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Diethyl sulfate

Diethyl sulfate
Diethyl sulfate structure
CAS No.
64-67-5
Chemical Name:
Diethyl sulfate
Synonyms
DS;DHYS;Ethylsulpate;Diethylsulfat;ETHYL SULFATE;Diaethylsulfat;DIETHYL SULFATE;DIETHYL SULPHATE;Two ethyl sulfate;sulfatediethylique
CBNumber:
CB9483493
Molecular Formula:
C4H10O4S
Formula Weight:
154.18
MOL File:
64-67-5.mol

Diethyl sulfate Properties

Melting point:
-24 °C
Boiling point:
208 °C(lit.)
Density 
1.177 g/mL at 25 °C(lit.)
vapor density 
5.3 (vs air)
vapor pressure 
<0.01 mm Hg ( 20 °C)
refractive index 
n20/D 1.399(lit.)
Flash point:
173 °F
storage temp. 
Refrigerator (+4°C)
form 
Liquid
color 
Clear
Water Solubility 
5 g/L (20 ºC)
Merck 
14,3130
BRN 
1209714
Stability:
Moisture sensitive. May react violently with oxidizing agents.
CAS DataBase Reference
64-67-5(CAS DataBase Reference)
NIST Chemistry Reference
Sulfuric acid, diethyl ester(64-67-5)
EPA Substance Registry System
Sulfuric acid, diethyl ester(64-67-5)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T
Risk Statements  45-46-20/21/22-34
Safety Statements  53-45
RIDADR  UN 1594 6.1/PG 2
WGK Germany  3
RTECS  WS7875000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29209090
Hazardous Substances Data 64-67-5(Hazardous Substances Data)
Toxicity LD50 orally in rats: 0.88 g/kg (Smyth)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
Precautionary statements:
P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.

NFPA 704

Diamond Hazard Value Description
1
1
Health  
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   1 Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
Special  

(NFPA, 2010)

Diethyl sulfate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D100706 Diethyl sulfate 98% 64-67-5 1kg $44.7 2018-11-13 Buy
Sigma-Aldrich D100706 Diethyl sulfate 98% 64-67-5 2kg $87.2 2018-11-13 Buy
TCI Chemical D0525 Diethyl Sulfate >98.0%(GC) 64-67-5 25mL $14 2018-11-22 Buy
TCI Chemical D0525 Diethyl Sulfate >98.0%(GC) 64-67-5 500mL $23 2018-11-22 Buy
Alfa Aesar L14291 Diethyl sulfate, 98% 64-67-5 500ml $37.5 2018-11-15 Buy

Diethyl sulfate Chemical Properties,Uses,Production

Chemical Properties

colourless oily liquid

Uses

Chiefly as an ethylating agent; as an accelerator in the sulfation of ethylene; in some sulfonations.

General Description

A clear colorless liquid with a peppermint odor. Burns, though may be difficult to ignite. Corrosive to metals and tissue.

Air & Water Reactions

Highly flammable. Slowly reacts with water to form ethyl alcohol, a flammable liquid, and ethyl sulfate, with eventual conversion to sulfuric acid.

Reactivity Profile

The presence of moisture in a metal container of Diethyl sulfate caused the formation of sulfuric acid which reacts with the metal to release hydrogen which pressurized and exploded the container [Chem. Abst. 28:2908(1934)].

Health Hazard

May be fatal if inhaled, swallowed or absorbed through skin. Inhalation causes nausea and vomiting. Causes burns to skin and eyes. Ingestion may cause nausea, vomiting abdominal pain and collapse.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by inhalation and subcutaneous routes. Moderately toxic by ingestion and sktn contact. A severe skin irritant. An experimental teratogen. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. Moisture causes liberation of H2SO4. Violent reaction with potassium tert-butoxide. Reacts violently with 3,8-dnitro-6-phenylphenanthridine + water. Reaction with iron + water forms explosive hydrogen gas. To fight fire, use alcohol foam, H2O foam, CO2, dry chemicals. When heated to decomposition it emits toxic fumes of SOx. See also SULFATES.

Purification Methods

Wash the ester with aqueous 3% Na2CO3 (to remove acidic material), then distilled water, dry (CaCl2), filter and distil it in a vacuum. It is an ethylating agent and blisters the skin. [Beilstein 1 IV 1236.]

Diethyl sulfate Preparation Products And Raw materials

Raw materials

Preparation Products


Diethyl sulfate Suppliers

Global( 157)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20516 58
Dalian Idery Biotechnology Co., Ltd. 0411-62696576/0411-66160116/15141125520
0411-66160116 dlidery@yeah.net China 89 58
Jinan Century Tongda Chemical Co., Ltd. 13370556116 0531-58051019
3350933950@qq.com China 50 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62
New Energy Chemicals 0515-82159099,0515-82159098,0515-82159088
sales@njuchem.com China 393 65
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30168 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24560 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 3395 62

View Lastest Price from Diethyl sulfate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-19 Diethyl sulfate
64-67-5
US $1.00 / kg 1kg 99% Customized career henan chemical co

Diethyl sulfate Spectrum


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