(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル

(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル 化学構造式
102851-06-9
CAS番号.
102851-06-9
化学名:
(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル
别名:
N-[2-クロロ-4-(トリフルオロメチル)フェニル]-D-バリンα-シアノ-3-フェノキシベンジル;(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル;タウフルバリナート;N-[2-クロロ-4-(トリフルオロメチル)フェニル]-D-バリンシアノ(3-フェノキシフェニル)メチル;Tau-フルバリナート;αシアノ3フェノキシベンジル=N(2クロロα,α,αトリフルオロpトリル)Dバリナト;フルバリネート;Τ-フルバリネート;Τ-フルバリネート STANDARD;τ-フルバリネート Standard, 100 µg/mL in Acetonitrile;τ-フルバリネート Standard, 100 µg/mL in MeOH;τ-フルバリネート Standard, 1000 µg/mL in MeOH;τ?フルバリネート;タウ?フルバリネート
英語名:
Tau-fluvalinate
英語别名:
t-Fluvalinate;Mavric;MK 128;Apistan;Tau-fluvalite;τ-Fluvalinate;au-fluvalinate;tau-fluvaliate;TAO-FLUVALINATE;Tau-fluvalinate
CBNumber:
CB0498483
化学式:
C26H22ClF3N2O3
分子量:
502.91
MOL File:
102851-06-9.mol
MSDS File:
SDS

(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル 物理性質

沸点 :
450°C
比重(密度) :
1.2900
蒸気圧:
9×10-11 Pa (25 °C)
闪点 :
90 °C
貯蔵温度 :
Sealed in dry,Room Temperature
溶解性:
DMF: 10 mg/ml,DMSO: 10 mg/ml,Ethanol: 10 mg/ml
水溶解度 :
0.001 mg l-1 (20 °C)
酸解離定数(Pka):
-1.16±0.50(Predicted)
BRN :
8092907
LogP:
7.310 (est)
CAS データベース:
102851-06-9(CAS DataBase Reference)
EPAの化学物質情報:
Tau-fluvalinate (102851-06-9)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn,N
Rフレーズ  22-38-50/53
Sフレーズ  24-59-61
RIDADR  UN2810 6.1/PG 3
WGK Germany  3
HSコード  29269090
絵表示(GHS) GHS hazard pictogramsGHS hazard pictograms
注意喚起語 警告
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H302 飲み込むと有害 急性毒性、経口 4 警告 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書き
P273 環境への放出を避けること。
P501 内容物/容器を...に廃棄すること。

(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル 価格 もっと(5)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-356S τ-フルバリネート Standard
Tau-Fluvalinate Standard, 100 ug/mL in MeOH
102851-06-9 1mL ¥14200 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-356N τ-フルバリネート
Tau-Fluvalinate
102851-06-9 10mg ¥14200 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) 99053309 フルバリネート(タウフルバリネート) 標準品
Fluvalinate(Tau-fluvalinate) 標準品
102851-06-9 100mg ¥20000 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-356S-CN τ-フルバリネート Standard
Tau-Fluvalinate Standard, 100 ug/mL in Acetonitrile
102851-06-9 1mL ¥14200 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-356S-10X τ-フルバリネート Standard
Tau-Fluvalinate Standard, 1000 ug/mL in MeOH
102851-06-9 1mL ¥24500 2024-03-01 購入

(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル 化学特性,用途語,生産方法

説明

Fluvalinate is a viscous, yellow oil in appearance. It is very soluble in organic solvents and aromatic hydrocarbons and insoluble in water. It is a synthetic pyrethroid. It is used as a broad-spectrum insecticide against moths, beetles, fleas, turf and ornamental insects, and other insect pests on cotton, cereal, grape, potato, fruit tree, vegetable, and plantation crops. It is available in emulsifiable concentrates, suspensions, and flowable formulations. Fluvalinate is a moderately toxic compound in the U.S. EPA toxicity class II. Some formulations may have the capacity to cause corrosion of the eyes. Pesticides containing fluvalinate must bear the signal word DANGER on the product label. Fluvalinate is classified as an RUP because of its high toxicity to fish and aquatic invertebrates.

化学的特性

Yellow viscous liquid

使用

Fluvalinate is used to control a wide range of insects and spider mites on fruit trees, vines, vegetables, cereals, cotton, tea, tobacco, ornamentals and other crops. It is also used for parasite control in bee hives.

定義

ChEBI: The (2R) diastereomers of fluvalinate. A synthetic pyrethroid insecticide, it is used to control varroa mites in honey bee colonies.

健康ハザード

Exposures to fl uvalinate cause coughing, sneezing, throat irritation, itching, or burning sensations on the arms or face with or without a rash, headache, and nausea. Prolonged period of exposures to pyrethroids cause adverse effects on the CNS, liver, and kidneys. Fluvalinate is slightly toxic to birds.

職業ばく露

Pyrethroid insecticide used as a broad spectrum insecticide to control moths, beetles and other pests on cereals, potatoes, fruit trees, vegetables, fleas, cot ton, turf and ornamentals. It is also used to control varroa mites in honey bees. Some applications may be classified as a United States Environmental Protection Agency Restricted Use Pesticide (RUP). Formerly used as an insec ticide. Production discontinued by Sandoz Agro, Inc. Incompatibilities: Corrosive to some metals. Keep away from strong oxidizers and alkaline materials. Decomposes in temperatures above 350℃ releasing toxic vapors of hydrogen chloride, nitrogen oxides, and hydrogen fluoride.

代謝経路

The information reported below is derived from studies on fluvalinate, the racemic m-valinate (CASRN 69409-94-5). This has been superseded by the D-isomer. Evidence is given below to show that the results derived from fluvalinate are relevant to tau-fluvalinate. The chemical and photochemical degradation of fluvalinate and its degradation in soils have been reported. Information on metabolism in plants, rats, monkeys, cows and chickens is also published. The metabolism of fluvalinate is dominated by hydrolysis followed by oxidation and conjugation of the metabolites. Novel bile acid conjugates are highlighted. All quantitative data reported below are for the lower of usually two doses.

貯蔵

Fluvalinate should be kept stored only in its original container at a temperature not exceeding 40°C. It should be kept away from food, drink, and animal feedstuffs.

輸送方法

UN2902 Pesticides, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

廃棄物の処理

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

予防処置

Occupational workers should avoid contact of fl uvalinate with the skin and eyes and avoid breathing contaminated fumes. Wear suitable protective clothing, nitrile rubber gloves, and safety glasses or a face shield. Fluvalinate is an RUP and should be used, handled, and/or purchased only by certifi ed applicators.

(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル 上流と下流の製品情報

原材料

準備製品


(R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル 生産企業

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102851-06-9((R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル)キーワード:


  • 102851-06-9
  • tau-fluvalinate (bsi,e-iso)
  • Cyano-(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate
  • Tau-fluvalinate
  • TAO-FLUVALINATE
  • (RS)-alpha-Cyano-3-phenoxybenzyl N-(2-chloro-a,a,a-trifluoro-p-tolyl)-D-valinate
  • (RS)-a-Cyano-3-phenoxybenzyl-N-(2-chloro-a.a.a-trifluoro-p-tolyl)-D-valina
  • τ-Fluvalinate solution,100ppm
  • Tau-fluvalite
  • tau-fluvalinate cyano-(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate
  • Apistan
  • Mavric
  • MK 128
  • N-(2-chloro-4-trifluoromethylphenyl)-DL-2-valine(alpha) cyano-(3-phenoxy-phenyl) methyl ester
  • N-[2-Chloro-4-(trifluoromethyl)phenyl]-D-valine cyano(3-phenoxyphenyl)methyl ester
  • N-[2-Chloro-4-(trifluoromethyl)phenyl]-D-valine α-cyano-3-phenoxybenzyl ester
  • (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methyl-butyric acid [cyano-[3-(phenoxy)phenyl]methyl] ester
  • [cyano-[3-(phenoxy)phenyl]methyl] (2R)-2-[[2-chloro-4-(trifluoromethyl)phenyl]amino]-3-methyl-butanoate
  • [cyano-[3-(phenoxy)phenyl]methyl] (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate
  • tau-Fluvalinate 100mg [102851-06-9]
  • Mavrik,τ-Fluvalinate, N-[2-Chloro-4-(trifluoromethyl)phenyl]-D-valine (RS)-cyano(3-phenoxyphenyl)methyl ester,
  • TAU-FLUVALINATE 250MG
  • TAU-FLUVALINATE PESTANAL, 250 MG
  • MAVRIK, 100MG, NEAT
  • (alpha-RS,2R)-Fluvalinate
  • D-Valine, N-2-chloro-4-(trifluoromethyl)phenyl-, cyano(3-phenoxyphenyl)methyl ester
  • n-[2-chloro-4-(trifluoromethyl)phenyl]-d-valine (rs)-cyano(3-phenoxyphenyl)methyl ester
  • tau-fluvalinateSolution,100mg/L,1ml
  • τ-Fluvalinate (Mixture of Diastereomers)
  • Tau-Fluvalinate @100 μg/mL in MeOH
  • Tau-Fluvalinate @1000 μg/mL in MeOH
  • N-[2-クロロ-4-(トリフルオロメチル)フェニル]-D-バリンα-シアノ-3-フェノキシベンジル
  • (R)-2-[[2-クロロ-4-(トリフルオロメチル)フェニル]アミノ]-3-メチルブタン酸シアノ(3-フェノキシフェニル)メチル
  • タウフルバリナート
  • N-[2-クロロ-4-(トリフルオロメチル)フェニル]-D-バリンシアノ(3-フェノキシフェニル)メチル
  • Tau-フルバリナート
  • αシアノ3フェノキシベンジル=N(2クロロα,α,αトリフルオロpトリル)Dバリナト
  • フルバリネート
  • Τ-フルバリネート
  • Τ-フルバリネート STANDARD
  • τ-フルバリネート Standard, 100 µg/mL in Acetonitrile
  • τ-フルバリネート Standard, 100 µg/mL in MeOH
  • τ-フルバリネート Standard, 1000 µg/mL in MeOH
  • τ?フルバリネート
  • タウ?フルバリネート
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