Fenarimol | 60168-88-9

Fenarimol Properties

Melting point	117-119°C
Boiling point	0°C
Density	1.3886 (rough estimate)
vapor pressure	6.5 x 10^-5 Pa at 25 °C
refractive index	1.5490 (estimate)
Flash point	0°C
storage temp.	0-6°C
solubility	Chloroform (Slightly), Methanol (Slightly)
pka	2.58
Water Solubility	14.6 mg l^-1 (pH 3), 13.7 mg l^-1 (pH 7), 13.8 mg l^-1 (pH 10) at 25 °C
color	Off-White to Light Yellow
Merck	13,3986
BRN	5972869
CAS DataBase Reference	60168-88-9(CAS DataBase Reference)
EWG's Food Scores	4
FDA UNII	O088GU930Q
NIST Chemistry Reference	5-Pyrimidinemethanol, «alpha»-(2-chlorophenyl)-«alpha»-(4-chlorophenyl)-(60168-88-9)
Pesticides Freedom of Information Act (FOIA)	Fenarimol
EPA Substance Registry System	Fenarimol (60168-88-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS08,GHS09
Signal word	Warning
Hazard statements	H361fd-H362-H411
Precautionary statements	P202-P260-P263-P264-P273-P308+P313
Hazard Codes	Xn;N,N,Xn
Risk Statements	51/53-62-63-64
Safety Statements	36/37-61
RIDADR	UN 3017/3077
WGK Germany	2
RTECS	UV9279400
Toxicity	LD50 in mice, rats (mg/kg): 4500, 2500 orally (Beraud)

Fenarimol price More Price(8)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	45484	Fenarimol PESTANAL	60168-88-9	250mg	$175	2024-03-01	Buy
TRC	F245735	Fenarimol	60168-88-9	100mg	$295	2021-12-16	Buy
TRC	F245735	Fenarimol	60168-88-9	250mg	$605	2021-12-16	Buy
American Custom Chemicals Corporation	AGR0000077	FENARIMOL 95.00%	60168-88-9	100MG	$650	2021-12-16	Buy
American Custom Chemicals Corporation	AGR0000077	FENARIMOL 95.00%	60168-88-9	5G	$10900	2021-12-16	Buy

Product number	Packaging	Price	Buy
45484	250mg	$175	Buy
F245735	100mg	$295	Buy
F245735	250mg	$605	Buy
AGR0000077	100MG	$650	Buy
AGR0000077	5G	$10900	Buy

Fenarimol Chemical Properties,Uses,Production

Uses

Fenarimol is a pyrimidine based fungicide which acts against rusts, blackspot and mildew fungi and it works by inhibiting the fungus’s biosynthesis of important steroid molecules.

Uses

Fenarimol is a broad spectrum pyrimidine carbinol fungicide with protective, curative and eradicative activities against powdery mildew (Erysiphe spp., Pudusphaera leucutricha, Uncinula necatur, Sphaerutheca spp., Leveillula spp.) and scab (Venturia spp.) in many crops. It also controls powdery mildew (Sphaerutheca pannusa) in ornamentals and Fusarium patch (Micruduccium niuale), Take-all patch (Laefisaria fuciformis), Dollar spot (Sderutina humeucavpa) and red thread (Gaeumannumyces graminis) in turf and amenity grasses.

Uses

Plant fungicide.

Definition

ChEBI: (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol is a member of the class of pyrimidines that is pyrimidin-5-ylmethanol in which one of the hydrogens attached to the carbon bearing the hydroxy group is replaced by a 2-chlorophenyl group while the other is replaced by a 4-chlorophenyl group. It is a tertiary alcohol, a member of monochlorobenzenes and a member of pyrimidines.

General Description

Pure white crystalline solid. Used as a fungicide. Irritates skin and mucous membranes.

Reactivity Profile

Fenarimol produces toxic gases when heated to decomposition.

Safety Profile

Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland NOx.

Metabolic pathway

The primary dissipation mechanism of fenarimol in the environment involves photolysis on plants/soil surfaces and water. More than 80 photoproducts have been observed, resulting from the reduction of the pyrimidine ring, hydrolysis, ring migration and cleavage of the phenyl and pyrimidine ring moieties. Under laboratory conditions in the dark, fenarimol is relatively persistent in soil, but a more rapid dissipation was observed under field conditions with DT₅₀ values of 18-140 days, attributed to photolysis of fenarimol on the soil surface. Fenarimol degrades in/on plant foliage/fruit surfaces mainly by photochemical processes. In animals, fenarimol is metabolised extensively to yield hydroxylated, cleavage and dechlorination products. The primary photolytic and metabolic pathways of fenarimol are presented in Schemes 1 and 2.

Degradation

Fenarimol(1) is stable in sterile buffered water in the dark at pH 3,6 and 9 at 25 °C, 37 °C and 52 °C for 28 days (Decker and Sullivan, 1975) but is readily degraded via photolysis. The photolytic DT₅₀ in distilled water under natural sunlight and clear sky conditions at 40°N in mid-summer was approximately 12 hours (Day, 1975). The primary aqueous photolysis reaction involved the migration of the pyrimidine ring to one of the chlorophenyl rings, followed by the oxidation of the carbinol moiety to the corresponding ketone to yield 4-chloro-2-(5-pyrimidyl)-2'-chlorobenzophenone (2).
Fenarimol was extensively photodegraded on solid surfaces. More than 80 photodegradation products were formed when fenarimol was exposed to sunlight on a stainless steel surface for up to 200 hours (Althaus and Bewley, 1978a). All photoproducts were formed at very low levels (less than 3% each) and 14 were identified. An abbreviated photogradation pathway of fenarimol is presented in Scheme 1. These products were generated from the following reactions: the migration of the pyrimidine ring to one of the chlorophenyl rings, followed by the oxidation of the carbinol moiety to yield compound 2; cleavage of either one of the chlorophenyl (to yield 3,4) or pyrimidine rings (5,6); aryl hydroxylation of one of the chlorophenyl rings (7); carbinol dehydroxylation reaction to yield 8 and a bridged fluorene product (9) from the dechlorination reaction. Various cleavage products (carboxylic acids) derived from the chlorophenyl (10-13) and the pyrimidine moieties (14) were also observed.

Fenarimol synthesis

Synthesis of Fenarimol from Methanone, (4-chlorophenyl)-5-pyriMidinyl- and 2-Bromochlorobenzene

Fenarimol Preparation Products And Raw materials

Raw materials

n-Butyllithium 2-Chlorobenzoyl chloride Methanone, (4-chlorophenyl)-5-pyriMidinyl- 2,4'-Dichlorobenzophenone 5-Bromopyrimidine

2-Bromochlorobenzene

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Preparation Products

Fenarimol Suppliers

Global( 106)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	19892	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58
Hebei Zhanyao Biotechnology Co. Ltd	15369953316 +8615369953316	admin@zhanyaobio.com	China	2136	58
Dideu Industries Group Limited	+86-29-89586680 +86-15129568250	1026@dideu.com	China	29474	58
Henan Alfa Chemical Co., Ltd	+8618339805032	alfa4@alfachem.cn	China	12755	58
LEAP CHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	24738	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
Hubei Jusheng Technology Co.,Ltd.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
TargetMol Chemicals Inc.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Hebei Zhanyao Biotechnology Co. Ltd	58
Dideu Industries Group Limited	58
Henan Alfa Chemical Co., Ltd	58
LEAP CHEM CO., LTD.	58

View Lastest Price from Fenarimol manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-02-17	Fenarimol 60168-88-9	US $1.10 / g	1g	99.00%	100 Tons	Dideu Industries Group Limited
2021-10-15	2-Chloronicotinamide 60168-88-9	US $10.00 / KG	1KG	99%	20 Tons	Hebei Zhanyao Biotechnology Co. Ltd
2020-01-05	Fenarimol 60168-88-9	US $1.00 / KG	1KG	95-99%	1ton	Career Henan Chemical Co

Fenarimol
60168-88-9
US $1.10 / g
99.00%
Dideu Industries Group Limited

2-Chloronicotinamide
60168-88-9
US $10.00 / KG
99%
Hebei Zhanyao Biotechnology Co. Ltd

Fenarimol
60168-88-9
US $1.00 / KG
95-99%
Career Henan Chemical Co

60168-88-9(Fenarimol)Related Search:

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Chlorodiphenylphosphine 5-Pyrimidinemethanol Ancymidol

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(2-Chlorophenyl)(4-chlorophenyl)5-pyrimidinylmethanol (2-Chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidinemethanol .alpha.-(2-chlorophenyl)-.alpha.-(4-chlorophenyl)-5-Pyrimidinemethanol 2,4’-dichloro-alpha-(pyrimidin-5-yl)benzhydrylalcohol 5-Pyrimidinemethanol, alpha-(2-chlorophenyl)-alpha-(4-chlorophenyl)- 2，4-Dichloro-α-(pyrimidin-5-y1)diphenylmethanol 2,4'-DICHLORO-A-(PYRIMIDIN-5-YL)DIPHENYLMETHANOL 2,4'-dichloro-alpha-(5-pyrimidinyl)benzhydryl alcohol EL-222 FENARIMOL BLOC(R) A-(2-CHLOROPHENYL)-A-(4-CHLOROPHENYL)-5-(PYRIMIDINEMETHANOL) RUBIGAN RUBIGAN(R) (±)2-(2-chlorophenyl)-2-(4-chlorophenyl)-5-pyrimidinemethanol (±)2,4-dichloro-α-(pyrimidin-5-yl)benzhydryl alcohol FENARIMOL, 100MG, NEAT FENARIMOL PESTANAL (2,4'-DICHLORO- A-(PY fenarimol (bsi,iso,ansi) RUBIGAN-4 RUBIGAN12EC .alpha.-(2-chlorophenyl)-.alpha.-(4-chlorophenyl)-5-Pyrimidinemethanol .alpha.-(2-Chlorophenyl)-.alpha.-(4-chlorophenyl)-5-pyrimidinemethanol fenarimol (ISO) 2,4'-dichloro-α-(pyrimidin-5-yl)benzhydryl alcohol alpha-(2-chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidinemethano alpha-(2-Chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidinemethanol Bloc Rimidin 2，4'-dichloro-α-(pyrimidin-5-yl) dipehenylmethanol (2-Chlorophenyl)-(4-chlorophenyl)-pyrimidin-5-yl-methanol alpha-(2-Chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidineme α-(2-Chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol α-(2-Chlorophenyl)α-(4-chlorophenyl)-5-pyrimidinemethanol Fenarimol 100mg [60168-88-9] Fenarimol Standard Fenarimol Solution, 1000ppm Bloc @100 μg/mL in MeOH Fenarimol@1000 μg/mL in Acetone 5-Pyrimidinemethanol, α-(2-chlorophenyl)-α-(4-chlorophenyl)- Fenarimol ISO 9001：2015 REACH Pioglitazone Impurity 33 60168-88-9 C17H12Cl2NO FA - FLPesticides Alpha sort E-GAlphabetic F Fungicides Pesticides&Metabolites Pyrimidines Alphabetic