1,4-ビス(2,2,2-トリクロロ-1-ホルミルアミノエチル)ピペラジン 化学特性,用途語,生産方法
外観
白色,結晶性粉末～粉末
溶解性
水9mg/l(20℃)。ジメチルホルムアミド,DMSO, N-メチルピロリドンに容易に溶ける。テトラヒドロフランに溶ける。アセトン,ジクロロメタン, メタノール, ジオキサン, シクロヘキサノンにわずかに溶ける。ベンゼン,石油エーテル, シクロヘキサンに溶けない。アセトンに溶け、水にほとんど溶けない。
説明
Triforine is a clear light yellow colour with an ethanol (alcohol) odour and a highly flammable
liquid. It is used as a fungicide for the control of black spot, powdery mildew, and
diseases of rust in roses, fruits, vegetables, cereals, and ornamentals. Application of triforine
acts both as a preventative and a curative fungicide and is known to destroying
diseases already in the plant and also preventing disease infestations. It is also used as
a post-harvest control of brown rot on peaches, nectarines, apricots, cherries, and plums.
使用
Triforine is used to control powdery mildews on cereals, fruits,
vines, hops, ornamentals, cucurbits and some vegetables, rusts on cereals,
fruit, ornamentals and beans. It also controls Munilia spp. on stone
fruit, Ascochyta blight on chrysanthemums, black spot on roses, scab
on apples and fairy rings on turf. Triforine also suppresses tetranychid
mite activity.
定義
ChEBI: A member of the class of N-alkylpiperazines in which the two amino groups of piperazine are replaced by 1-formamido-2,2,2-trichloroethyl groups. A fungicide active against a range of diseases including powdery mildew, scab and rust.
一般的な説明
Colorless crystals. Non corrosive. Used as a fungicide.
反応プロフィール
A piperazine, trichloromethylformamide derivative. Decomposed in strong acid to trichloroacetaldehyde and piperazine salts, and in strongly alkaline media to chloroform and piperazine.
危険性
Low toxicity by ingestion, inhalation, and
skin contact. Human systemic effects.
农业用途
Fungicide: Triforine is a systemic fungicide with protectant,
eridicant, and curative activity. It is locally systemic, is
quickly absorbed by the plant and should be applied on or
before an infection occurs. Triforine is used for control of
black spot, brown rot, scab, petal blight, rust and other diseases on fruits such as apples, peaches, plumbs, nectarines,
apricots, and strawberry; in hops, vegetables, cereals, and
ornamentals such as roses and chrysanthemums. Triforine
breaks down rapidly in the environment. Not approved for
use in EU countries
. Registered for use in the U.S.
製品名
CELA50®; CW524®; DENARIN®
FUNGINEX®; SAPROL®; TRIFORIN®; W524®
接触アレルゲン
This pesticide is widely used in flower growing. Cross-
reactions are expected to dichlorvos.
安全性プロファイル
Low toxicity by
ingestion, inhalation, and skin contact.
Human systemic effects: change in taste
function. When heated to decomposition
emits toxic fumes of NOx and Cl-.
代謝経路
Thermal reaction of triforine with several alcohols in a
closed glass tube gives N-(1-alkoxy-2,2,2-
trichloroethyl) formamides.
1,4-ビス(2,2,2-トリクロロ-1-ホルミルアミノエチル)ピペラジン 上流と下流の製品情報
原材料
準備製品