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Tris(dibenzylideneacetone)dipalladium

Description Uses Reactions References
Tris(dibenzylideneacetone)dipalladium
Tris(dibenzylideneacetone)dipalladium structure
CAS No.
51364-51-3
Chemical Name:
Tris(dibenzylideneacetone)dipalladium
Synonyms
(DBA)3PD2;CB9855353;51364-51-3;Pd2(dbba)3;Tris(dibenzyL;ideneacetone)dipaL;Tris(dibenzylideneac;Tris(dba)dipalladium(0);Pd2(dibenzylideneacetone)3;Tris(dibenzylideneacetone)dipa
CBNumber:
CB9855353
Molecular Formula:
C51H42O3Pd2
Formula Weight:
915.71738
MOL File:
51364-51-3.mol

Tris(dibenzylideneacetone)dipalladium Properties

Melting point:
152-155°C
storage temp. 
2-8°C
solubility 
Soluble in chlorinated solvents, benzene and THF.
form 
Fine Crystalline Powder
color 
Purple to black
Water Solubility 
insoluble
Sensitive 
Air & Moisture Sensitive
InChIKey
IBXMKLPFLZYRQZ-VCHVFRDLSA-N
CAS DataBase Reference
51364-51-3(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS08
Signal word  Warning
Hazard statements  H351
Precautionary statements  P281
Hazard Codes  Xn
Risk Statements  20/22-36-40
Safety Statements  24/25-36/37
WGK Germany  3
TSCA  No
HS Code  28439000

Tris(dibenzylideneacetone)dipalladium price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 51364-51-3 1g $74.5 2020-08-18 Buy
Sigma-Aldrich 328774 Tris(dibenzylideneacetone)dipalladium(0) 97% 51364-51-3 5g $165 2020-08-18 Buy
TCI Chemical T2184 Tris(dibenzylideneacetone)dipalladium(0) 51364-51-3 200MG $23 2021-03-22 Buy
TCI Chemical T2184 Tris(dibenzylideneacetone)dipalladium(0) >75.0%(T) 51364-51-3 1g $72 2021-03-22 Buy
TCI Chemical T2184 Tris(dibenzylideneacetone)dipalladium(0) >75.0%(T) 51364-51-3 5g $358 2021-03-22 Buy

Tris(dibenzylideneacetone)dipalladium Chemical Properties,Uses,Production

Description

Tris(dibenzylideneacetone) dipalladium (Tris DBA) is used as catalyst for a wide variety of Pd catalyzed reactions including Suzuki coupling, Heck coupling, Negishi coupling, Carroll reaarangement, Trost asymmetric allylic alkylation, Buchwald-Hartwig amination of acryl halides, fluorination of allylic chlorides, arylation of ketones, carbonylation of 1,1-dichloro-1-alkenes, ß-arylation of carboxylic esters, and conversion of aryl and vinyl triflates to aryl and vinyl halides. It is also involved in the synthesis of azepane. Tris DBA is also a novel inhibitor of N-myristoyltransferase-1 with significant antitumor activity.

Uses

Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. Also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor.

Reactions

1. Catalyst precursor for conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
2. Catalyst for the synthesis of epoxides.
3. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins.
4. Site-selective benzylic sp3 palladium-catalyzed direct arylation.
5. Palladium-catalyzed one-pot synthesis of tricyclic indolines.
6. Active catalyst for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles.
7. Catalyst in combination with BINAP for the asymmetric Heck Arylation of olefins.
8. Precursor for palladium-catalyzed carbon-nitrigen bond formation.
9. Catalyst for α-arylation of ketones,
10. Cross-coupling of aryl halides with aryl boronic acids.

References

  1. https://en.wikipedia.org/wiki/Tris(dibenzylideneacetone)dipalladium(0)
  2. http://www.sigmaaldrich.com
  3. https://www.alfa.com
  4. https://pubchem.ncbi.nlm.nih.gov
  5. S. S. Bhandarkar, J. Bromberg, C. Carrillo, P. Selvakumar, R. K. Sharma, B. N. Perry, B. Govindarajan, L. Fried, A. Sohn, K. Reddy and J. L. Arbiser, Tris (Dibenzylideneacetone) Dipalladium, a N-Myristoyltransferase-1 Inhibitor, Is Effective against Melanoma Growth In vitro and In vivo, Clinical Cancer Research, 2008, vol. 18, 5743-5748

Chemical Properties

dark purple solid

Uses

suzuki reaction

Uses

A cycloaddition catalyst.

Tris(dibenzylideneacetone)dipalladium Preparation Products And Raw materials

Raw materials

Preparation Products


Tris(dibenzylideneacetone)dipalladium Suppliers

Global( 349)Suppliers
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Wuhan LPBchem Technology Co.,Ltd
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Wuhan Pengo Technology.,Ltd.
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info@spring-chem.com China 2065 57
Capot Chemical Co.,Ltd.
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+86-571-85864795 sales@capotchem.com China 20010 60
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 21031 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
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+86-571-56059825 fandachem@gmail.com CHINA 8882 55
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View Lastest Price from Tris(dibenzylideneacetone)dipalladium manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-07-13 Tris(dibenzylideneacetone)dipalladium
51364-51-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10 Tris(dibenzylideneacetone)dipalladium
51364-51-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-06-11 Tris(dibenzylideneacetone)dipalladium
51364-51-3
US $10.00-10.00 / g 1g 0.98 50kg Wuhan LPBchem Technology Co.,Ltd

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