トリメチロールプロパントリアクリラート 化学特性,用途語,生産方法
外観
無色～うすい黄色～うすい黄赤色透明液体
定義
本品は、次の化学式で表されるトリエステルである。
用途
中間物、有機化学製品、合成樹脂、希釈剤、光重合時の架橋剤、紫外線硬化型インキ、ゴム?合成樹脂改質剤
化粧品の成分用途
ヘアコンディショニング剤、ヘアスタイリング剤、皮膜形成剤
主な用途／役割
反応性アクリル系樹脂の希釈剤として使用される。
説明
Trimethylolpropane triacrylate (TMPTA) is a multifunctional
acrylie monomer. It reacts with propyleneimine
to form polyfunctional aziridine. Sensitization
was observed in a textile fabric printer. Patch tests
were positive with the polyfunctional aziridine hardener,
but were negative to TMPTA. TMPTA caused
contact dermatitis in an optic-fiber manufacturing
worker and was reported as a sensitizer in a floor top
coat or in photopolymerizable inks.
化学的特性
Colorless viscid liquid
使用
Trimethylolpropane triacrylate has important properties like low volatility, resistance against weather, chemical, water and abrasion, and immediate curing property. The above mentioned properties prompted its use in the production of adhesives, plastics, sealant chemicals, paint additives, photosensitive chemicals, ink and toner. It finds application in alkyd coatings, dental polymers, compact discs, hardwood floors, concrete polymers, screen printing, elastomers, automobile headlamps, acrylics and plastic components for the medical industry.
製造方法
Synthesis of trimethylolpropane triacrylate: 2.44 kg of trimethylolpropane, 3.93 kg of acrylic acid, 0.5 kg of an acid ion exchanger (Lewatit 3333 of BAYER AG), 9 g of hydroquinone and 1.5 liters of petroleum ether (boiling range 60° to 70° C) were heated under a water separator, whilst stirring, in a 10 liter three-necked flask equipped with a stirrer, water separator and gas inlet tube. At the same time, a constant stream of air saturated with allyl alcohol was passed through the flask at a rate of 2 liters/hour. In total, 16 ml of allyl alcohol were introduced into the esterification mixture in this way. After 80 hours, the reaction mixture had an acid number of 32 and the boiling point had risen to 72° C. The petroleum ether was distilled off, remnants being removed by applying a vacuum of 0.2 mm Hg at a product temperature of 40° C. The esterification catalyst was separated off by filtration and was kept for further use. The trimethylolpropane triacrylate obtained in practically quantitative yield was pale yellowish and clear. The viscosity corresponded to a time of outflow of 20 seconds measured in a DIN cup 4 at 20° C. The product showed no change even on storage for 4 months at 60° C. When used in a UV light-curing printing ink which contained a photoinitiator, the product polymerised at high speed.
Literature source US04059721
トリメチロールプロパントリアクリラート 上流と下流の製品情報
原材料
準備製品