2-Chlorobenzaldehyde
- CAS No.
- 89-98-5
- Chemical Name:
- 2-Chlorobenzaldehyde
- Synonyms
- ORTHO CHLORO BENZALDEHYDE;OCBA;O-CHLOROBENZALDEHYDE;OCAD;2-Clorobenzaldeide;usafm-7;USAF m-7;NSC 15347;AKOS BBS-00003191;2-Chlorbenzaldehyd
- CBNumber:
- CB9469909
- Molecular Formula:
- C7H5ClO
- Molecular Weight:
- 140.57
- MDL Number:
- MFCD00003304
- MOL File:
- 89-98-5.mol
- MSDS File:
- SDS
| Melting point | 9-11 °C (lit.) |
|---|---|
| Boiling point | 209-215 °C (lit.) |
| Density | 1.248 g/mL at 25 °C (lit.) |
| vapor density | 4.84 (vs air) |
| vapor pressure | 1.27 mm Hg ( 50 °C) |
| refractive index |
n |
| Flash point | 190 °F |
| storage temp. | Store in RT |
| solubility | 1.8g/l |
| form | Liquid |
| color | Clear colorless to light yellow |
| PH | 2.9 (H2O)(saturated aqueous solution) |
| Water Solubility | 0.1-0.5 g/100 mL at 24 ºC |
| Sensitive | Air Sensitive |
| BRN | 385877 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases, iron, strong reducing agents. Moisture and light-sensitive. |
| LogP | 2.44 at 25℃ |
| CAS DataBase Reference | 89-98-5(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | QHR24X1LXK |
| NIST Chemistry Reference | Benzaldehyde, 2-chloro-(89-98-5) |
| EPA Substance Registry System | 2-Chlorobenzaldehyde (89-98-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-45 | |||||||||
| RIDADR | UN 3265 8/PG 3 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | CU5075000 | |||||||||
| F | 8-9-23 | |||||||||
| Autoignition Temperature | 746 °F | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29130000 | |||||||||
| Toxicity | LD50 orally in Rabbit: 2160 mg/kg | |||||||||
| NFPA 704 |
|
2-Chlorobenzaldehyde price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.20276 | 2-Chlorobenzaldehyde for synthesis | 89-98-5 | 250ML | $42.5 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20276 | 2-Chlorobenzaldehyde for synthesis | 89-98-5 | 1L | $116 | 2024-03-01 | Buy |
| Sigma-Aldrich | 124974 | 2-Chlorobenzaldehyde 99% | 89-98-5 | 100g | $65.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 124974 | 2-Chlorobenzaldehyde 99% | 89-98-5 | 500g | $73.9 | 2024-03-01 | Buy |
| TCI Chemical | C0561 | 2-Chlorobenzaldehyde >99.0%(GC) | 89-98-5 | 25g | $16 | 2024-03-01 | Buy |
2-Chlorobenzaldehyde Chemical Properties,Uses,Production
Chemical Properties
2-Chlorobenzaldehyde is a colorless to yellowish liquid with a penetrating odor. Insoluble in water, soluble in benzene, alcohol and ether. 2-Chlorobenzaldehyde is considerably more resistant to oxidation than benzaldehyde. When it is heated with sodium sulfite solution under pressure, benzaldehyde-2-sulfonic acid forms.
Uses
2-Chlorobenzaldehyde can be used to make alcohols, acids, and dyes; used in the rubber, tanning, and paper industries; used as an intermediate for optical brighteners, agricultural chemicals, and pharmaceuticals.It can also be used to prepare triphenyl methane and related dyes, organic intermediate.
Uses
2-Chlorobenzaldehyde has been used in generation of small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and thioureas.
Preparation
2-Chlorobenzaldehyde is produced mainly by chlorination of 2-chlorotoluene to form 2-chlorobenzal chloride, which is then subjected to acid hydrolysis. Metal salts, such as iron(III) chloride, are used as catalysts. The hydrolysis can also be accomplished using formic acid without a catalyst.
2-Chlorobenzaldehyde can also be produced by oxidation of 2-chlorobenzyl chloride with N-oxides of tertiary amines or with dilute nitric acid.
https://pubchem.ncbi.nlm.nih.gov/compound/2-Chlorobenzaldehyde
Application
2-Chlorobenzaldehyde is used acid zinc plating brightener, also be used for organic synthesis, agricultural pesticide and pharmaceutical industries. It is used to synthesize the acaricides clofentezine and flutenzine. 2-Chlorobenzaldehyde undergoes alkynylation with phenylacetylene in the presence of catalytic ligands and dimethylzinc at 0°C to form binaphthyl-derived amino alcohols.
Synthesis Reference(s)
Tetrahedron Letters, 34, p. 8037, 1993 DOI: 10.1016/S0040-4039(00)61444-2
General Description
2-chlorobenzaldehyde is a clear colorless to yellowish liquid. (NTP, 1992)
Air & Water Reactions
2-Chlorobenzaldehyde is moisture and light sensitive. Slightly water soluble.
Reactivity Profile
2-Chlorobenzaldehyde reacts with iron and strong oxidizers, strong bases and strong reducing agents.
Health Hazard
Symptoms of exposure to 2-Chlorobenzaldehyde may include skin, eye and upper respiratory tract irritation. This compound may cause skin, eye and respiratory tract irritation. When heated to decomposition it emits toxic fumes.
Fire Hazard
2-Chlorobenzaldehyde is combustible.
Safety Profile
Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of Cl-. See also ALDEHYDES and CHLORIDES.
Purification Methods
Wash it with 10% Na2CO3 solution, then fractionally distil it in the presence of a small amount of catechol as stabiliser. [Beilstein 7 H 233, 7 IV 561.]
2-Chlorobenzaldehyde Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Tangshan Moneide Trading Co., Ltd. | +86-315-8309571 +8615633399667 | sales@moneidechem.com | China | 568 | 58 |
| Wuhan Pinestone Fortune International Trading Co., Ltd. | +86-027-85615902 +86-13971435335 | imp.exp8@fengfan.net | China | 29 | 58 |
| ZHEJIANG ESTCHEM CO.,LTD | 15957180504 | sales@zjestchem.com | China | 193 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12457 | 58 |
| Dorne Chemical Technology co. LTD | +86-13583358881 +86-18560316533 | Ethan@dornechem.com | China | 294 | 58 |
| Firsky International Trade (Wuhan) Co., Ltd | +8615387054039 | admin@firsky-cn.com | China | 436 | 58 |
| Henan Bao Enluo International TradeCo.，LTD | +86-17331933971 +86-17331933971 | deasea125996@gmail.com | China | 2503 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7613 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
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View Lastest Price from 2-Chlorobenzaldehyde manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-24 | 2-Chlorobenzaldehyde
89-98-5
|
US $1.00 / g | 1g | 99% | 1000kg | Dorne Chemical Technology co. LTD | |
 |
2024-04-24 | 2-Chlorobenzaldehyde
89-98-5
|
US $79.00-65.00 / kilograms | 1kilograms | 99% | 100tons | Hebei Dangtong Import and export Co LTD | |
 |
2024-04-24 | 2-Chlorobenzaldehyde
89-98-5
|
US $0.00 / KG | 1KG | 99% | 500mt/year | Jinan Finer Chemical Co., Ltd |
-
- 2-Chlorobenzaldehyde
89-98-5
- US $1.00 / g
- 99%
- Dorne Chemical Technology co. LTD
-
- 2-Chlorobenzaldehyde
89-98-5
- US $79.00-65.00 / kilograms
- 99%
- Hebei Dangtong Import and export Co LTD
-
- 2-Chlorobenzaldehyde
89-98-5
- US $0.00 / KG
- 99%
- Jinan Finer Chemical Co., Ltd
89-98-5(2-Chlorobenzaldehyde )Related Search:
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