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4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン

4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン 化学構造式
161265-03-8
CAS番号.
161265-03-8
化学名:
4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン
别名:
4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン;キサントホス;4,5‐ビス(ジフェニルホスフィノ)‐9,9‐ジメチルキサンテン;9,9-ジメチル-4,5-ビス(ジフェニルホスフィノ)キサンテン
英語化学名:
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
英語别名:
XANT PHOS;Xantphos 97%;9-diMethyl-4;98% XantPhos;4,5-Bis(diphenylphosphino)-9,9;9,9-DiMethyl-4,5-bis(diphenylp;Dimethylbisdiphenylphosphinoxanthene;5-bis(diphenylphosphino)-9H-xanthene;4,5- two -9,9- two methyl oxygen hetero;4,5-Bis(diphenylphospheno)-9,9-dimethyl
CBNumber:
CB0141028
化学式:
C39H32OP2
分子量:
578.62
MOL File:
161265-03-8.mol

4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン 物理性質

融点 :
224-228 °C(lit.)
闪点 :
450℃
貯蔵温度 :
Room temperature.
溶解性:
Soluble in organic solvents.
外見 :
Crystals
色:
White to light yellow
InChIKey:
CXNIUSPIQKWYAI-UHFFFAOYSA-N
CAS データベース:
161265-03-8(CAS DataBase Reference)

安全性情報

主な危険性  Xn
Rフレーズ  37-20/22
Sフレーズ  37/39-26
WGK Germany  3
HSコード  29319090

4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン 価格 もっと(19)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-1242 9,9-ジメチル-4,5-ビス(ジフェニルホスフィノ)キサンテン
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene
161265-03-8 1g ¥13200 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-1242 9,9-ジメチル-4,5-ビス(ジフェニルホスフィノ)キサンテン
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene
161265-03-8 5g ¥58000 2018-12-26 購入
東京化成工業 B2709 4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン >98.0%(HPLC)
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene >98.0%(HPLC)
161265-03-8 5g ¥17500 2018-12-04 購入
東京化成工業 B2709 4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン >98.0%(HPLC)
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene >98.0%(HPLC)
161265-03-8 1g ¥5000 2018-12-04 購入
関東化学株式会社(KANTO) 04883-62 4,5‐ビス(ジフェニルホスフィノ)‐9,9‐ジメチルキサンテン >95.0%(HLC)
4,5‐Bis(diphenylphosphino)‐9,9‐dimethylxanthene >95.0%(HLC)
161265-03-8 1g ¥6200 2018-12-13 購入

4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン 化学特性,用途語,生産方法

外観

白色~淡黄色、結晶性粉末~粉末

用途

有機合成触媒。

用途

触媒及び触媒配位子

使用上の注意

不活性ガス封入

化学的特性

White to light yellow crystals

使用

suzuki reaction

反応性

  1. Ligand used for the hydroformylation of alkenes.
  2. Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides.
  3. Ligand used in the intermolecular coupling of amides with aryl halides or triflates.
  4. Ligand used in the coupling of heteroarylamines and aryl halides.
  5. Ligand used in the hydrophosphinylation of alkenes and alkynes.
  6. Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols.
  7. Ligand used for the sulfinylation of aryl iodides.
  8. Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines.
  9. Ligand used for the Ni-cataltzed alkynylcyanation of alkynes.
  10. Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole.
  11. Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes.
  12. Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides.
  13. Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles.
  14. Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes.
  15. Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates.
  16. Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes
  17. Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones.
  18. Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines.
  19. Ligand used for the Cu-catalyzed intermolecular coupling of alkynes with aryl iodides.
  20. Ligand used for the Pd-catalyzed ene-type reaction of aldehydes with 1,3-diene.
  21. Ligand used for the Ru-catalyzed intermolecular addition of 2-phenylbenzoic acid onto unactivated olefins.
  22. Ligand used for the Pd/Cu-catalyzed direct arylation of heteroarenes.
  23. Ligand used for the Pd-catalyzed reaction of propargyl-substituted malonate esters with aryl halides.
  24. Ligand used for the Pd-catalyzed decarboxylative coupling of tertiary cyanoacetate salts with aryl halides and triflates.
  25. Ligand used for the Pd-catalyzed hydroesterification of alkynes.
  26. Ligand used for the Cu-catalyzed arylation of arylboronic acids with aldehydes.
  27. Ligand used for the Ru-catalyzed oxidative synthesis of heterocycles from alcohols.
  28. Ligand used for the Rh-catalyzed borylation of nitriles.
  29. Ligand used in the Pd-catalyzed α-arylation of benzylic phosphine oxides.
  30. Ligand used in the Pd-Catalyzed Oxidative Coupling of Enamides and Alkynes.
  31. Ligand used in the Pd-catalyzed difunctionalization of enol ethers to amino acetals with aminals and alcohols.
  32. Ligand used in the Pd-catalyzed alkoxycarbonylation of α-chloroketones. 

4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン 上流と下流の製品情報

原材料

準備製品


4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン 生産企業

Global( 334)Suppliers
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161265-03-8(4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン)キーワード:


  • 161265-03-8
  • XANT PHOS
  • 4,5-BIS-DIPHENYLPHOSPHANYL-9,9-DIMETHYL-9H-XANTHENE
  • 4,5-BIS(DIPHENYLPHOSPHINO)-9,9-DIMETHYLXANTHENE
  • 9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE
  • (9,9-DIMETHYL-9H-XANTHENE-4,5-DIYL)BIS[DIPHENYL PHOSPHINE]
  • Dimethylbisdiphenylphosphinoxanthene
  • 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, XANTPHOS
  • 4,5-BIS(DIPHENYLPHOSPHINO)-9,9-DIMETHYLX
  • 4,5-Bis(diphenylphosphino)-9,9
  • 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene,min.98%XANTPHOS
  • 9,9-DiMethyl-4,5-bis(diphenylphosphiNA)xanthene
  • Phosphine, (9,9-diMethyl-9H-xanthene-4,5-diyl)bis[diphenyl- (9CI)
  • 9,9-DiMethyl-4,5-bis(diphenylp
  • [5-(diphenylphosphanyl)-9,9-diMethyl-9H-xanthen-4-yl]diphenylphosphane
  • Xantphos, (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane)
  • 4,5-Bis(diphenylphosphino)-9,9-diMethylxanthene 97%
  • 4,5-Bis(diphenylphosphino)-9,9-diMethylxanthene, 97+%
  • DiMethylbisdiphenylphosphinoxanthene SynonyMs 9,9-DiMethyl-4,5-bis(diphenylphosphino)xanthene
  • 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene,98% XantPhos
  • 4,5-Bis(diphenylphosphino)-9,9-dimethyl-xanthene, Dimethylbisdiphenylphosphinoxanthene
  • 4,5- two -9,9- two methyl oxygen hetero
  • Xantphos 97%
  • (2,3-dimethyl-9H-xanthene-1,9-diyl)bis(diphenylphosphine)
  • 4,5-Bis(diphenylphosphino)-9,9-dimethyl xanthenes
  • (5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane
  • (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane)
  • 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
  • 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthenes
  • 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene 99%
  • 9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE99%
  • 4,5-ビス(ジフェニルホスフィノ)-9,9-ジメチルキサンテン
  • キサントホス
  • 4,5‐ビス(ジフェニルホスフィノ)‐9,9‐ジメチルキサンテン
  • 9,9-ジメチル-4,5-ビス(ジフェニルホスフィノ)キサンテン
  • ホスフィン配位子
  • ホスフィン配位子 (鈴木宮浦クロスカップリング)
  • 鈴木―宮浦クロスカップリング反応
  • 有機合成化学
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