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Cyanogen bromide

CAS No. 506-68-3
Chemical Name: Cyanogen bromide
Synonyms: BrCN;tl822;(CN)Br;TL 822;Campilit;Bromcyan;BROMOCYAN;NSC 89684;BROMOCYANE;Cyanobromide
CBNumber: CB9853692
Molecular Formula: CBrN
Formula Weight: 105.92
MOL File: 506-68-3.mol
Cyanogen bromide Property
Melting point : 50-53 °C(lit.)
Boiling point : 61-62 °C(lit.)
density : 1.443 g/mL at 25 °C
vapor density : 3.65 (vs air)
vapor pressure : 100 mm Hg ( 22.6 °C)
Fp : 61.4°C
storage temp. : 0-6°C
solubility : Soluble in chloroform, dichloromethane, ethanol, diethyl ether, benzene and acetonitrile.
Sensitive : Moisture & Light Sensitive
Merck : 14,2693
Stability:: Stable. Reacts violently with water and with mineral and organic acids.
CAS DataBase Reference: 506-68-3(CAS DataBase Reference)
NIST Chemistry Reference: Cyanogen bromide(506-68-3)
EPA Substance Registry System: Cyanogen bromide ((CN)Br)(506-68-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : T+,N,F,C
Risk Statements : 26/27/28-34-50/53-40-11-36/37-32-51/53
Safety Statements : 53-28-36/37/39-45-60-61-26-16-7/9-29-7
RIDADR : UN 3390 6.1/PG 1
WGK Germany : 3
RTECS : GT2100000
F : 8-17-19-21
TSCA : Yes
HazardClass : 6.1
PackingGroup : I
Hazardous Substances Data: 506-68-3(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P320 Specific treatment is urgent (see … on this label).
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.

Cyanogen bromide Chemical Properties,Usage,Production

Chemical Properties
white crystalline solid
Uses
Reaction with C60Ph5Cl produces a novel phenylated isoquinolino[3′,4′:1,2][60]fullerene.1
General Description
Cyanogen bromide is a colorless to white crystalline solid with a penetrating odor. Cyanogen bromide is slightly soluble in water. Cyanogen bromide is gradually decomposed by water and very rapidly by acids to give off hydrogen bromide, a flammable and poisonous gas. Contamination with many materials can cause rapid decomposition of the material. Cyanogen bromide is toxic by inhalation of its vapors or by the hydrogen cyanide from decomposition or by ingestion. Toxic oxides of nitrogen are produced in fire involving Cyanogen bromide. Cyanogen bromide is used in gold extraction, to make other chemicals, and as a fumigant.
Air & Water Reactions
Cyanogen bromide is slightly soluble in water. Cyanogen bromide is gradually decomposed by water and very rapidly by acids to give off hydrogen bromide, a poison gas.
Reactivity Profile
Cyanogen bromide is not combustible itself, but impure Cyanogen bromide decomposes rapidly and tends to explode. A violent reaction may take place on contact with large quantities of acid. Avoid physical damage, contact with acids or water, and store away from a location where water may be needed for fire control. [EPA, 1998]. Benzene and cyanogen halides yield HCl as a byproduct (Hagedorn, F. H. Gelbke, and Federal Republic of Germany. 2002. Nitriles. In Ullman Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA.).
Health Hazard
Super toxic; probable oral lethal dose in humans is less than 5 mg/kg or a taste (less than 7 drops) for a 70 kg (150 lb.) person. Vapors are highly irritant and very poisonous. Individuals with chronic diseases of the kidneys, respiratory tract, skin, or thyroid are at greater risk of developing toxic cyanide effects.
Fire Hazard
Cyanogen bromide is not combustible itself, but impure Cyanogen bromide decomposes rapidly and tends to explode. A violent reaction may take place on contact with large quantities of acid. Vapors are highly irritating. When material is heated to decomposition, Cyanogen bromide emits very toxic fumes of cyanide and bromide. Avoid water, acids. Avoid physical damage, contact with acids or water, and store away from a location where water may be needed for fire control.
Cyanogen bromide Preparation Products And Raw materials
Raw materials
Preparation Products
DIETHYLCYANAMIDE ((1R,4S)-2-Azabicyclo[2.2.1]hept-5-en-3-one Diethyl cyanophosphonate 4-METHOXY-2-MORPHOLIN-4-YL-THIAZOLE-5-CARBALDEHYDE 1,1,1,3,3,3-Hexafluoro-2-propanol Fluoxetine 2-(4-difluoromethoxy)phenyl-3-methyl butyric acid MORPHOLINE-4-CARBOTHIOAMIDE Admire 2-Bromofuran
Cyanogen bromide Suppliers      Global( 105)Suppliers     
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Capot Chemical Co.,Ltd. +86 (0)571-855 867 18
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JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
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Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
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021-67582001/03/05 saleschina@alfa-asia.com China 30315 84
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