2-(Perfluorobutyl)ethyl acrylate
- CAS No.
- 52591-27-2
- Chemical Name:
- 2-(Perfluorobutyl)ethyl acrylate
- Synonyms
- TEAc-4;DAIKIN R-1420;Perfluorobutylethyl acrylate;2-(Perfluorobutyl)ethyl acrylate;1H,1H,2H,2H-Nonafluorohexyl acrylate;1H,1H,2H,2H-Perfluorohexyl acrylate 97%;3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate;3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate;Acrylic acid 2-(nonafluorobutyl)ethyl ester;Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
- CBNumber:
- CB9485109
- Molecular Formula:
- C9H7F9O2
- Molecular Weight:
- 318.14
- MDL Number:
- MFCD00236104
- MOL File:
- 52591-27-2.mol
| Boiling point | 164 °C |
|---|---|
| Density | 1.414 |
| refractive index | 1.310 |
| Flash point | 52 °C |
| storage temp. | Store at 2-8 ℃ |
| solubility | Chloroform (Soluble), Ethyl Acetate (Slightly) |
| form | clear liquid |
| color | Colorless to Light yellow |
| Specific Gravity | 1.440 |
| EPA Substance Registry System | 1,1,2,2-Tetrahydroperfluorohexyl acrylate (52591-27-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P280 | |||||||||
| RIDADR | UN 3272 3/PG III | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2916120090 | |||||||||
| NFPA 704 |
|
2-(Perfluorobutyl)ethyl acrylate price More Price(13)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | N1107 | 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC) >98.0%(GC) | 52591-27-2 | 5g | $48 | 2024-03-01 | Buy |
| TCI Chemical | N1107 | 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC) >98.0%(GC) | 52591-27-2 | 25g | $139 | 2024-03-01 | Buy |
| TCI Chemical | N0977 | 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ) >98.0%(GC) | 52591-27-2 | 5g | $39 | 2021-12-16 | Buy |
| Apolloscientific | PC5906D | 3,3,4,4,5,5,6,6,6-Nonafluorohex-1ylacrylate 97% | 52591-27-2 | 5g | $42 | 2021-12-16 | Buy |
| SynQuest Laboratories | 2324-3-Y3 | 1H,1H,2H,2H-Perfluorohexyl acrylate 97% | 52591-27-2 | 25g | $100 | 2021-12-16 | Buy |
2-(Perfluorobutyl)ethyl acrylate Chemical Properties,Uses,Production
Uses
2-(Perfluorobutyl)ethyl Acrylate can be used as an acrylic resin surface modifier with high water repellency and oil repellency for coating agents. It can also be used in a super concentrated emulsion method to prepare a solid sheet polycarboxylic acid water reducing agent.
Application
2-(Perfluorobutyl)ethyl acrylate has been used in a wide range of scientific research applications. It has been used to create polymers for biomedical applications, such as drug delivery systems and tissue engineering scaffolds. It has also been used to create polymers for industrial applications, such as coatings and adhesives. In addition, it has been used to create polymers for energy applications, such as fuel cells and solar cells.
Synthesis
1H,1H,2H,2H-nonafluoro-1-hexanol (52.8 g) as fluoro alcohol and triethylamine (50 g) were dissolved in 500 ml of tetrahydrofuran. A solution of 18.1 g of acryloyl chloride as acid chloride in 100 ml of tetrahydrofuran was dropped in this solution over 2 hours while the mixture was being cooled in ice and stirred. After the completion of the dropping, the resulting white precipitate was filtrated and tetrahydrofuran and triethylamine were removed from the filtrate using a rotary evaporator. NMR measurement revealed that the resulting compound was 1H,1H,2H,2H-nonafluorohexyl acrylate.
Research
Since the bioaccumulation of the degradation products of fluoropolymer with a long Rf side chain (C ≥ 8) has a potential environmental risk, it is necessary to design fluoropolymer coating with a short Rf side chain. Honda et al. studied the effect of α-substituent on the wetting behavior and molecular motion at the surfaces of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C4], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C4], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C4], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C4] films. In the case of PFA-Cy with long Rf groups [y ≥ 8], the mobility of the side chains is low at room temperature because of the crystallization of the Rf groups at the surface region[1].
References
[1] Koji Honda . "Effect of α-substituents on molecular motion and wetting behaviors of poly(fluoroalkyl acrylate) thin films with short fluoroalkyl side chains." Polymer 55 24 (2014): Pages 6303-6308.
2-(Perfluorobutyl)ethyl acrylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Tianjin Huiren Chemtech Co., Ltd | +86-86-22-23707858 +86-86-13672008665 | huirentech@foxmail.com | China | 169 | 58 |
| WEIFANG OUCHEM TRADE CO.,LTD. | +86-18506360988 +86-18506360988 | wtaili@ouchem.cn | China | 44 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| BEYOND INDUSTRIES (CHINA) LIMITED | +86-21-52699951; +8613917686115 | sales@beyondindustriesgroup.com | China | 699 | 58 |
View Lastest Price from 2-(Perfluorobutyl)ethyl acrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-01-21 | 2-(Perfluorobutyl)ethyl acrylate
52591-27-2
|
US $0.00-0.00 / kg | 0.1kg | 98% Min. | 2000kg | WEIFANG OUCHEM TRADE CO.,LTD. | |
 |
2023-04-29 | 2-(Perfluorobutyl)ethyl acrylate
52591-27-2
|
US $0.00 / KG | 1KG | 98% | 10000 | Wuhan Silworld Chemical Co.,Ltd | |
 |
2022-10-10 | 2-(Perfluorobutyl)ethyl acrylate
52591-27-2
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- 2-(Perfluorobutyl)ethyl acrylate
52591-27-2
- US $0.00-0.00 / kg
- 98% Min.
- WEIFANG OUCHEM TRADE CO.,LTD.
-
- 2-(Perfluorobutyl)ethyl acrylate
52591-27-2
- US $0.00 / KG
- 98%
- Wuhan Silworld Chemical Co.,Ltd
-
- 2-(Perfluorobutyl)ethyl acrylate
52591-27-2
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.