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D-Phenothrin

CAS No.
26046-85-5
Chemical Name:
D-Phenothrin
Synonyms
D-PHENOTHRIN;D-permethrin;D-trans-Phenot;D-TRANS-PHENOTHRIN;rich-d-t-Phenothrin;(-)-trans-Phenothrin;(1r)-trans-phenothrin;Pesticide D-Phenothrin;(1r-trans)-henyl)methyleste;d-trans-phenothrin (bsi,ido,ban)
CBNumber:
CB9699395
Molecular Formula:
C23H26O3
Molecular Weight:
350.45
MDL Number:
MFCD01735786
MOL File:
26046-85-5.mol
MSDS File:
SDS
Last updated:2024-03-27 17:09:02

D-Phenothrin Properties

Boiling point 437.0±45.0 °C(Predicted)
Density 1.120±0.06 g/cm3(Predicted)
vapor pressure 1.9×10-5Pa (21.4 °C)
storage temp. Sealed in dry,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
Water Solubility <0.01 mg l-1 (25 °C)
color Colourless to Dark Yellow
CAS DataBase Reference 26046-85-5(CAS DataBase Reference)
FDA UNII 6JX527V7HJ
EPA Substance Registry System d-Phenothrin (26046-85-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS09
Signal word  Warning
Hazard statements  H410
Precautionary statements  P273-P391-P501
Toxicity LD50 oral in mouse: > 10gm/kg

D-Phenothrin price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC P318108 (-)-trans-Phenothrin 26046-85-5 500mg $400 2021-12-16 Buy
TRC P318108 (-)-trans-Phenothrin 26046-85-5 1g $700 2021-12-16 Buy
American Custom Chemicals Corporation PST0000179 D-PHENOTHRIN 95.00% 26046-85-5 100MG $945.95 2021-12-16 Buy
Alichem 26046855 (1R,3R)-3-Phenoxybenzyl2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylate 26046-85-5 1g $545 2021-12-16 Buy
Chemenu CM276400 (1R,3R)-3-Phenoxybenzyl2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylate 95% 26046-85-5 1g $580 2021-12-16 Buy
Product number Packaging Price Buy
P318108 500mg $400 Buy
P318108 1g $700 Buy
PST0000179 100MG $945.95 Buy
26046855 1g $545 Buy
CM276400 1g $580 Buy

D-Phenothrin Chemical Properties,Uses,Production

Uses

Phenothrin is used for the control of insects for public health. It is also used to protect stored grain.

Definition

ChEBI: (1R)-trans-phenothrin is a phenothrin. It is functionally related to a (+)-trans-chrysanthemic acid.

Metabolic pathway

Phenothrin is the name given to the 1RS-cis-trans isomer mixture (racemic). The product now used is d-phenothrin which is 95% 1R and 75% trans. It has no field use because the chrysanthemate moiety is very sensitive to photodegradation. Nevertheless, information on its photochemistry and its fate in soils and plants has been published. Several studies in rodents have been reported; this is a reflection of its use in public health. Phenothrin is degraded mainly by photo-oxidation and by hydrolysis and oxidation in plants and animals.

Degradation

Phenothrin is stable under normal storage conditions but it is labile to base, being hydrolysed to trans-2,2-dimethyl-3-(2-methylprop-1-enyl)- cyclopropanecarboxylic acid (11, trans-chrysanthemic acid) and 3-phenoxybenzyl alcohol (13,3PBAlc) (Scheme 2). It is sensitive to light and, for example, as a thin film at midday in the summer at 55 ° N, it was degraded with a DT50 of 2.5-3.0 hours (Samsonov and Makarov, 1996).
When (lR)-trans-[14C-carboxyl]phenotwhraisn irradiated in degassed benzene solution, the only product was the cis-isomer. However, in oxygenated benzene solution, degradation was about 10-fold faster and many products were detected (Ruzo et al., 1982). A similar array of products was seen on exposure of thin films to sunlight. Major products (Scheme 1) were formed by oxidation at the isobutylene substituent giving the epoxide (2), the alcohol (3), the aldehyde (4) and the carboxylic acid (5). Caronaldehyde (6) and the caronic acid derivative (7) were formed by cleavage of ozonolysis products and the hydroperoxide (8) was formed by ene reactions at the 1’-position. Ester cleavage to 3PBAlc, 3PBAl and 3PBA (not shown in Scheme 1) was relatively minor.

D-Phenothrin Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 153)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Shanxi Naipu Import and Export Co.,Ltd
+86-13734021967 +8613734021967 kaia@neputrading.com China 1011 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58

View Lastest Price from D-Phenothrin manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
pesticide  pictures 2024-03-27 pesticide
26046-85-5
US $18.00 / kg 1kg 99.9%min 10000kgs/month Wuhan Boyuan Import & Export Co., LTD
D-Phenothrin pictures 2023-09-19 D-Phenothrin
26046-85-5
US $0.00 / kg 1kg 99% 20tons Hebei Yanxi Chemical Co., Ltd.
D-Phenothrin pictures 2023-08-15 D-Phenothrin
26046-85-5
US $10.00 / KG 1KG 99% 5000000kg Hebei Mojin Biotechnology Co., Ltd
  • pesticide  pictures
  • pesticide
    26046-85-5
  • US $18.00 / kg
  • 99.9%min
  • Wuhan Boyuan Import & Export Co., LTD
  • D-Phenothrin pictures
  • D-Phenothrin
    26046-85-5
  • US $0.00 / kg
  • 99%
  • Hebei Yanxi Chemical Co., Ltd.
  • D-Phenothrin pictures
  • D-Phenothrin
    26046-85-5
  • US $10.00 / KG
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
(1R)-2β-(2-Methyl-1-propenyl)-3,3-dimethylcyclopropane-1α-carboxylic acid m-phenoxybenzyl ester (1R)-3,3-Dimethyl-2β-(2-methyl-1-propenyl)cyclopropane-1α-carboxylic acid 3-phenoxybenzyl ester (1R,3R)-2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid 3-phenoxybenzyl ester (1R,3R)-2,2-Dimethyl-3α-(2-methyl-1-propenyl)cyclopropanecarboxylic acid (3-phenoxyphenyl)methyl ester (1R-trans)-2,2-Dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylic acid D-trans-Phenot (1r)-trans-phenothrin (1r-trans)-henyl)methyleste 2,2-dimethyl-3-(2-methyl-1-propenyl)-,(3-phenoxyphenyl)methylester,(1r-trans)-cyclopropanecarboxylicaci D-TRANS-PHENOTHRIN D-PHENOTHRIN (1R-trans)-2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid-(3-phenoxyphenyl)methyl ester- d-trans-phenothrin (bsi,ido,ban) (1R-trans)-2,2-Dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylic acid, (3-phenoxyphenyl)methyl ester 3-Phenoxybenzyl (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate 3-PHENOXYBENZYL(+)-TRANS-CHRYSANTHEMATE rich-d-t-Phenothrin (1R)-2,2-Dimethyl-3α-(2-methyl-1-propenyl)cyclopropane-1β-carboxylic acid 3-phenoxybenzyl ester m-phenoxybenzyl (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate Pesticide D-Phenothrin (3-phenoxyphenyl)methyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid (3-phenoxyphenyl)methyl ester Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, (3-phenoxyphenyl)methyl ester, (1R,3R)- (-)-trans-Phenothrin (1R,3R)-3-Phenoxybenzyl 2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylate D-permethrin 26046-85-5