Furfuryl mercaptan
- CAS No.
- 98-02-2
- Chemical Name:
- Furfuryl mercaptan
- Synonyms
- 2-Furfurylthiol;2-FURANMETHANETHIOL;FURFURYL THIOL;Furfural mercaptan;usafb-58;NSC 41142;USAF B-58;FEMA 2493;Coffee mercaptan;FUFURYL MERCAPTAN
- CBNumber:
- CB9387119
- Molecular Formula:
- C5H6OS
- Molecular Weight:
- 114.17
- MDL Number:
- MFCD00003254
- MOL File:
- 98-02-2.mol
- MSDS File:
- SDS
| Melting point | 157.5 °C |
|---|---|
| Boiling point | 155 °C(lit.) |
| Density | 1.132 g/mL at 25 °C(lit.) |
| refractive index |
n |
| FEMA | 2493 | FURFURYL MERCAPTAN |
| Flash point | 113 °F |
| storage temp. | Flammables area |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| pka | 9.59±0.10(Predicted) |
| form | Liquid |
| color | Clear colorless to pale yellow |
| Odor | at 0.10 % in dipropylene glycol. sulfury roasted coffee oily fatty burnt smoky |
| Odor Type | coffee |
| Water Solubility | insoluble |
| Sensitive | Air Sensitive |
| JECFA Number | 1072 |
| BRN | 383594 |
| Stability | Air Sensitive |
| LogP | 1.73 |
| CAS DataBase Reference | 98-02-2(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | FURFURYL MERCAPTAN |
| FDA UNII | 29W096TCPG |
| NIST Chemistry Reference | 2-Furanmethanethiol(98-02-2) |
| EPA Substance Registry System | 2-Furanmethanethiol (98-02-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226 | |||||||||
| Precautionary statements | P210 | |||||||||
| Hazard Codes | F,Xn | |||||||||
| Risk Statements | 10-36/37-20/21/22 | |||||||||
| Safety Statements | 23-24/25-16-36-26-7/9 | |||||||||
| RIDADR | UN 3336 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | LU2100000 | |||||||||
| F | 10-13-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29321900 | |||||||||
| NFPA 704 |
|
Furfuryl mercaptan price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W249311 | Furfuryl Mercaptan natural, 98%, FG | 98-02-2 | 100g | $683 | 2024-03-01 | Buy |
| Sigma-Aldrich | W249311 | Furfuryl Mercaptan natural, 98%, FG | 98-02-2 | 500g | $2800 | 2024-03-01 | Buy |
| Sigma-Aldrich | W249300 | Furfuryl Mercaptan ≥97%, FG | 98-02-2 | 1kg | $205 | 2024-03-01 | Buy |
| Sigma-Aldrich | W249300 | Furfuryl Mercaptan ≥97%, FG | 98-02-2 | 2.5kg | $479 | 2024-03-01 | Buy |
| Sigma-Aldrich | F20408 | 2-Furanmethanethiol 98% | 98-02-2 | 25g | $58.4 | 2024-03-01 | Buy |
Furfuryl mercaptan Chemical Properties,Uses,Production
Description
Furfuryl mercaptan has a characteristic unpleasant odor. It is prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfide in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina. Furfuryl mercaptan tends to polymerize when heated in the presence of mineral acids.
Chemical Properties
2-Furylmethanethiol is an important constituent of the aroma of roasted coffee. It is a liquid with an unpleasant odor, which becomes like coffee when diluted.
Chemical Properties
clear colorless to pale yellow liquid
Chemical Properties
Furfuryl mercaptan has a characteristic unpleasant odor.
Occurrence
Reported found in raw and roasted chicken, cooked beef, grilled pork, sesame seed oil, coffee and popcorn; tends to polymerize when heated in the presence of mineral acids
Uses
Furfuryl Mercaptam is a volatile flavor component of corn tortilla chips.
Definition
ChEBI: 2-Furanmethanethiol is a heteroarene.
Preparation
Furfuryl mercaptan is prepared from furfuryl alcohol, thiourea, and hydrogen chloride.The resulting S-furfurylisothiouronium chloride is cleaved with sodium hydroxide to give furfuryl mercaptan.
Aroma threshold values
Detection: 0.005 to 0.01 ppb; aroma characteristics at 0.01%: intense sulfurous onion impact, lacrimator, slightly skunk-like with a dairy nuance and a hint of savory and coffee-like notes.
Taste threshold values
Taste characteristics at 0.2 to 1 ppb: sulfureous, roasted, onion, garlic and coffee.
General Description
Darkens on storage
Safety Profile
Poison by intraperitoneal route. Experimental reproductive effects. Used as a flavoring in chocolate, fruit, nuts, and coffee. When heated to decomposition it emits toxic fumes of SOx. See also MERCAPTANS.
Synthesis
Prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfde in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina.
Furfuryl mercaptan Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8823 | 58 |
| Cangzhou Wanyou New Material Technology Co.,Ltd | 18631714998 | sales@czwytech.com | CHINA | 906 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | sales@amoychem.com | China | 6387 | 58 |
| Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2169 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
View Lastest Price from Furfuryl mercaptan manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-08-15 | Furfuryl mercaptan
98-02-2
|
US $100.00 / kg | 1kg | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-03-11 | Furfuryl mercaptan
98-02-2
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Guanlang Biotechnology Co., Ltd. | |
 |
2021-08-12 | Furfuryl mercaptan
98-02-2
|
US $0.00 / g | 1g | 99% | 50ton | Shijiazhuang tongyang Import and Export Co., LTD |
-
- Furfuryl mercaptan
98-02-2
- US $100.00 / kg
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Furfuryl mercaptan
98-02-2
- US $10.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- Furfuryl mercaptan
98-02-2
- US $0.00 / g
- 99%
- Shijiazhuang tongyang Import and Export Co., LTD
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