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Di-n-butyl peroxydicarbonate(in solution,content≤27%)

CAS No.
16215-49-9
Chemical Name:
Di-n-butyl peroxydicarbonate(in solution,content≤27%)
Synonyms
Dibutyl perdicarbonate;n-Butyl perdicarbonate;Dibutylperoxydicarbonat;Butyl peroxydicarbonate.;dibutyl peroxydicarbonate;Di-n-butyl perdicarbonate;Di-n-butyl peroxydicarbonate;Peroxydicarbonic acid dibutyl;n-butyl peroxy dicarbonate;Di-2-ethoxyethyl perdicarbonate
CBNumber:
CB9851825
Molecular Formula:
C10H18O6
Molecular Weight:
234.25
MDL Number:
MOL File:
16215-49-9.mol
Last updated:2023-05-04 15:13:36

Di-n-butyl peroxydicarbonate(in solution,content≤27%) Properties

Boiling point 296.56°C (rough estimate)
Density 1.1351 (rough estimate)
vapor pressure 0.056Pa at 25℃
refractive index 1.4390 (estimate)
Water Solubility 54.44mg/L at 25℃
LogP 3.19 at 20℃
EPA Substance Registry System Peroxydicarbonic acid, dibutyl ester (16215-49-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS02,GHS09
Signal word  Danger
Hazard statements  H410-H317-H400-H242
Precautionary statements  P273-P391-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P273-P391-P501-P210-P220-P234-P280-P370+P378-P403+P235-P411-P420-P501
RIDADR  3119
HazardClass  5.2
PackingGroup  II

Di-n-butyl peroxydicarbonate(in solution,content≤27%) Chemical Properties,Uses,Production

Chemical Properties

Butyl peroxydicarbonate is a colorless liquid. Highly unstable peroxide, it crystallizes when dry or heated. May explode from heat, shock, or friction, when dry. During decomposition, it emits acrid smoke and irritating vapors. Handle with extreme care. It decomposes violently or explosively at temperatures 0–10°C owing to self-accelerating exothermic decomposition. Several recorded explosions were due to shock, heat, or friction; amines and certain metals can cause accelerated decomposition. Shipped or stored with not more than 62% peroxide in solution of organic solvent (12d). Refer to the Code for the Storage of Organic Peroxide Formulations (13a). It is commonly used as oxidant agent. No additional information was found on this compound.

General Description

A colorless liquid. Shipped or stored with not more than 62% peroxide in solution of organic solvent. Crystallizes when dry. May explode from heat, shock or friction, when dry. Handle with extreme care.

Reactivity Profile

Di-n-butyl peroxydicarbonate(in solution,content≤27%) decomposes violently or explosively at temperatures 0-10°C owing to self-accelerating exothermic decomposition. Several recorded explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry.

Di-n-butyl peroxydicarbonate(in solution,content≤27%) Preparation Products And Raw materials

Raw materials

Preparation Products

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di-(4-t-butylcyclohexyl) peroxydicarbonate, <=42% in water di-(4-t-butylcyclohexyl) peroxydicarbonate, pure di-n-butyl peroxydicarbonate, 28-52% in solution [α,β-Peroxy]dicarbonic acid dibutyl ester Dibutyl perdicarbonate Peroxybis(formic acid butyl) ester Peroxydicarbonic acid dibutyl Peroxydicarbonic acid dibutyl ester Di-2-ethoxyethyl perdicarbonate n-Butyl perdicarbonate Peroxydicarbonic acid di(2-ethoxyethyl) ester n-butyl peroxy dicarbonate Di-n-butyl peroxydicarbonate(in solution,content≤27%) Di-n-butyl peroxydicarbonate(in solution,content≤52%) dibutyl peroxydicarbonate Di-n-butyl perdicarbonate Di-n-butyl peroxydicarbonate Butyl peroxydicarbonate. Dibutylperoxydicarbonat di-n-butyl peroxydicarbonate, <= 27% in solution 16215-49-9