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Propyl chloroformate

Propyl chloroformate
Propyl chloroformate structure
CAS No.
109-61-5
Chemical Name:
Propyl chloroformate
Synonyms
NPCF;Propyl chloroforMat;PROPYL CHLOROFORMATE;Proply chloroformate;PROPYL CHLOROCARBONATE;N-PROPYL CHLOROFORMATE;Chloride propyl forMate;Propyl chloridocarbonate;n-Propyl chlorocarbonate;propyl carbonochloridate
CBNumber:
CB9852781
Molecular Formula:
C4H7ClO2
Formula Weight:
122.55
MOL File:
109-61-5.mol

Propyl chloroformate Properties

Boiling point:
105-106 °C(lit.)
Density 
1.09 g/mL at 25 °C(lit.)
vapor pressure 
0.87 psi ( 20 °C)
refractive index 
n20/D 1.404(lit.)
Flash point:
84 °F
storage temp. 
2-8°C
solubility 
benzene: miscible(lit.)
Specific Gravity
1.09
Merck 
13,7940
InChIKey
QQKDTTWZXHEGAQ-UHFFFAOYSA-N
CAS DataBase Reference
109-61-5(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
A5Y2T003JU
NIST Chemistry Reference
n-Propylchloroformate(109-61-5)
EPA Substance Registry System
Propyl chloroformate (109-61-5)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H225-H302-H314-H331
Precautionary statements  P210-P261-P280-P305+P351+P338-P310
Hazard Codes  T,F
Risk Statements  10-23-34-22-11
Safety Statements  26-36-45-16
RIDADR  UN 2740 6.1/PG 1
WGK Germany  1
RTECS  LQ6830000
HazardClass  6.1(a)
PackingGroup  I
HS Code  29151300

Propyl chloroformate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 249467 Propyl chloroformate 98% 109-61-5 25g $36.3 2019-12-02 Buy
Sigma-Aldrich 249467 Propyl chloroformate 98% 109-61-5 100g $111 2019-12-02 Buy

Propyl chloroformate Chemical Properties,Uses,Production

Chemical Properties

Propyl chloroformate is a colorless liquid.

Uses

Organic synthesis, military poison gas (lachry- mator).

Production Methods

Prepared by the reaction of liquid anhydrous n-propyl alcohol with molar excess of dry, chlorine-free phosgene at low temperature.

General Description

A colorless liquid. May be decomposed by water. Severely irritates skin and eyes. Very toxic by ingestion, inhalation or skin absorption. Denser than water and vapors heavier than air. Flash point 50°F. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Water (moisture in air or soil) reacts with generation of heat and hydrochloric acid.

Reactivity Profile

Unstable, decomposes spontaneously to form hydrochloric acid and other products. Avoid moist air. [EPA, 1998]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Hazard

Toxic by inhalation and ingestion, strong irritant to eyes.

Health Hazard

Strongly irritating to eyes and mucous membranes. Poisonous; may be fatal if inhaled, swallowed or absorbed through skin.

Fire Hazard

When heated to decomposition, Propyl chloroformate emits toxic fumes of chlorine containing compounds. Propyl chloroformate is a flammable/combustible material; Propyl chloroformate may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat or fire. Vapor explosion and poison hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Runoff from fire control or dilution water may cause pollution. Gradually decomposed by water and alcohol. Unstable, decomposes spontaneously to form hydrochloric acid and other products. Avoid moist air.

Safety Profile

Poison by skin contact. Moderately toxic by ingestion and inhalation. A corrosive irritant to skin, eyes, and mucous membranes. Flammable when exposed to heat or flame, can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-. Used as a reactive intermediate to polymerization initiators.

Potential Exposure

Propyl chloroformate is used in organic synthesis; as an intermediate for polymerization initiators; may have been used as a military poison gas.

Shipping

UN2740 n-Propyl chloroformate, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, 8-Corrosive material. Inhalation Hazard Zone B

Incompatibilities

Propyl chloroformate forms explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, water and alcohols. Reaction with water forms heat and hydrochloric acid. Attacks some metals and coating in the presence of moisture.

Propyl chloroformate Preparation Products And Raw materials

Raw materials

Preparation Products


Propyl chloroformate Suppliers

Global( 152)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293
+86 0531-67809011 sales@sdzschem.com CHINA 2995 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30052 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23979 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28235 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6372 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23048 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35438 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47484 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072
+8613111626072 zzwenxi@126.com CHINA 7497 58
Amadis Chemical Company Limited
0086-571-89925085
0086-571-89925065 sales@amadischem.com China 132152 58

View Lastest Price from Propyl chloroformate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-15 Propyl chloroformate
109-61-5
US $1.00 / kg 1kg 99% Customized career henan chemical co

Propyl chloroformate Spectrum


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