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3-Chloro-2-methylpropene

Description
3-Chloro-2-methylpropene
3-Chloro-2-methylpropene structure
CAS No.
563-47-3
Chemical Name:
3-Chloro-2-methylpropene
Synonyms
Mac;NCI-C54820;3-chloroisobu;Methallylchlorid;3-chloro-2-methyl;3-CHLOROISOBUTENE;AKOS BBS-00004062;clorurodimetallile;METHALLYL CHLORIDE;2-methallylchloride
CBNumber:
CB9402043
Molecular Formula:
C4H7Cl
Formula Weight:
90.55
MOL File:
563-47-3.mol

3-Chloro-2-methylpropene Properties

Melting point:
-80 °C (lit.)
Boiling point:
71-72 °C (lit.)
Density 
0.925 g/mL at 20 °C (lit.)
vapor density 
3.12 (vs air)
vapor pressure 
102 mm Hg ( 20 °C)
refractive index 
n20/D 1.427(lit.)
Flash point:
9 °F
storage temp. 
2-8°C
solubility 
H2O: insoluble
form 
Liquid
color 
Clear
explosive limit
2.2-10.4%(V)
Water Solubility 
0.5 g/L (20 ºC)
Merck 
14,2148
BRN 
878160
CAS DataBase Reference
563-47-3(CAS DataBase Reference)
EWG's Food Scores
3-4
FDA UNII
7A9X1C3I3O
Proposition 65 List
3-Chloro-2-methylpropene
IARC
2B (Vol. 63, 115) 2018
NIST Chemistry Reference
1-Propene, 3-chloro-2-methyl-(563-47-3)
EPA Substance Registry System
3-Chloro-2-methyl-1-propene (563-47-3)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05,GHS06,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H332-H301+H331-H304-H335-H371-H225-H302+H332-H314-H317-H411
Precautionary statements  P210-P273-P280-P305+P351+P338-P310-P233-P240-P241+P242+P243-P260-P264-P270-P271-P272-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P370+P378-P391-P403+P233-P260h-P303+P361+P353-P405-P501a
Hazard Codes  F,C,N
Risk Statements  11-20/22-34-43-51/53
Safety Statements  9-16-29-36/37/39-45-61-26
RIDADR  UN 2554 3/PG 2
WGK Germany  2
RTECS  UC8050000
Autoignition Temperature 899 °F
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29032900
NFPA 704
3
2 1

3-Chloro-2-methylpropene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.05905 3-Chloro-2-methyl-1-propene for synthesis 563-47-3 100 mL $31.08 2021-03-22 Buy
Sigma-Aldrich 108030 3-Chloro-2-methyl-1-propene technical grade, 90% 563-47-3 1l $70.2 2021-03-22 Buy
Sigma-Aldrich 108030 3-Chloro-2-methyl-1-propene technical grade, 90% 563-47-3 100ml $37.1 2021-03-22 Buy
Sigma-Aldrich 8.05905 3-Chloro-2-methyl-1-propene for synthesis 563-47-3 500 mL $57.35 2021-03-22 Buy
TCI Chemical C0209 3-Chloro-2-methyl-1-propene >98.0%(GC) 563-47-3 25mL $19 2021-03-22 Buy

3-Chloro-2-methylpropene Chemical Properties,Uses,Production

Description

3-Chloro-2-methylpropene is used as an intermediate to produce carbofuran, herbicides, plastics, pharmaceuticals and other organics. It is also used as an additive in textile and perfumes. It was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate and cationic polymerization of 3-Chloro-2-methylpropene with AICI3 and AIBr3 as initiators. It is also the reactant for the synthesis of cyclobutanone.

Chemical Properties

clear liquid

Uses

In organic synthesis.

Biological Functions

MAC is a valuable index for clinical anesthesia, but it is seldom employed without taking other factors into consideration. For example, inhibiting movement in only 50% of patients is not acceptable. Consequently, if an inhalational agent were being used alone—that is, without the administration of other anesthetics or analgesic drugs—the anesthesiologist would employ a multiple of its MAC value to ensure immobility.MAC is frequently multiplied by a factor of 1.3 to achieve nearly 100% clinical efficacy. On the other hand, useful clinical results may be achieved with doses of anesthetics below MAC levels. For example, mild analgesia and amnesia often occur with doses of inhalational agents that are near 0.5 MAC. In this state, it may even be possible to communicate with patients intraoperatively, while their recall is limited.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 824, 1981 DOI: 10.1021/jo00317a041

General Description

A colorless to straw-colored liquid with a sharp penetrating odor. Less dense than water and insoluble in water. Flash point below 0°F. May be toxic by ingestion. Irritating to skin and eyes. Used to make plastics and pharmaceuticals.

Air & Water Reactions

Highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. . Insoluble in water.

Reactivity Profile

3-Chloro-2-methylpropene is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. 3-Chloro-2-methylpropene is incompatible with strong bases. 3-Chloro-2-methylpropene may react with water at elevated temperatures. .

Hazard

Irritant; poison; anesthetic; questionable carcinogen; toxic.

Health Hazard

Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.

Carcinogenicity

3-Chloro-2-methylpropene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

3-Chloro-2-methylpropene Preparation Products And Raw materials

Raw materials

Preparation Products


3-Chloro-2-methylpropene Suppliers

Global( 211)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20010 60
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29965 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5098 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
Standardpharm Co. Ltd.
86-714-3992388
overseasales1@yongstandards.com United States 14344 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58

View Lastest Price from 3-Chloro-2-methylpropene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-04-13 3-Chloro-2-methylpropene
563-47-3
US $10.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
2020-01-09 3-Chloro-2-methylpropene
563-47-3
US $0.10 / KG 1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd
2019-07-06 3-Chloro-2-methylpropene
563-47-3
US $1.00 / kg 1kg 99% Customized career henan chemical co

3-Chloro-2-methylpropene Spectrum


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