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メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル

メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル 化学構造式
2032-65-7
CAS番号.
2032-65-7
化学名:
メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル
别名:
メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル;メトメルカプツロン;トラザ;ドラザ;メルカプトジメツル;メチオカーブ;メトメルカプトロン;メチオカルブ;メスロール;メスロールフェノール;N-メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル;メスロール50;メルカプトジメツル標準品;メチオカルブ標準品;CS_N-12398-100MG_メチオカルブメルカプトジメツルスルホン;メルカプトジメツル メチオカルブ;メチオカルブ IN ACETONITRILE;メチオカルブ STANDARD;メチオカルブ Standard, 100 µg/mL in MeOH;メチオカルブ, 0.1 mg/mL in Acetonitrile
英語化学名:
Mercaptodimethur
英語别名:
Club;MXMC;OMS93;H 321;Draza;b37344;certan;dcr736;Esurol;sd9228
CBNumber:
CB1254073
化学式:
C11H15NO2S
分子量:
225.31
MOL File:
2032-65-7.mol

メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル 物理性質

融点 :
119°C
比重(密度) :
1.1838 (rough estimate)
蒸気圧:
1.5 x 10-5 Pa (20 °C)
屈折率 :
1.4790 (estimate)
貯蔵温度 :
0-6°C
Boiling Point:
310.7±42.0 °C(Predicted)
Density:
1.14±0.1 g/cm3(Predicted)
Melting Point:
119 °C
酸解離定数(Pka):
12.16±0.46(Predicted)
Boiling Point:
310.7±42.0 °C(Predicted)
Density:
1.14±0.1 g/cm3(Predicted)
Melting Point:
119 °C
酸解離定数(Pka):
12.16±0.46(Predicted)
外見 :
Crystalline Solid
色:
White
水溶解度 :
Insoluble
BRN :
1881431
CAS データベース:
2032-65-7(CAS DataBase Reference)
NISTの化学物質情報:
4-Methylthio-3,5-xylyl methylcarbamate(2032-65-7)
EPAの化学物質情報:
Phenol, 3,5-dimethyl-4-(methylthio)-, methylcarbamate(2032-65-7)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T;N,N,T
Rフレーズ  25-50/53
Sフレーズ  22-37-45-60-61
RIDADR  UN 2811/2757
WGK Germany  3
RTECS 番号 FC5775000
国連危険物分類  6.1(a)
容器等級  II
有毒物質データの 2032-65-7(Hazardous Substances Data)
毒性 LD50 in male, female rats (mg/kg): 70, 60 orally (Gaines)
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 P264, P270, P301+P310, P321, P330,P405, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P264 取扱い後は皮膚をよく洗うこと。
P264 取扱い後は手や顔をよく洗うこと。
P273 環境への放出を避けること。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。
P501 内容物/容器を...に廃棄すること。

メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル 価格 もっと(10)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-531-11 メチオカルブ in Acetonitrile
Methiocarb in Acetonitrile, 0.1 mg/mL in Acetonitrile
2032-65-7 1mL ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-632-11 メチオカルブ in Acetonitrile
Methiocarb in Acetonitrile, 0.1 mg/mL in Acetonitrile
2032-65-7 1mL ¥4400 2018-12-26 購入
関東化学株式会社(KANTO) 49801-45 メチオカルブ標準品
Methiocarb standard
2032-65-7 100mg ¥13000 2018-12-13 購入
Sigma-Aldrich Japan 36152 PESTANAL?, analytical standard
Methiocarb PESTANAL?, analytical standard
2032-65-7 100mg ¥9900 2018-12-25 購入
林純薬工業株式会社 99057456 CS_N-12398-100MG_メチオカルブメルカプトジメツルスルホン
CS_N-12398-100MG_Methiocarb Mercaptodimethur
2032-65-7 100mg ¥10000 2018-12-15 購入

メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル 化学特性,用途語,生産方法

農薬用途

殺虫剤

化学的特性

Methiocarb is a colorless crystalline powder.

使用

Insecticide, acaricide and bird repellent.

使用

Insecticide; molluscicide; bird repellent.

使用

Methiocarb is an insecticide, molluscicide and acaricide with contact and stomach action. It is used to control slugs, snails and insects in a wide range of crops. Soil insects are controlled. Methiocarb is also used as a seed-treatment and bird repellent.

定義

ChEBI: A carbamate ester obtained by the formal condensation of the phenolic group of 3,5-dimethyl-4-(methylsulfanyl)phenol with the carboxy group of methylcarbamic acid.

一般的な説明

White crystalline powder with a mild odor. Used as an insecticide and immobilizing agent for birds, acaricide and molluscicide.

反応プロフィール

Mercaptodimethur is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

健康ハザード

As a carbamate insecticide, Mercaptodimethur is a reversible cholinesterase inhibitor and acts on the nervous system. It is classified as very toxic, and the probable oral lethal dose for humans is 50-500 mg/kg or between 1 teaspoon and 1 ounce for a 150 lb. adult.

健康ハザード

Highly toxic cholinesterase inhibitor; exhibitsacute, delayed and chronic effects; routesof entry — ingestion, skin absorption andinhalation of vapors; reversible action ofshort duration; toxic symptoms includesalivation, lacrimation, bradycardia, blurredvision, labored breathing, headache, muscle twitching, tremor, and slight paralysis;gastrointestinal effects include nausea, vomiting, abdominal pain, and diarrhea; severepoisoning may lead to convulsions and coma;oral intake of probably 5–10 g may be fatalto adult humans.
LD50 oral (rat): 15–20 mg/kg
LD50 oral (guinea pig): 40 mg/kg
LD50 skin (rat): 350 mg/kg
LD50 skin (wild bird): 100 mg/kg.

火災危険

When heated to decomposition, Mercaptodimethur emits very toxic fumes of nitrogen and sulfur oxides.

农业用途

Acaricide, Molluscicide, Insecticide: Used to control slugs and snails, soil insects and spider mites in pome fruit, stone fruit, hops, strawberries, potatoes, beets, maize, vegetables and ornamentals. Also used as seed treatment to control fruit flies on maize and bird repellant on berries and cherries. Methiocarb producers deleted all food uses from their product labels between 1989-92. It is A U.S. EPA restricted Use Pesticide (RUP) except for residential application.

製品名

AI3-25726®; ALCO SLUB”M[C]; B 37344®; BAY 5024®; BAY 9026®; BAY 37344®; BAYER 37344®; DCR 736®; DRAZA®; DRAZA G MICROPELLETS®; H 321®; MESUROL®; METHIOCARBE®; OMS- 93®; PBI SLUG GARD®; PROVADA®; SD 9228®; SLUG-GETA®[C]

接触アレルゲン

Methiocarb is an insecticide or molluscicide with a cholinesterase inhibiting effect. A case of contact dermatitis was reported in a carnation grower.

安全性プロファイル

Poison by ingestion, skin contact, and intraperitoneal routes. Used as an insecticide, molluscicide, and bird repellent. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also ESTERS and CARBAMATES.

職業ばく露

A potential danger to those involved in the manufacture, formulation, and application of this nonsystemic acaricide and insecticide.

環境運命予測

Soil. Methiocarb was oxidized, probably by singlet oxygen, to the corresponding sulfoxide and trace amounts (<5% yield) of sulfone when sorbed on soil and exposed to sunlight. The photosensitized oxidation was faster in soils containing the lowest organic carbon content (Gohre and Miller, 1986).
Plant. On and/or in bean plants, the methylthio group is rapidly oxidized to the sulfoxide and sulfone (Abdel-Wahab et al., 1966) followed by hydrolysis yielding the corresponding thiophenol, methylsulfoxide phenol and methylsulphonyl phenol (Har
Photolytic. When methiocarb in ethanol was irradiated by UV light, only a few unidentified cholinesterase inhibitors were formed (Crosby et al., 1965).
Chemical/Physical. Emits toxic fumes of nitrogen and sulfur oxides when heated to decomposition (Sax and Lewis, 1987).

代謝経路

Methiocarb is oxidised to a sulfoxide and a sulfone in biological media. The resulting two carbamate esters and the parent compound are hydrolysed in soils and plants to the corresponding phenols. Hydroxylation of the N-methyl group on the carbamate function occurs in mammalian preparations in vitro.

輸送方法

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Degradation

Methiocarb is unstable in alkaline solution. Its DT50 values at pH 4,7 and 9 (22 °C) are >1 year, 35 days and 6 hours, respectively. Photodegradation (DT50 6-16 days) contributes to the loss of methiocarb from the environment (PM).
River water containing methiocarb was stored in sunlight or artificial light. Samples were taken and analysed by TLC. Methiocarb was rapidly hydrolysed (half-life 3 days) to the phenol (2) which itself degraded (Eichelberger and Lichtenberg, 1971).

廃棄物の処理

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. Remove material with contaminated soil and place in impervious containers. May be incinerated in a pesticide incinerator at the specified temperature/dwell-time combination. Any liquids, sludges, or solid residues generated should be disposed of in accordance with all applicable federal, state, and local pollution control requirements. If appropriate incineration facilities are not available, material may be buried in a chemical waste landfill. May be amenable to biological treatment at a municipal sewage treatment plant. (Sax/DPIMR).

メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル 上流と下流の製品情報

原材料

準備製品


メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル 生産企業

Global( 61)Suppliers
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Mainchem Co., Ltd.
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Hubei Jusheng Technology Co.,Ltd.
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027-59599243 sales@jushengtech.com CHINA 28236 58
Xiamen AmoyChem Co., Ltd
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
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Shanghai T&W Pharmaceutical Co., Ltd. +86 21 61551611
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2032-65-7(メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル)キーワード:


  • 2032-65-7
  • OMS93
  • 3,5-Dimethyl-4-(methylsulfanyl)phenyl methylcarbamate
  • 3,5-dimethyl-4-(methylthio)-phenomethylcarbamate
  • 3,5-dimethyl-4-methylmercaptophenyl-n-methyl-carbamate
  • 3,5-Dimethyl-4-methylthiophenyl N-methylcarbamate
  • 3,5-Dimethyl-4-methyl-thiophenyl-N-carbamat
  • 3,5-dimethyl-4-methylthiophenyln-methylcarbamate
  • 3,5-Xylenol, 4-(methylthio)-, methylcarbamate
  • 4-(Methylthio)-3,5-dimethylphenyl methylcarbamate
  • 4-Methylmercapto-3,5-dimethylphenyl N-methylcarbamate
  • 4-methylmercapto-3,5-dimethylphenyln-methylcarbamate
  • 4-Methylmercapto-3,5-xylyl methylcarbamate
  • 4-methylmercapto-3,5-xylylmethylcarbamate
  • 3,5-Dimethyl-4-(methylthio)phenol methylcarbamate
  • 3,5-DIMETHYL-4-[METHYLTHIO]PHENYL METHYLCARBAMATE
  • METHIOCARB
  • Mesurol
  • MESUROL(R)
  • MERCAPTODIMETHUR
  • Methylcarbamic acid 4-(methylthio)-3,5-xylyl ester
  • BAYER 37344
  • ENT25726
  • H 321
  • METHIOCARB, 1GM, NEAT
  • MERCAPTODIMETHUR PESTANAL
  • Metmercapturon[R]
  • mercaptodimethur (iso,f,frg)
  • methiocarb (bsi,can,nz,esa,iso)
  • Methiocarb(Mercaptodimethur)
  • mercaptodimethur (ISO) methiocarb 3,5-dimethyl-4-methylthiophenyl N-methylcarbamate
  • メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル
  • メトメルカプツロン
  • トラザ
  • ドラザ
  • メルカプトジメツル
  • メチオカーブ
  • メトメルカプトロン
  • メチオカルブ
  • メスロール
  • メスロールフェノール
  • N-メチルカルバミド酸3,5-ジメチル-4-メチルチオフェニル
  • メスロール50
  • メルカプトジメツル標準品
  • メチオカルブ標準品
  • CS_N-12398-100MG_メチオカルブメルカプトジメツルスルホン
  • メルカプトジメツル メチオカルブ
  • メチオカルブ IN ACETONITRILE
  • メチオカルブ STANDARD
  • メチオカルブ Standard, 100 µg/mL in MeOH
  • メチオカルブ, 0.1 mg/mL in Acetonitrile
  • メチオカルブ, 100 µg/mL in MeOH
  • カーバメート系殺虫剤
  • 忌避剤
  • 軟体動物駆除剤
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