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CHLOROSILANE

CAS No.
13465-78-6
Chemical Name:
CHLOROSILANE
Synonyms
SiH3Cl;chloro-silan;CHLOROSILANE;chlorosilicon;Silane, chloro-;Trihydridesilicon chloride;Silicon trihydride chloride;chlorosilanes,corrosive,n.o.s.;chlorosilanes,corrosive,flammable,n.o.s.;chlorosilanes,water-reactive,flammable,corrosive,n.o.s.
CBNumber:
CB9741883
Molecular Formula:
ClH3Si
Lewis structure
sih3cl lewis structure
Molecular Weight:
66.56
MDL Number:
MFCD07777018
MOL File:
13465-78-6.mol
MSDS File:
SDS
Last updated:2023-10-17 17:11:58

CHLOROSILANE Properties

Melting point -118°C
Boiling point -30,4°C
Density 1,145 g/cm3
Flash point -90°C (-133°F)
form colorless gas
Specific Gravity 1.145
color colorless
Hydrolytic Sensitivity 10: reacts extremely rapidly with moisture and oxygen - may be pyrophoric - sealed system required
EPA Substance Registry System Silane, chloro- (13465-78-6)

CHLOROSILANE Chemical Properties,Uses,Production

Chemical Properties

colorless gas; enthalpy of vaporization 21kJ/mol; entropy of vaporization 82.8kJ/(mol·K) [CIC73] [CRC10]

General Description

Chlorosilanes are a class of liquids that range in color from clear colorless to light yellow colored. A clear to light yellow liquid. Slightly more dense than water. Contact may burn skin, eyes and mucous membranes. May be toxic by ingestion, inhalation, and skin absorption. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Based on the properties of similar materials, there is the possibility that the reaction of CHLOROSILANE with water may be vigorous or violent. Products of the reaction include hydrogen chloride. The reaction generates heat and this heat may be sufficient to ignite the product. The chlorosilicon hydrides(ClxSiHy) are spontaneously flammable in air, NFPA 1991.

Reactivity Profile

Chlorosilanes are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

Health Hazard

Highly toxic: contact with water produces toxic gas, may be fatal if inhaled. Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.

Fire Hazard

Produce flammable and toxic gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Containers may explode when heated. Runoff may create fire or explosion hazard.

CHLOROSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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CHLOROSILANE Silicon trihydride chloride Trihydridesilicon chloride Silane, chloro- chloro-silan chlorosilanes,corrosive,flammable,n.o.s. chlorosilanes,corrosive,n.o.s. chlorosilanes,water-reactive,flammable,corrosive,n.o.s. SiH3Cl chlorosilicon 13465-78-6 ClH3Si H3ClSi