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COBALT CARBONYL

Description Reaction Sources
COBALT CARBONYL
COBALT CARBONYL
CAS No.
10210-68-1
Chemical Name:
COBALT CARBONYL
Synonyms
Co2(CO)8;cobaltcarbonyle;COBALT CARBONYL;dicobaltcarbonyl;cobaltoctacarbonyl;carbonyl,tetra-cobal;OCTACARBONYLDICOBALT;cobaltcarbonyl(asco);COBALT TETRACARBONYL;DICOBALT OCTACARBONYL
CBNumber:
CB9432426
Molecular Formula:
C8Co2O8+4
Formula Weight:
341.95
MOL File:
10210-68-1.mol

COBALT CARBONYL Properties

Melting point:
51-52 °C
Boiling point:
52°C
Density 
1.81
Flash point:
-13 °C
storage temp. 
2-8°C
form 
crystal
color 
dark orange
Water Solubility 
Insoluble in water. Soluble in alcohol, ether and carbon disulfideSoluble in ether, naphtha and carbon disulfide. Slightly soluble in alcohol. Insoluble in water.
Sensitive 
Air Sensitive
Merck 
13,3112
CAS DataBase Reference
10210-68-1(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,Xn,T+
Risk Statements  11-22-40-43-48/20-52/53-62-26
Safety Statements  36/37-61-45-28
RIDADR  UN 3190 4.2/PG 2
WGK Germany  3
RTECS  GG0300000
23-25
TSCA  No
HazardClass  4.1
PackingGroup  II
Toxicity LD50 in mice, rats (mg/kg): 377.7, 753.8 by gavage (Spiridonova, Shabalina)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
P210, P240,P241, P280, P370+P378
H251 Self-heating; may catch fire Self-heating substances and mixtures Category 1 Danger
H252 Self-heating in large quantities; may catch fire Self-heating substances and mixtures Category 2 Warning P235+P410, P280, P407, P413, P420
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

COBALT CARBONYL price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 60811 Cobalt carbonyl 96% 10210-68-1 5g $156 2018-11-13 Buy
Sigma-Aldrich 60811 Cobalt carbonyl 96% 10210-68-1 25g $488 2018-11-13 Buy
TCI Chemical D3213 Dicobalt Octacarbonyl (stabilized with 1-5% Hexane) 10210-68-1 5g $85 2018-11-22 Buy
TCI Chemical D3213 Dicobalt Octacarbonyl (stabilized with 1-5% Hexane) 10210-68-1 25g $260 2018-11-22 Buy
Alfa Aesar 013060 Octacarbonyldicobalt, stab. with 1-5% hexane 10210-68-1 25g $152 2018-11-16 Buy

COBALT CARBONYL Chemical Properties,Uses,Production

Description

Cobalt carbonyl (known as dicobalt octocarbonyl) is a versatile reagent and catalyst in organometallic chemistry and organic synthesis. It has catalytic applications in various chemical reactions such as hydroformylation of unsaturated compound, homogeneous hydrogenation of aromatic hydrocarbons, hydrosilation of alkenes, reactions of disulfides such as carbonylation to thio-esters and desulfurization to sulfides, hydroformylation as well as the conversion of alkenes into aldehydes. It can also promote both the Pauson-Khand reactions and Nicholas reaction.

Reaction

  1. Reagent for the Pauson-Khand conversion of an olefin, an alkyne and carbon monoxide into a cyclopentenone.
  2. Precatalyst in combination with triphenylphosphite for the cataytic Pauson-Khand reaction.
  3. Catalyzes the rearrangement of 1-alkynylcyclopropanols to cyclopentenones.
  4. Catalyzes the conversion of aziridines to β-lactams.
  5. Catalyzes the conversion of diallylanilines and aryliminies to quinolines.
  6. Reagent for the selective cleavage of benzyl ethers.
  7. Domino Nicholas and Pauson-Khand process induced by nitroarene reduction.

Sources

Adkins, Homer., and G. Krsek. JACS 71.9(1949):3051-3055.
Feder, Harold M., and J. Halpern. Cheminform 7.7(1976):no-no.
Seitz, Friedrich, and M. S. Wrighton. Angewandte Chemie International Edition 27.2(1988):289-291.
Antebi, Shlomo, and H. Alper. Tetrahedron Letters 16.38(1985):no-no.
Krafft, Marie E., L. V. R. Boñaga, and C. Hirosawa. Cheminform 32.37(2001):no-no.
https://en.wikipedia.org/wiki/Dicobalt_octacarbonyl

Chemical Properties

red-orange to dark red crystals or flakes

Chemical Properties

Cobalt carbonyl is a pyrophoric (spontaneously flammable in air), red-orange (when pure) to dark-brown crystalline solid.

Uses

Cobalt octacarbonyl is used as a catalyst in the Oxo process. It also is used as a catalyst for hydrogenation, isomerization, hydrosilation and polymerization reactions. The compound is also a source of producing pure cobalt metal and its purified salts.

Hazard

Toxic by ingestion and inhalation.

Safety Profile

Poison by inhalation and intraperitoneal routes. Questionable carcinogen. Decomposes in air to form a product that ignites spontaneously in air. "hen heated to decomposition it emits acrid smoke and fumes. See also CARBONYLS and COBALT COMPOUNDS.

Potential Exposure

This material is used as a catalyst for a number of reactions. It is also used in antiknock gasoline and for high-purity cobalt salts.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek Medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a Medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy

Shipping

UN3124 Toxic solids, self-heating, n.o.s., Hazard Class: 6.1; 6.1-Poisonous materials, 4.2-Spontaneously combustible material. Technical Name Required. UN3190 Self-heating solid, inorganic, Hazard Class: 4.2; Labels: 4.2-Spontaneously combustible material, Technical Name Required. UN1325 Flammable solid, organic, n.o.s. Hazard Class: 4.1; Labels: 4.1-Flammable solid

Purification Methods

It forms orange-brown crystals on recrystallisation from n-hexane under a carbon monoxide atmosphere [Ojima et al. J Am Chem Soc 109 7714 1987; see also Hileman in Preparative Inorganic Reactions, Ed. Jolly, Vol 1 p 101 1987].

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Decomposes on exposure to air or heat (@ ~52°C) producing toxic fumes of cobalt and oxides of carbon

COBALT CARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products


COBALT CARBONYL Suppliers

Global( 84)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
City Chemical LLC
2039322489
203.937.8400 sales@citychemical.com United States 101 58
BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807
010-87653215;0757-86311057;021-55236763 sales@hwrkchemical.com China 14616 55
Shanghai Amquar Biological Technology Co., Ltd. 021-51088985
021-20423591 sale@amquar.com China 89 55
Conier Chem & Phamra Limited 86-023-62922305 18523575427
86-023-62912751 sales@conier.com China 104 56
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40399 62
INTATRADE GmbH +49 3493/605464
+49 3493/605470 sales@intatrade.de Germany 3587 66
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30308 84

View Lastest Price from COBALT CARBONYL manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-15 COBALT CARBONYL
10210-68-1
US $8.00 / kg 1kg 99% 100MT career henan chemical co

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