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Ethyl methacrylate

Ethyl methacrylate
Ethyl methacrylate structure
CAS No.
97-63-2
Chemical Name:
Ethyl methacrylate
Synonyms
EMA;PEMT;CD227;Episialin;rhoplexac-33;Rhoplex ac-33;Ethyl methacryla;Ethylmethacrylat;CA15-3 ELISA Kit;ETHYL METHACRYLATE
CBNumber:
CB9486656
Molecular Formula:
C6H10O2
Formula Weight:
114.14
MOL File:
97-63-2.mol

Ethyl methacrylate Properties

Melting point:
-75 °C
Boiling point:
118-119 °C(lit.)
Density 
0.917 g/mL at 25 °C(lit.)
vapor density 
>3.9 (vs air)
vapor pressure 
15 mm Hg ( 20 °C)
refractive index 
n20/D 1.413(lit.)
Flash point:
60 °F
storage temp. 
Refrigerator (+4°C) + Flammables area
solubility 
5.1g/l
form 
Liquid
color 
Clear colorless
Odor
Acrid acrylic.
explosive limit
1.8%(V)
Water Solubility 
4 g/L (20 ºC)
BRN 
471201
Stability:
Polymerizes in the presence of light or heat. Incompatible with peroxides, oxidizing agents, bases, acids, reducing agents, halogens and amines. Flammable.
CAS DataBase Reference
97-63-2(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoic acid, 2-methyl-, ethyl ester(97-63-2)
EPA Substance Registry System
2-Propenoic acid, 2-methyl-, ethyl ester(97-63-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F,Xi
Risk Statements  11-36/37/38-43
Safety Statements  9-16-29-33
RIDADR  UN 2277 3/PG 2
WGK Germany  1
RTECS  OZ4550000
Autoignition Temperature 771 °F
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29161490
Hazardous Substances Data 97-63-2(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 14600 mg/kg LD50 dermal Rabbit > 9130 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

NFPA 704

Diamond Hazard Value Description
3
0
Health  
Flammability   3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

Ethyl methacrylate price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 234893 Ethyl methacrylate contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99% 97-63-2 100ml $50.5 2018-11-13 Buy
Sigma-Aldrich 234893 Ethyl methacrylate contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99% 97-63-2 1l $82.9 2018-11-13 Buy
TCI Chemical M0084 Ethyl Methacrylate (stabilized with HQ) >99.0%(GC) 97-63-2 25mL $14 2018-11-22 Buy
TCI Chemical M0084 Ethyl Methacrylate (stabilized with HQ) >99.0%(GC) 97-63-2 500mL $28 2018-11-22 Buy
Alfa Aesar A17518 Ethyl methacrylate, 98+%, stab. with 100ppm 4-methoxyphenol 97-63-2 250ml $23.4 2018-11-13 Buy

Ethyl methacrylate Chemical Properties,Uses,Production

Chemical Properties

colourless liquid with an unpleasant odour

Uses

Polymers, chemical intermediates.

General Description

A colorless moderately toxic liquid with an acrid odor. Flash point of 70°F. Boiling point 278°F. Vapors irritate the eyes and respiratory system. Less dense than water. Not soluble in water. Used to make polymers and other chemicals.

Air & Water Reactions

Highly flammable. A very dangerous fire and explosion hazard. Not soluble in water.

Reactivity Profile

May polymerize if heated for prolonged periods or accidentally contaminated. If polymerization takes place inside a container, the container may violently rupture. Can react with oxidizing materials. When heated to decomposition Ethyl methacrylate emits irritating fumes and acrid smoke [Sax, 9th ed., 1996, p. 1576].

Hazard

Flammable, dangerous fire and explosion hazard. An irritant.

Health Hazard

Inhalation may cause irritation of the mucous membrane. Ingestion causes irritation of mouth and stomach. Contact with liquid irritates eyes and skin.

Fire Hazard

Behavior in Fire: Sealed containers may rupture explosively if hot. Heat can cause a violent polymerization reaction with rapid release of energy. Vapors are heavier than air and can travel to a source of ignition and flash back.

Fire Hazard

Flash Point (°F): 85 ℃; 80 ℃; Flammable Limits in Air (%): 1.8 (LFL); Fire Extinguishing Agents: Foam, dry chemical, carbon dioxide; Fire Extinguishing Agents Not To Be Used: Water may be ineffective; Special Hazards of Combustion Products: Data not available; Behavior in Fire: Sealed container may rupture explosively if hot. Heat can cause a violent polymerization reaction with rapid release of energy. Vapors are heavier than air and can travel considerable distance to a source of ignition and flash back; Ignition Temperature (°F): 740; Electrical Hazard: Data not available; Burning Rate: 4.56 mm/min.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: If proper concentration of inhibitor is not present or when material is hot, a violent polymerization reaction may occur; Inhibitor of Polymerization: Oxygen in the air inhibits polymerization.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Mildly toxic by inhalation. Experimental teratogenic and reproductive effects. A skin irritant. A very dangerous fire and explosion hazard when exposed to heat, sparks, or flame; can react with oxidzing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Purification Methods

Wash the ester successively with 5% aqueous NaNO2, 5% NaHSO3, 5% NaOH, then water. Dry it over MgSO4, add 0.2% (w/w) of phenyl-.-naphthylamine, and distil it through a short Vigreux column (p 11) [Schultz J Am Chem Soc 80 1854 1958]. [Beilstein 2 IV 1523.]

Ethyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products


Ethyl methacrylate Suppliers

Global( 148)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1771 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20653 58
Xiayi Yuhao Additives Co., Ltd.
18616206849
export@xyyhzj.com CHINA 67 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23982 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20094 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 4660 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30168 84

View Lastest Price from Ethyl methacrylate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-16 Ethyl methacrylate
97-63-2
US $1.00 / kg 1kg 98% 100mt career henan chemical co

Ethyl methacrylate Spectrum


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