バソフェナントロリンジスルホン酸二ナトリウム水和物 化学特性,用途語,生産方法
化学的特性
slightly pinkish-beige powder
使用
Bathophenanthrolinedisulfonic acid disodium salt trihydrate was used in double electrochemical covalent coupling method for the fabrication of sensitive amperometric immunosensor, which was based on electro-click chemistry and diazonium chemistry. It was also used in an experimental study based upon, correlating the iron content with the activity, preparation and reconstituting the apoenzyme phenylamine hydroxylase.
定義
ChEBI: An organic sodium salt having 4,7-diphenyl-1,10-phenanthroline 4',4''-disulfonate as the counterion.
一般的な説明
Bathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.
純化方法
Dissolve crude sample in the minimum volume of water and add EtOH to precipitate the contaminants. Carefully evaporate the filtrate to obtain pure material. It forms a dark red complex with Fe2+ with 535nm ( 2.23 x 104mol-cm -1) [Imasaka et al. Anal Chim Acta 115 407 1980]. It is prepared by sulfonating bathophenanthroline with ClSO3H: to 100g of bathophenanthroline is added 0.5mL of Fe free ClSO3H and heated over a flame for 30seconds. Cool and carefully add 10mL of pure distilled H2O and warm on a water bath with stirring till all solid dissolves. A stock solution is made by diluting 3mL of this reagent to 100mL with 45% aqueous NaOAc, filter off the solid and store in a dark bottle. In this way it is stable for several months. [Landers & Bennie Am J Clinical Pathology 29 590 1958.]
バソフェナントロリンジスルホン酸二ナトリウム水和物 上流と下流の製品情報
原材料
準備製品