >99.0%(T) 82113-65-3 25g $141 2025-07-31 Buy
Sigma-Aldrich 464635 Trifluoromethanesulfonimide ≥95.0% (19F-NMR) 82113-65-3 5g $112 2025-07-31 Buy
Product number Packaging Price Buy
15220 5g $177 Buy
15220 25g $292 Buy
B2541 5g $48 Buy
B2541 25g $141 Buy
464635 5g $112 Buy

Trifluoromethanesulfonimide Chemical Properties,Uses,Production

Chemical Properties

light yellow to brown liquid

Uses

Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.

Uses

Trifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.

Uses

1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes.

Application

Trifluoromethanesulfonimide may be used in the following studies:
As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
As a component of solid polymer electrolytes.

General Description

Bis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.

Synthesis

Lithium bis(trifluoromethanesulphonyl)imide

90076-65-6

Trifluoromethanesulfonimide

82113-65-3

The general procedure for the synthesis of lithium bis(trifluoromethanesulfonyl)imide (HTf2N) from lithium bis(trifluoromethanesulfonyl)imide (LiTf2N) is as follows: LiTf2N is dissolved in concentrated sulfuric acid, followed by sublimation at 70 °C under reduced pressure (10^-3 mbar) to give the HTf2N crude product. This crude product can be further purified. The yield was 90%. The NMR hydrogen spectrum (1H-NMR, D2O) of the product showed: δ 4.77 (s, 1H); the NMR fluorine spectrum (19F-NMR, D2O) showed: δ -79.16 (s, 6F); and the NMR carbon spectrum (13C{19F}NMR, D2O) showed: δ 119.27 (s, 2C).

References

[1] Journal fuer Praktische Chemie/Chemiker-Zeitung, 1998, vol. 340, # 6, p. 506 - 512
[2] Physical Chemistry Chemical Physics, 2011, vol. 13, # 2, p. 725 - 731
[3] Journal of Fluorine Chemistry, 2007, vol. 128, # 10, p. 1326 - 1334
[4] Chemistry - A European Journal, 2010, vol. 16, # 11, p. 3355 - 3365
[5] Journal of Molecular Liquids, 2014, vol. 192, p. 191 - 198

Trifluoromethanesulfonimide synthesis

35034-08-3
82113-65-3
Synthesis of Trifluoromethanesulfonimide from Methanesulfonamide, 1,1,1-trifluoro-N-(phenylmethyl)-N-[(trifluoromethyl)sulfonyl]-

Trifluoromethanesulfonimide Preparation Products And Raw materials

Raw materials

Methanesulfonamide, 1,1,1-trifluoro-N-(phenylmethyl)-N-[(trifluoromethyl)sulfonyl]- Lithium bis(trifluoromethanesulphonyl)imide

Preparation Products

1-BUTYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE Sliver bis(trifluoromethane sulfonimide) 1-IODO-3,4-METHYLENEDIOXYBENZENE

Trifluoromethanesulfonimide Suppliers

Global( 322)Suppliers
Supplier Tel Email Country ProdList Advantage
JIANGXI TIME PHARMACEUTICAL CO.,LTD
+86-0794-7183888 +86-13155888520 sales@groupchem.com China 27 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21616 55
LY Global chemicals co.,ltd .
+8618939937369 info@lychems.cn China 969 58
Hebei Yanxi Chemical Co., Ltd. 		+8618531123677 faithe@yan-xi.com China 5853 58
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 8422 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18126 58
Hebei Zhuanglai Chemical Trading Co Ltd 		+86-16264648883 niki@zlchemi.com China 7245 58
Fluoropharm Co., Ltd. 		+86-0571-85586753 +86-13336034509 sales@fluoropharm.com China 1445 60
Zjartschem 		+86-571 87238903 jocelynpan@zjarts.com CHINA 988 58
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29850 58
Supplier Advantage
JIANGXI TIME PHARMACEUTICAL CO.,LTD
58
Henan Tianfu Chemical Co.,Ltd.
55
LY Global chemicals co.,ltd .
58
Hebei Yanxi Chemical Co., Ltd. 		58
Shanghai UCHEM Inc. 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Hebei Zhuanglai Chemical Trading Co Ltd 		58
Fluoropharm Co., Ltd. 		60
Zjartschem 		58
career henan chemical co 		58

Related articles

View Lastest Price from Trifluoromethanesulfonimide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TRIFLUOROMETHANESULFONIMIDE pictures 2025-11-10 TRIFLUOROMETHANESULFONIMIDE
82113-65-3
 0.99 RongNa Biotechnology Co.,Ltd
Bis(trifluoromethane)sulfonimide pictures 2025-11-10 Bis(trifluoromethane)sulfonimide
82113-65-3
 US $24.00-327.00 / g 25g 0.98 100kg Shanghai UCHEM Inc.
TRIFLUOROMETHANESULFONIMIDE pictures 2025-06-27 TRIFLUOROMETHANESULFONIMIDE
82113-65-3
 US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd

Trifluoromethanesulfonimide Spectrum

Trifluoromethanesulfonimide(82113-65-3)13CNMRTrifluoromethanesulfonimide(82113-65-3)19FNMRTrifluoromethanesulfonimide(82113-65-3)FT-IR

82113-65-3(Trifluoromethanesulfonimide)Related Search:

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TRIFLUOROMETHANESULFONIMIDE Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine Bis(trifluoromethane)sulfonimide,Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine Trifluoromethanesulfonimide,Bis(trifluoromethanesulfonyl)amine Trifluoromethansulfonimide BISTRIFLUOROMETHANESULFONIMIDE SOL., ~0. 5 M IN DICHLOROM. N,N-Bis(trifluoromethylsulfonyl)amine bis(trifluoromethane)sulfonimide solution Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)- N,N-Bis-(trifluoromethylsulfonyl)-imide TRIFLUOROMETHANSULFONAMIDE Bis(trifluoromethanesulfonyl)imide,99% bis(trifluroMethanesulfonyl) iMide Bis(trifluoroMethanesulfonyl)iMide, 99% 5GR TrifluoroMethanesulfoniMide 95% Bis(trifluoromethylsulfonyl)imide for synthesis 1,1,1-Trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide BIS(TRIFLUOROMETHYLSULFONYL)AMINE BIS(TRIFLUOROMETHANE)SULFONAMIDE bistrifluoromethanesulfonimidesol. 1,1,1-TRIFLUORO-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE Bis(trifluoroMethane)sulfoniMide puruM, >=95.0% (19F-NMR) N,N-BIS(TRIFLUOROMETHYLSULPHONYL)AMINE N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE ACID TRIFLUOROMETHANESULFONIMIDE 82113-65-3 Bis(trifluoromethane)sulfonimide Bis(trifluoromethane)sulfonimide in stock Factory N,N-Bis(trifluoromethanesulfonyl)imide, 20mM in nitromethane SKL1549 bis(Trifluoromethanesulphonyl)imide Bis[(trifluoroMethyl)sulphonyl]aMine Bis(trifluoromethanesulfonyl)imide BIS(TRIFLUOROMETHANESULFONYL)AMINE BISTRIFLUOROMETHANESULFONIMIDE bis(trifluoromethanesulfonyl)amide Tf2NH TFSI HNTF2 TRIFLUOROMETHANESULFONIMIDE 99.5% 82113-65-3 822113-65-3 CF3SO22NH C2HF6NO4S2 Synthetic Reagents Sulfonimides/Sulfinimides Building Blocks Organic Building Blocks Fluorination C-X Bond Formation (Halogen) Sulfur Compounds Trifluoromethylation Chemical Synthesis Fluorination Fluorination Reagents Synthetic Reagents Building Blocks Organic Building Blocks Sulfonimides/Sulfinimides