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[Bis(trifluoroacetoxy)iodo]benzene

CAS No.
2712-78-9
Chemical Name:
[Bis(trifluoroacetoxy)iodo]benzene
Synonyms
PIFA;BTI;DFAIB;Bacillus thuringiensis israelensis;[Bis(trifluoroacetox;LABOTEST-BB LT00454809;uoroacetoxy)iodo]benzene;[Bis(trifluoroacetoxy)iodo]ben;1Bis-trifluoroacetoxyiodobenzene;BIS(TRIFLUORACETOXY)- IODOBENZENE
CBNumber:
CB9419191
Molecular Formula:
C10H5F6IO4
Molecular Weight:
430.04
MDL Number:
MFCD00009672
MOL File:
2712-78-9.mol
MSDS File:
SDS
Last updated:2023-12-26 17:07:23

[Bis(trifluoroacetoxy)iodo]benzene Properties

Melting point 121-125 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form Crystalline Powder
color White to pale yellow
Water Solubility insoluble
Sensitive Moisture & Light Sensitive
BRN 764767
Stability Air and Moisture Sensitive
CAS DataBase Reference 2712-78-9(CAS DataBase Reference)
FDA UNII 659SFV27XS

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
4.10-8-9-21
Hazard Note  Irritant/Keep Cold
HazardClass  IRRITANT, KEEP COLD, LIGHT SENSITIVE
HS Code  29036990
NFPA 704
1
2 1

[Bis(trifluoroacetoxy)iodo]benzene price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 15230 [Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT) 2712-78-9 10g $91.2 2024-03-01 Buy
Sigma-Aldrich 15230 [Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT) 2712-78-9 50g $200 2024-03-01 Buy
Alfa Aesar L15141 [Bis(trifluoroacetoxy)iodo]benzene, 97% 2712-78-9 5g $45.8 2024-03-01 Buy
Alfa Aesar L15141 [Bis(trifluoroacetoxy)iodo]benzene, 97% 2712-78-9 25g $118 2024-03-01 Buy
Sigma-Aldrich 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 2712-78-9 10g $91.9 2024-03-01 Buy
Product number Packaging Price Buy
15230 10g $91.2 Buy
15230 50g $200 Buy
L15141 5g $45.8 Buy
L15141 25g $118 Buy
232130 10g $91.9 Buy

[Bis(trifluoroacetoxy)iodo]benzene Chemical Properties,Uses,Production

Chemical Properties

White to pale yellow crystalline powder

Uses

In oxidation, cyclization, dehydrogenation, and dearomatization reactions.

Uses

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Purification Methods

Crystallise the iodo compound from warm trifluoroacetic acid and dry it over NaOH pellets. Recrystallise it also from Me2CO/pet ether. Its melting point depends on the heating rate. [Spyroudis & Varvoglis Synthesis 445 1975, application: Almond et al. Org Synth 66 132 1988.]

[Bis(trifluoroacetoxy)iodo]benzene Preparation Products And Raw materials

Global( 325)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 6506 58
Henan Fengda Chemical Co., Ltd
+8613613820652 info@fdachem.com China 4685 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 14770 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21703 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3012 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29919 58
NINGBO INNO PHARMCHEM CO., LTD.
13867897135 sales@nbinno.com CHINA 925 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58

View Lastest Price from [Bis(trifluoroacetoxy)iodo]benzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[Bis(trifluoroacetoxy)iodo]benzene pictures 2024-03-19 [Bis(trifluoroacetoxy)iodo]benzene
2712-78-9
US $0.00 / kg 1kg 99% 100mt Jinan Finer Chemical Co., Ltd
[Bis(trifluoroacetoxy)iodo]benzene pictures 2024-02-23 [Bis(trifluoroacetoxy)iodo]benzene
2712-78-9
US $8.00-129.00 / g 25g 0.98 25kg Shanghai UCHEM Inc.
[Bis(trifluoroacetoxy)iodo]benzene pictures 2023-12-26 [Bis(trifluoroacetoxy)iodo]benzene
2712-78-9
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) IODINE, PHENYLBIS(TRIFLUOROACETATO)- IODOBENZENE BIS(TRIFLUOROACETATE) IODOBENZENE I,I-BIS(TRIFLUOROACETATE) BIS(TRIFLUORACETOXY)- IODOBENZENE [BIS(TRIFLUOROACETOXY)IODO]BENZENE [Bis(trifluoroacetoxy)](phenyl)iodane Iodobenzene 1,1-bis(trifluoroacetate) [Bis(trifluoroacetoxy)iodo]benzene purum, >=95.0% (AT) [Bis(trifluoroacetoxy)iodo]benzene SynonyMs Phenylbis(trifluoroacetato-O)iodine [phenyl-(2,2,2-trifluoroacetyl)oxy-3-iodanyl] 2,2,2-trifluoroacetate BTI~Iodosobenzene bis(trifluoroacetate)~Phenyliodine(III) bis(trifluoroacetate)~PIFA phenylbis(trifluoroacetato-O)iodine Bis-Trifluoroacetoxyiodobenzene99% Bis-Trifluoroacetoxyiodobenzene 99% Iodosobenzene-bis(trifluoroacetate) Phenyliodine(III)bis(trifluoroacetate) Bis(trifluoroacetoxy)iodoübenzene, 97% BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA [Bis(trifluoroacetoxy)iodo(III)]benzene [Di(trifluoroacetoxy)iodo(III)]benzene Bis(trifluoroacetic acid)phenyliodine(III) salt Phenylbis(trifluoroacetyloxy) iodine(III) Iodine, phenylbis(trifluoroacetato-.kappa.O)- bis(I,I-trifluoroacetoxy)iodobenzene [Bis(trifluoroacetoxy)iodo]benzene,98% 1Bis-trifluoroacetoxyiodobenzene [Bis(trifluoroethoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene,BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA [Bis(trifluoroacetox [Bis(trifluoroacetoxy)iodo]benzene, 98% 10GR [Bis(trifluoroacetoxy)iodo]benzene, 98% 50GR LABOTEST-BB LT00454809 BIS(TRIFLUOROACETOXY)IODOBENZENE FOR SYN [Bis(trifluoroacetoxy)iodo]ben [phenyl-(2,2,2-trifluoroacetyl)oxy-λ3-iodanyl] 2,2,2-trifluoroacetate uoroacetoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene, 98%, for synthesis [Bis(trifluoroacetoxy)iodo]benzene > Iodine, phenylbis(2,2,2-trifluoroacetato-κO)- [Bis(trifluoroacetoxy)iodo]benzene ISO 9001:2015 REACH [phenyl-(2,2,2-trifluoroacetyl)oxy- BTI DFAIB Bacillus thuringiensis israelensis PIFA 2712-78-9 C10H5F6IO4 C10H5O4F6I CF3CO22IC6H5 C10F6H5I1O4 C10H9F6IO2 C10H3F6IO4 Oxidation Synthetic Reagents Hypervalent Iodine Carbazoles