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4-Chlorotoluene structure
Chemical Name:
Molecular Formula:
Formula Weight:
MOL File:

4-Chlorotoluene Properties

Melting point:
6-8 °C(lit.)
Boiling point:
162 °C(lit.)
1.07 g/mL at 25 °C(lit.)
vapor density 
4.38 (vs air)
vapor pressure 
10 mm Hg ( 45 °C)
refractive index 
n20/D 1.52(lit.)
Flash point:
121 °F
storage temp. 
7.4 (H2O)(saturated aqueous solution)
explosive limit
Water Solubility 
<0.1 g/100 mL at 20 ºC
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference
106-43-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-4-methyl-(106-43-4)
EPA Substance Registry System
Benzene, 1-chloro-4-methyl-(106-43-4)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn,N,T,F
Risk Statements  20-51/53-39/23/24/25-23/24/25-11-10-43
Safety Statements  24/25-61-45-36/37-16-7
RIDADR  UN 2238 3/PG 3
WGK Germany  2
RTECS  XS9010000
Hazard Note  Harmful
HazardClass  3
PackingGroup  III
HS Code  29036990
HS Code  29337900
Hazardous Substances Data 106-43-4(Hazardous Substances Data)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.

4-Chlorotoluene price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 111929 4-Chlorotoluene 98% 106-43-4 100g $44.3 2018-11-13 Buy
Sigma-Aldrich 111929 4-Chlorotoluene 98% 106-43-4 500g $198 2018-11-13 Buy
Alfa Aesar L04672 4-Chlorotoluene, 98% 106-43-4 500g $72 2018-11-13 Buy
Alfa Aesar L04672 4-Chlorotoluene, 98% 106-43-4 100g $24 2018-11-13 Buy
Sigma-Aldrich 47798 4-Chlorotoluene analytical standard 106-43-4 47798 $26.3 2018-11-23 Buy

4-Chlorotoluene Chemical Properties,Uses,Production

Chemical Properties

colourless liquid


4-Chlorotoluene is used in a variety of organic synthesis, such as acting as coupling precursors for palladium-catalyzed acylation of acetanilides.


Solvent; dyestuff intermediate; in organic syntheses.


Avoid inhalation; strong irritant.

Safety Profile

Moderately toxic by ingestion. Mdly toxic by inhalation. Flammable when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl-. See also TOLYL CHLORIDE and CHLORINATED HYDROCARBONS, AROMATIC.

Purification Methods

Dry it with BaO, fractionally distil it, then fractionally crystallise it by partial freezing. [Beilstein 5 IV 806.]

4-Chlorotoluene Preparation Products And Raw materials

Raw materials

Preparation Products

4-Chlorotoluene Suppliers

Global( 228)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 China 19919 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817 CHINA 21909 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693 CHINA 20680 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 CHINA 1367 55
Mainchem Co., Ltd.
+86-0592-6210733 CHINA 32457 55
Hebei Aicrowe Biotech Co., Ltd
0311-66855331 CHINA 308 58
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114 CHINA 6374 58
career henan chemical co
+86-371-86658258 CHINA 20653 58
Chemwill Asia Co.,Ltd.
86-21-51861608;;; CHINA 23982 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254 CHINA 20094 58

View Lastest Price from 4-Chlorotoluene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-05-28 4-Chlorotoluene 106-43-4
US $10.00 / Kg/Drum 1g 99.6% 2000 Hebei Aicrowe Biotech Co., Ltd
2018-12-16 4-Chlorotoluene
US $7.00 / kg 1kg 99% 100KG career henan chemical co

4-Chlorotoluene Spectrum

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