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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

CAS No.
35789-01-6
Chemical Name:
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Synonyms
)amide]samarium(III);samarium tris(hexamethylsilazide);samarium tris(hexamethyldisilazde);SAMARIUM TRIS(HEXAMETHYLDISILAZIDE);tris(bis(trimethylsilyl)amino)samarium;Tris[N,N-bis(trimethylsilyl)amide]samarium;TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III);Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium;Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM;1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt
CBNumber:
CB9775244
Molecular Formula:
C6H19NSi2Sm
Molecular Weight:
311.76
MDL Number:
MFCD03427097
MOL File:
35789-01-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Properties

Melting point 93-106 °C(lit.)
Boiling point 83-4°C/1x10-4mmHg
Flash point 36 °F
form solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05
Signal word  Danger
Hazard statements  H228-H261-H314
Precautionary statements  P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  F,C
Risk Statements  11-14/15-34
Safety Statements  16-26-36/37/39-43-45-7/8
RIDADR  UN 3396 4.3/PG 2
WGK Germany  3
TSCA  No

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 547980 Tris[N,N-bis(trimethylsilyl)amide]samarium(III) 98% 35789-01-6 1g $193 2024-03-01 Buy
Product number Packaging Price Buy
547980 1g $193 Buy

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Chemical Properties,Uses,Production

Uses

Reactant for synthesis of:

  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Preparation Products And Raw materials

Raw materials

Preparation Products

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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III) Tris[N,N-bis(trimethylsilyl)amide]samarium Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium samarium tris(hexamethylsilazide) Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C samarium tris(hexamethyldisilazde) tris(bis(trimethylsilyl)amino)samarium )amide]samarium(III) 35789-01-6 CH33Si2N3Sm C18H54N3Si6Sm SmNSiCH3323 Catalysis and Inorganic Chemistry Samarium Rare-Earth Metals Catalysis and Inorganic Chemistry Chemical Synthesis Precursors by Metal SamariumVapor Deposition Precursors Samariun