ChemicalBook
Chinese english Germany Korea

過酸化ベンゾイル (約25%水湿潤品)

過酸化ベンゾイル (約25%水湿潤品) 化学構造式
94-36-0
CAS番号.
94-36-0
化学名:
過酸化ベンゾイル (約25%水湿潤品)
别名:
過酸化ベンゾイル (約25%水湿潤品);ベンゾイルスーパーオキシド;過酸化ベンゾイル;ビスベンゾイルペルオキシド;ペルカドックスS;パノキシル;ペルサドックス;オキシリット;過酸化ジベンゾイル;ジベンゾイルペルオキシド;ルシドール;安息香酸過安息香酸無水物;ベンゾイルペルオキシド;ベンソイルパ-オキサイド;ベンゾイルパーオキサイド;酸化ベンゾイル;過酸化ジベンゾイル (約25%水湿潤品);過酸化ベンゾイル, 75% IN WATER;LUPEROX® AFR40 溶液;フタル酸ジシクロヘキシル配合過酸化ベンゾイル
英語化学名:
Benzoyl peroxide
英語别名:
G20;BPO;Cadet;Garox;Topex;Xerac;Oxy 5;oxy-5;Oxy-L;BZF-60
CBNumber:
CB0484149
化学式:
C14H10O4
分子量:
242.23
MOL File:
94-36-0.mol

過酸化ベンゾイル (約25%水湿潤品) 物理性質

融点 :
105 °C(lit.)
沸点 :
176°F
比重(密度) :
1.16 g/mL at 25 °C(lit.)
屈折率 :
1.5430 (estimate)
闪点 :
>230 °F
貯蔵温度 :
2-8°C
溶解性:
0.35mg/l
外見 :
powder
色:
White
水溶解度 :
Insoluble
Merck :
14,1116
BRN :
984320
暴露限界値:
TLV-TWA 5 mg/m3; IDLH 7000 mg/m3.
安定性::
Strong oxidizer. Highly flammable. Do not grind or subject to shock or friction. Incompatible with reducing agents, acids, bases, alcohols, metals, organic materials. Contact with combustible material, heating or friction may cause fire or explosion.
InChIKey:
OMPJBNCRMGITSC-UHFFFAOYSA-N
CAS データベース:
94-36-0(CAS DataBase Reference)
NISTの化学物質情報:
Benzoyl peroxide(94-36-0)
EPAの化学物質情報:
Peroxide, dibenzoyl(94-36-0)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  O,Xn,N,Xi,E,T
Rフレーズ  8-36/37/38-43-36-2-7-1-51/53-21/22-62-50-61-3-39/23/24/25-40
Sフレーズ  53-17-26-36/37-45-60-36/37/39-3/7-14A-14-47-35-7-61-37/39-24
RIDADR  UN 3108 5.2
WGK Germany  2
RTECS 番号 DM8575000
自然発火温度 176 °F
TSCA  Yes
国連危険物分類  5.2
容器等級  II
HSコード  29163200
有毒物質データの 94-36-0(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: 7710 mg/kg
消防法 危険物第5類
化審法 (3)-1349
安衛法 57-2
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H241 熱すると火災や爆発のおそれ 自己反応性化学品;有機過酸化物 タイプ B 危険 P210, P220, P234, P280, P370+P378,P370+ P380+P375, P403+P235, P411,P420, P501
H242 熱すると火災のおそれ 自己反応性化学品;有機過酸化物 タイプ C, D,タイプ E, F
タイプ G
危険
警告
P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H317 アレルギー性皮膚反応を起こすおそれ 感作性、皮膚 1 警告 P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 強い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 P264, P280, P305+P351+P338,P337+P313P
H335 呼吸器への刺激のおそれ 特定標的臓器毒性、単回暴露; 気道刺激性 3 警告
H361 生殖能または胎児への悪影響のおそれの疑い 生殖毒性 2 警告 P201, P202, P281, P308+P313, P405,P501
H400 水生生物に強い毒性 水生環境有害性、急性毒性 1 警告 P273, P391, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P201 使用前に取扱説明書を入手すること。
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P220 衣類/.../可燃物から遠ざけること。
P234 他の容器に移し替えないこと。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P308+P313 暴露または暴露の懸念がある場合:医師の診断/手当てを 受けること。
P370+P378 火災の場合:消火に...を使用すること。
P410 日光から遮断すること。
P412 500C 以上の温度に暴露しないこと。
P420 他の物質から離して保管すること。

過酸化ベンゾイル (約25%水湿潤品) 価格 もっと(18)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01AFAL13174 過酸化ベンゾイル, 75% in water
Benzoyl peroxide, 75% in water
94-36-0 50g ¥3870 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01AFAL13174 過酸化ベンゾイル, 75% in water
Benzoyl peroxide, 75% in water
94-36-0 250g ¥7640 2018-12-26 購入
東京化成工業 B3152 過酸化ベンゾイル (約25%水湿潤品) >75.0%(T)
Benzoyl Peroxide (wetted with ca. 25% Water) >75.0%(T)
94-36-0 25g ¥2500 2018-12-04 購入
関東化学株式会社(KANTO) 21178-1A 過酸化ベンゾイル 75%
Benzoyl peroxide 75%
94-36-0 5g ¥4500 2018-12-13 購入
関東化学株式会社(KANTO) 21178-2A 過酸化ベンゾイル 75%
Benzoyl peroxide 75%
94-36-0 1kg ¥35300 2018-12-13 購入

過酸化ベンゾイル (約25%水湿潤品) MSDS


Perkadox L

過酸化ベンゾイル (約25%水湿潤品) 化学特性,用途語,生産方法

定義

本品は、次の化学式で表される過酸化物である。

用途

小麦粉?油脂?蝋などの漂白剤、重合触媒、硬化剤、ポリマー架橋剤、医薬?化粧品、ゴム配合剤、乾燥剤、食品添加物(小麦粉等改良剤)

化粧品の成分用途

抗アクネ剤、人工爪剤

効能

抗ニキビ薬, 角質溶解薬

商品名

ベピオ (マルホ)

化学的特性

white powder or crystals

化学的特性

Benzoyl peroxide is an odorless, white or colorless crystalline powder.

使用

Benzoyl peroxide is used as a source offree radicals in many organic syntheses andto initiate polymerizations of styrene, vinylchloride, vinyl acetate, and acrylics; to curethermoset polyester resins and silicone rubbers;in medicine for treating acne; and forbleaching vegetable oil, cheese, flour, and fats.

使用

vitamin B complex

使用

Benzoyl Peroxide is a widely used organic compound of the peroxide family. Benzoyl Peroxide is often used in acne treatments , bleaching and polymerizing polyester and many other uses.

使用

Source of free radicals for industrial processes. Oxidizing agent in bleaching oils, flour, etc.; catalyst in the plastics industry; initiator in polymerization.

使用

benzoyl peroxide is an antibacterial ingredient commonly used in acne treatments. It functions by forcing an oxidant (peroxide in this case) into the philosebaceous orifice where it releases oxygen, thereby diminishing the P. acnes population. This reduces the level of free fatty acids and skin infection. Benzoyl peroxide may cause skin irritation in people with sensitive skin.

使用

Benzoyl Peroxide is a colorless, crystalline solid with a faint odor of benzaldehyde resulting from the interaction of benzoyl chloride and a cooled sodium peroxide solution. it is insoluble in water. it is used in specified cheeses at 0.0002% of milk level. it is used for the bleaching of flour, slowly decomposing to exert its full bleaching action, which results in whiter flour and bread.

適応症

Benzoyl peroxide is a potent oxidizing agent that has both antimicrobial and comedolytic properties; its primary use is in treating acne vulgaris. It is converted in the skin to benzoic acid; clearance of absorbed drug is rapid, and no systemic toxicity has been observed. The major toxicities are irritation and contact allergy. Outgrowth of bacteria resistant to topical antibiotics used to treat acne can be reduced by the addition of benzoyl peroxide in combination products such as erythromycin (Benzamycin) and clindamycin (Benzaclin).

brand name

Acne-Aid Cream (Stiefel); Benoxyl (Stiefel); Benzac (Galderma); Benzac W (Galderma); Brevoxyl (Stiefel); Clear By Design (SmithKline Beecham); Dry and Clear (Whitehall-Robins); Epi-Clear (Bristol-Myers Squibb); Fostex BPO Bar, Gel, and Wash (Bristol-Myers Products); Loroxide (Dermik); PanOxyl (Stiefel); Persa-Gel (Ortho Pharmaceutical); Vanoxide (Dermik);Altex.

世界保健機関(WHO)

Benzoyl peroxide slowly releases oxygen and hence is bactericidal. It is also keratolytic, antiseborrheic and irritant. It is used in the treatment of acne. Benzoyl peroxide is listed in the WHO Model List of Essential Drugs.

一般的な説明

White, odorless powder, moderately toxic.

空気と水の反応

Insoluble in water.

反応プロフィール

Benzoyl peroxide reacts exothermically withstrong acids, strong bases, amines, reducingagents, and sulfur compounds. Explosionshave been reported when it reacted withcarbon tetrachloride and ethylene (Bolt andJoyce 1947), lithium aluminum hydride(Sutton 1951), N,N-dimethyl aniline (Hornerand Betzel 1953), hot chloroform (NFPA1986), and methyl methacrylate (NFPA1986). Lappin (1948) reported an explosionwhen a bottle was opened. Organic matterentrapped in the threads of the bottleprobably reacted explosively with benzoylperoxide.

危険性

Highly toxic via inhalation. May explode spontaneously when dry (<1% of water). Never mix unless at least 33% water is present. Skin and upper respiratory tract irritant. Questionable carcinogen.

健康ハザード

The health hazard from benzoyl peroxideis low. It can cause irritation of the skin,mucous membranes, and eyes. An intraperitonealinjection of 250 mg/kg was lethal toadult mice. Systemic toxicity in humans isnot known. It may be mild to moderatelytoxic on an acute basis. The oral LD50 valuein rats is 7710 mg/kg (NIOSH 1986). Itstoxicity from inhalation is low; an LC50 valueof 700 ppm in mice is suggested (ACGIH1986).
Benzoyl peroxide may cause gene damageand DNA inhibition. It has been foundto cause skin tumor. The evidence of its carcinogenicityin animals and humans is inadequate.

火災危険

Benzoyl peroxide can cause a major fire and explosion hazard. It is highly flammable and a strong oxidizer; autoignition temperature 80°C (176°F). It ignites instantly. The rate and violence of decomposition and the potential ease of such ignition or decomposition have been experimentally measured by Noller et al. (1964). Lead pipe deformation (LPD), pressure vessel test (PVT), and self-accelerating decomposition test (SADT) have been performed to measure these explosive characteristics. Heating 5 g of benzoyl peroxide in an aluminum tester containing an aperture vent and 6-atm rupture disk, caused the disk to blow up in 95 seconds when the aperture vent area was less than 174.7 mm2. Redried material was more violent. The decomposition hazard was greatly reduced with wet and diluted benzoyl peroxide.
Noller et al. (1964) measured the SADT temperature at 82.2°C (180°F), above which the decomposition was self-accelerating, sudden, and produced smoke.
Benzoyl peroxide is a deflagrant, posing a severe explosion hazard. The compound is sensitive to heavy shock, such as impact or blows, as well as to friction and heat. Especially in the dry state, it is highly dangerous.
A water sprinkler should be used to extinguish fires. Water should be used to keep the containers cool.

接触アレルゲン

Benzoyl peroxide is an oxidizing agent widely employed in acne topical therapy. It is also used as a polymerization catalyst of dental or industrial plastics and as a decolorizing agent of flours, oils, fats, and waxes. Irritant or allergic dermatitis may affect workers in the electronics and plastics (epoxy resins and catalysts) industries, electricians, ceramic workers, dentists and dental technicians, laboratory technicians, bakers, and acne patients. As it was contained in candles, it also induced contact dermatitis in a sacristan. Patch tests may be irritant.

職業ばく露

Used as polymerization initiator, curing agent, and cross-linking agent.

Veterinary Drugs and Treatments

Benzoyl peroxide products are used topically either as gels or in shampoos. Shampoos are generally used for seborrheas, greasy skin (seborrhea oleosa), or crusty pyodermas (such as seborrheic dermatitis/pyoderma commonly seen in Cocker Spaniels). Gels may be useful for treating recurrent localized skin infections (e.g., chin acne), localized Demodex lesions, superficial and deep pyodermas (adjunctive therapy), seborrhea oleosa, and Schnauzer comedo syndrome. Benzoyl peroxide possesses antimicrobial (especially antibacterial), keratolytic and antiseborrheic actions. It also is It has some mild antipruritic activity and wound healing effects, and is thought to increase follicular flushing. Benzoyl peroxide’s antimicrobial activity is due to the oxidative benzoyl peroxy radicals formed that disrupt cell membranes.

貯蔵

Benzoyl peroxide should be stored in acool and well-ventilated area, isolated fromother chemicals and free of heating andelectrical installations. Dry compound maybe shipped in polyethylene-lined paper bagsor fiber containers packed in wooden boxeso.

輸送方法

UN3104 : Organic peroxide type C, solid, Hazard Class: 5.2; Labels: 5.2—Organic peroxide, Technical Name Required. UN3108 : Organic peroxide type E, solid, Hazard Class: 5.2; Labels: 5.2—Organic peroxide, Technical

純化方法

Dissolve benzoyl peroxide in CHCl3 at room temperature and precipitate it by adding an equal volume of MeOH or pet ether. Similarly it is precipitated from acetone by adding two volumes of distilled water. It has also been crystallised from 50% MeOH and from diethyl ether. Dry it under vacuum at room temperature for 24hours. Store it in a desiccator in the dark at 0o. When purifying in the absence of water it can be EXPLOSIVE, and operations should be done on a very small scale with adequate protection. Large amounts should be kept moist with water and stored in a refrigerator. [Kim et al. J Org Chem 52 3691 1987, Beilstein 9 IV 777.]

不和合性

May explode when heated above melting point, 103 C. A strong oxidizer. Extremely explosionsensitive to heat, shock, friction, and concussion. May explode or cause fire on contact with reducing agents; combustible substances, organic substances, wood, paper, metal powders, lithium aluminum hydride. Violent reaction with alcohols, organic and inorganic acids, and amines.

廃棄物の処理

Pretreatment involves decomposition with sodium hydroxide. The final solution of sodium benzoate, which is very biodegradable, may be flushed into the drain. Disposal of large quantities of solution may require pH adjustment before release into the sewer or controlled incineration after mixing with a noncombustible material.

過酸化ベンゾイル (約25%水湿潤品) 上流と下流の製品情報

原材料

準備製品


過酸化ベンゾイル (約25%水湿潤品) 生産企業

Global( 245)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
GIHI CHEMICALS CO.,LIMITED
08657186217390
sales@gihichemicals.com CHINA 308 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 sales@guangaobio.com CHINA 23049 58
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19917 60
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 2763 55
Tianjin Zhongxin Chemtech Co., Ltd.
022-89880739
022-66880086 sales@tjzxchem.com CHINA 575 58
Yancheng Green Chemicals Co.,Ltd
86-515-87883661
86-515-87883652 sales@greenchem-china.com CHINA 348 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 27142 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23962 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8260 58

94-36-0(過酸化ベンゾイル (約25%水湿潤品))キーワード:


  • 94-36-0
  • Benzoyl peroxide[51% < content ≤100%, inert solid content ≤48%]
  • Benzoyl peroxide[35% < content ≤52%, inert solid content ≥48%]
  • Benzoyl peroxide[36% < content ≤42%, type A diluent ≥18%, water content ≤40%]
  • Benzoyl peroxide[77% < content ≤94%, water content ≥6%]
  • Benzoyl peroxide[content ≤42%, stable dispersion in water]
  • Benzoyl peroxide[content ≤62%, inert solid content ≥28%, water content ≥10%]
  • Benzoyl peroxide[content ≤77%, water content ≥23%]
  • Benzoyl peroxide[paste,52% < content ≤62%]
  • Benzoyl peroxide[paste, no more than 52%]
  • Benzoyl peroxide[paste, content ≤56.5%, water content ≥15%]
  • Benzoyl peroxide[content ≤35%, inert solids ≥65%]
  • benzoicacid,peroxide
  • benzoicacidperoxide
  • Benzol peroxide
  • Benzoyl
  • Benzoyl peroide
  • Benzoylperoxid
  • Benzoylperoxyde
  • Brevoxyl
  • BZF-60
  • cadatbpo
  • Cadet
  • Cadet BPO-70W
  • Cadox 40E
  • Cadox BPO-W40
  • Cadox bs
  • Cadox BTA
  • Cadox BTW-50
  • cadoxb-ch50
  • cadoxbs
  • 過酸化ベンゾイル (約25%水湿潤品)
  • ベンゾイルスーパーオキシド
  • 過酸化ベンゾイル
  • ビスベンゾイルペルオキシド
  • ペルカドックスS
  • パノキシル
  • ペルサドックス
  • オキシリット
  • 過酸化ジベンゾイル
  • ジベンゾイルペルオキシド
  • ルシドール
  • 安息香酸過安息香酸無水物
  • ベンゾイルペルオキシド
  • ベンソイルパ-オキサイド
  • ベンゾイルパーオキサイド
  • 酸化ベンゾイル
  • 過酸化ジベンゾイル (約25%水湿潤品)
  • 過酸化ベンゾイル, 75% IN WATER
  • LUPEROX® AFR40 溶液
  • フタル酸ジシクロヘキシル配合過酸化ベンゾイル
  • 過酸化ベンゾイル (JAN)
  • 有機過酸化物
  • 有機合成化学
  • 重合開始剤
Copyright 2017 © ChemicalBook. All rights reserved