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Chlorodiphenylmethane

CAS No.
90-99-3
Chemical Name:
Chlorodiphenylmethane
Synonyms
(ChloroMethylene)dibenzene;AI311230;AI3 11230;AI3-11230;AKOS BBS-00004295;alpha-chloroditan;1-Chloro-2-(αBENZHYDRYL CHLORIDE;DIPHENYLCHLOROMETHANE;CHLORODIPHENYLMETHANE
CBNumber:
CB9396670
Molecular Formula:
C13H11Cl
Molecular Weight:
202.68
MDL Number:
MFCD00000855
MOL File:
90-99-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-12 09:11:21
Product description Number Pack Size Price
Chlorodiphenylmethane 98% 125032 5g $30.5
Chlorodiphenylmethane 98% 125032 100g $296
Benzhydryl Chloride B1078 25ML $109
Benzhydryl Chloride B1078 500ML $896
Chlorodiphenylmethane C368015 500g $340
More product size

Chlorodiphenylmethane Properties

Melting point 15-17 °C(lit.)
Boiling point 140 °C3 mm Hg(lit.)
Density 1.14 g/mL at 25 °C(lit.)
refractive index n20/D 1.595(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Soluble), Methanol (Sparingly)
form Liquid
Specific Gravity 1.14
color Clear colorless to yellow
Water Solubility slightly soluble
BRN 607925
InChI 1S/C13H11Cl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H
InChIKey ZDVDCDLBOLSVGM-UHFFFAOYSA-N
SMILES ClC(c1ccccc1)c2ccccc2
CAS DataBase Reference 90-99-3(CAS DataBase Reference)
FDA UNII CN9N9AYV4B
NIST Chemistry Reference Benzene, 1,1'-(chloromethylene)bis-(90-99-3)
EPA Substance Registry System Benzene, 1,1'-(chloromethylene)bis- (90-99-3)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi,C
Risk Statements  36/38-36/37/38-36-34
Safety Statements  26-36-24/25-45-36/37/39-27
RIDADR  UN 3265 8/PG 2
WGK Germany  3
TSCA  TSCA listed
HazardClass  8
PackingGroup  III
HS Code  29036990
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Skin Corr. 1B
Hazardous Substances Data 90-99-3(Hazardous Substances Data)
REACH Registrations Active
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
0
3 0

Chlorodiphenylmethane price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 125032 Chlorodiphenylmethane 98% 90-99-3 5g $30.5 2026-04-30 Buy
Sigma-Aldrich 125032 Chlorodiphenylmethane 98% 90-99-3 100g $296 2026-04-30 Buy
TCI Chemical B1078 Benzhydryl Chloride 90-99-3 25ML $109 2026-04-30 Buy
TCI Chemical B1078 Benzhydryl Chloride 90-99-3 500ML $896 2026-04-30 Buy
TRC C368015 Chlorodiphenylmethane 90-99-3 500g $340 2021-12-16 Buy
Product number Packaging Price Buy
125032 5g $30.5 Buy
125032 100g $296 Buy
B1078 25ML $109 Buy
B1078 500ML $896 Buy
C368015 500g $340 Buy

Chlorodiphenylmethane Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

Chlorodiphenylmethane was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives.

Application

Benzhydryl chloride is used as a pharmaceutical intermediate, such as diphenhydramine intermediate.

Preparation

Chlorodiphenylmethane was synthesized by the radical substitution reaction between diphenylmethane and chlorine gas.

Purification Methods

Diphenylmethyl chloride (benzhydryl chloride) [90-99-3] M 202.7, m 17.0o, b 140o/3mm, 1 6 7o/17mm, n 1.5960. Dry the chloride with Na2SO4 and fractionally distil it under reduced pressure. [Beilstein 5 H 590, 5 I 278, 5 II 500, 5 III 1790, 5 IV 1847.]

91-01-0
90-99-3
Synthesis of Chlorodiphenylmethane from Benzhydrol
Global( 353)Suppliers
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Henan Fengda Chemical Co., Ltd
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View Lastest Price from Chlorodiphenylmethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Chlorodiphenylmethane pictures 2025-12-01 Chlorodiphenylmethane
90-99-3
US $0.00-0.00 / kg 1kg 98% kgs Shaanxi Dideu New Materials Co. Ltd
Chlorodiphenylmethane pictures 2025-09-25 Chlorodiphenylmethane
90-99-3
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Chlorodiphenylmethane Company Standards pictures 2021-11-15 Chlorodiphenylmethane Company Standards
90-99-3
US $0.00 / KG 1KG 99% 20 Tons Qiuxian Baitai New Material Co., LTD
1,1'-(chloromethylene)bisbenzene 1,1-DIPHENYLMETHYL CHLORIDE 1,1-DIPHENYLCHLOROMETHANE BENZHYDRYL CHLORIDE CHLORODIPHENYLMETHANE DIPHENYLCHLOROMETHANE DIPHENYLMETHYL CHLORIDE ALPHA-CHLORODIPHENYLMETHANE AKOS BBS-00004295 Benzhydryl chloride, (Chlorodiphenylmethane Benzhydrylchloride,98% Benzenebis[1,1'-[chloromethylene]] Benzhydryl chloride, Diphenylchloromethane Chlorodiphenylmethane,98% ChlorodiphenylMethane, 98% 250ML Chlorodiphenylmethane 98% alpha-Chlorodiphenylmethane 1,1-Diphenylchloromethane 1,1-Diphenylmethyl Chloride Methane,chlorodiphenyl- (6CI,8CI) [Chloro(phenyl)methyl]benzene 1,1’-(chloromethylene)bis-benzen alpha-chloroditan Benzene,1,1’-(chloromethylene)bis- Methane, chlorodiphenyl- CHLORODIPHENYLMETHANE FOR SYNTHESIS TwobenzeneMethyl chloride Benzhydryl Chloride, 97+% 4-phenyl-2-(phenylmethyl)phenol 1-Chloro-2-(&alpha -chlorophenylmethyl)benzene-d5 Benzhydryl Chloride > Chlorodiphenylmethane Company Standards Chlorodiphenylmethane ISO 9001:2015 REACH (ChloroMethylene)dibenzene AI3 11230 AI311230 AI3-11230 Diphenhydramine Impurity 12 Diphenylmethane chloride 90-99-3 C6H52CHCl Building Blocks Aryl C13 to C37+ Halogenated Hydrocarbons Organic Building Blocks Building Blocks C13 to C37+ Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks Aryl Pharmaceutical Intermediates bc0001