Chlorodiphenylmethane
- CAS No.
- 90-99-3
- Chemical Name:
- Chlorodiphenylmethane
- Synonyms
- (ChloroMethylene)dibenzene;AI311230;AI3 11230;AI3-11230;AKOS BBS-00004295;alpha-chloroditan;1-Chloro-2-(αBENZHYDRYL CHLORIDE;DIPHENYLCHLOROMETHANE;CHLORODIPHENYLMETHANE
- CBNumber:
- CB9396670
- Molecular Formula:
- C13H11Cl
- Molecular Weight:
- 202.68
- MDL Number:
- MFCD00000855
- MOL File:
- 90-99-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Chlorodiphenylmethane 98% | 125032 | 5g | $30.5 |
| Chlorodiphenylmethane 98% | 125032 | 100g | $296 |
| Benzhydryl Chloride | B1078 | 25ML | $109 |
| Benzhydryl Chloride | B1078 | 500ML | $896 |
| Chlorodiphenylmethane | C368015 | 500g | $340 |
| More product size | |||
| Melting point | 15-17 °C(lit.) |
|---|---|
| Boiling point | 140 °C3 mm Hg(lit.) |
| Density | 1.14 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Soluble), Methanol (Sparingly) |
| form | Liquid |
| Specific Gravity | 1.14 |
| color | Clear colorless to yellow |
| Water Solubility | slightly soluble |
| BRN | 607925 |
| InChI | 1S/C13H11Cl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H |
| InChIKey | ZDVDCDLBOLSVGM-UHFFFAOYSA-N |
| SMILES | ClC(c1ccccc1)c2ccccc2 |
| CAS DataBase Reference | 90-99-3(CAS DataBase Reference) |
| FDA UNII | CN9N9AYV4B |
| NIST Chemistry Reference | Benzene, 1,1'-(chloromethylene)bis-(90-99-3) |
| EPA Substance Registry System | Benzene, 1,1'-(chloromethylene)bis- (90-99-3) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
| PPE | Eyeshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xi,C | |||||||||
| Risk Statements | 36/38-36/37/38-36-34 | |||||||||
| Safety Statements | 26-36-24/25-45-36/37/39-27 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29036990 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Eye Dam. 1 Skin Corr. 1B |
|||||||||
| Hazardous Substances Data | 90-99-3(Hazardous Substances Data) | |||||||||
| REACH Registrations | Active | |||||||||
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
Chlorodiphenylmethane price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 125032 | Chlorodiphenylmethane 98% | 90-99-3 | 5g | $30.5 | 2026-04-30 | Buy |
| Sigma-Aldrich | 125032 | Chlorodiphenylmethane 98% | 90-99-3 | 100g | $296 | 2026-04-30 | Buy |
| TCI Chemical | B1078 | Benzhydryl Chloride | 90-99-3 | 25ML | $109 | 2026-04-30 | Buy |
| TCI Chemical | B1078 | Benzhydryl Chloride | 90-99-3 | 500ML | $896 | 2026-04-30 | Buy |
| TRC | C368015 | Chlorodiphenylmethane | 90-99-3 | 500g | $340 | 2021-12-16 | Buy |
Chlorodiphenylmethane Chemical Properties,Uses,Production
Chemical Properties
Clear colorless to yellow liquid
Uses
Chlorodiphenylmethane was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives.
Application
Benzhydryl chloride is used as a pharmaceutical intermediate, such as diphenhydramine intermediate.
Preparation
Chlorodiphenylmethane was synthesized by the radical substitution reaction between diphenylmethane and chlorine gas.
Purification Methods
Diphenylmethyl chloride (benzhydryl chloride) [90-99-3] M 202.7, m 17.0o, b 140o/3mm, 1 6 7o/17mm, n 1.5960. Dry the chloride with Na2SO4 and fractionally distil it under reduced pressure. [Beilstein 5 H 590, 5 I 278, 5 II 500, 5 III 1790, 5 IV 1847.]
Chlorodiphenylmethane Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20124 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21588 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2988 | 55 |
| Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8615060885618 | sales@amoychem.com | China | 6369 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29794 | 58 |
| zhangjiagang vinsce bio-pharm. limited. | 86-512-58389969 | sales1@swellxin.com | CHINA | 111 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| TargetMol Chemicals Inc. | +1-781-999-5354; +17819995354 | marketing@targetmol.com | United States | 32467 | 58 |
| Hebei Miaobian Biotechnology Co., Ltd | +8617733850068 | CHINA | 967 | 58 |
View Lastest Price from Chlorodiphenylmethane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-12-01 | Chlorodiphenylmethane
90-99-3
|
US $0.00-0.00 / kg | 1kg | 98% | kgs | Shaanxi Dideu New Materials Co. Ltd | |
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2025-09-25 | Chlorodiphenylmethane
90-99-3
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
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2021-11-15 | Chlorodiphenylmethane Company Standards
90-99-3
|
US $0.00 / KG | 1KG | 99% | 20 Tons | Qiuxian Baitai New Material Co., LTD |
-

- Chlorodiphenylmethane
90-99-3
- US $0.00-0.00 / kg
- 98%
- Shaanxi Dideu New Materials Co. Ltd
-

- Chlorodiphenylmethane
90-99-3
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-

- Chlorodiphenylmethane Company Standards
90-99-3
- US $0.00 / KG
- 99%
- Qiuxian Baitai New Material Co., LTD







