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Methyl chloroacetate

Methyl chloroacetate
Methyl chloroacetate structure
CAS No.
96-34-4
Chemical Name:
Methyl chloroacetate
Synonyms
IHT-FC MCA;ClH2CCOOCH3;AKOS BBS-00004061;Methylechloroacetate;Mathyl Chloroacetate;METHYL CHLOROACETATE;methylchloroethanoate;Methyl chloroethanoate;methylmonochloracetate;LABOTEST-BB LT00779142
CBNumber:
CB9854725
Molecular Formula:
C3H5ClO2
Formula Weight:
108.52
MOL File:
96-34-4.mol

Methyl chloroacetate Properties

Melting point:
-33 °C
Boiling point:
130 °C740 mm Hg(lit.)
Density 
1.238 g/mL at 25 °C(lit.)
vapor density 
3.8 (vs air)
vapor pressure 
10 mm Hg ( 25 °C)
refractive index 
n20/D 1.422(lit.)
Flash point:
125 °F
storage temp. 
Store at <= 20°C.
solubility 
51.6g/l (slow decomposition)
form 
Liquid
color 
Clear colorless
PH
4.6 (28g/l, H2O, 20℃)
explosive limit
4.6-18.5%(V)
Water Solubility 
28 g/L (20 ºC)
Merck 
14,6042
BRN 
506255
CAS DataBase Reference
96-34-4(CAS DataBase Reference)
EWG's Food Scores
1-3
FDA UNII
450VSB182I
NIST Chemistry Reference
Acetic acid, chloro-, methyl ester(96-34-4)
EPA Substance Registry System
Acetic acid, 2-chloro-, methyl ester (96-34-4)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05,GHS06,GHS07
Signal word  Danger
Hazard statements  H315-H226-H301-H318-H331-H335-H301+H331
Precautionary statements  P261-P280-P301+P310-P305+P351+P338-P311-P210-P301+P310a-P303+P361+P353-P405-P501a
Hazard Codes  T,Xi,F
Risk Statements  10-23/25-37/38-41-40-36/37/38-38
Safety Statements  26-37/39-45-36-16
RIDADR  UN 2295 6.1/PG 1
WGK Germany  2
RTECS  AF9500000
19
Autoignition Temperature 869 °F
TSCA  Yes
HS Code  2915 40 00
HazardClass  6.1
PackingGroup  I
Toxicity LD50 orally in Rabbit: 107 mg/kg
NFPA 704
2
2 1

Methyl chloroacetate price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.02413 Methyl chloroacetate for synthesis 96-34-4 100 mL $28.77 2021-03-22 Buy
Sigma-Aldrich 108413 Methyl chloroacetate 99% 96-34-4 500g $37 2021-03-22 Buy
Sigma-Aldrich 108413 Methyl chloroacetate 99% 96-34-4 1kg $55.8 2021-03-22 Buy
Sigma-Aldrich 8.02413 Methyl chloroacetate for synthesis 96-34-4 1 L $62.44 2021-03-22 Buy
Alfa Aesar A10325 Methyl chloroacetate, 99+% 96-34-4 250g $19.7 2021-03-22 Buy

Methyl chloroacetate Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

As solvent.

Synthesis Reference(s)

The Journal of Organic Chemistry, 50, p. 3408, 1985 DOI: 10.1021/jo00218a034

General Description

A crystalline solid or a solid dissolved in a liquid. Insoluble in water and denser than water. Contact may slightly irritate skin, eyes and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Methyl chloroacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

Extremely corrosive to the eyes, skin, nose, throat, and upper respiratory tract. Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

Fire Hazard

Special Hazards of Combustion Products: Toxic fumes of hydrogen chloride

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and subcutaneous routes. Flammable when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-.

Purification Methods

Shake the ester with saturated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (three times), saturated aqueous NaCl (twice), dry (Na2SO4) and fractionally distil it. Very toxic. [Beilstein 2 IV 480.]

Methyl chloroacetate Preparation Products And Raw materials

Raw materials

Preparation Products


Methyl chloroacetate Suppliers

Global( 308)Suppliers
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View Lastest Price from Methyl chloroacetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-11-26 Methyl chloroacetate
96-34-4
US $0.00 / Kg/Drum 1KG 99% 2000mt/year Jinan Finer Chemical Co., Ltd
2021-11-08 Methyl chloroacetate
96-34-4
US $10.00 / g 100g 99% 1000ton/Month Wuhan wingroup Pharmaceutical Co., Ltd
2021-10-11 Methyl chloroacetate
96-34-4
US $0.00 / Kg/Drum 1000KG 99% 10tons Foshan Sanshui Jingze Chemical Co.,Ltd

Methyl chloroacetate Spectrum


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