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ジアゾアミノベンゼン

ジアゾアミノベンゼン 化学構造式
136-35-6
CAS番号.
136-35-6
化学名:
ジアゾアミノベンゼン
别名:
ジアゾアミノベンゼン;フェニルアゾアニリン;アニリノアゾベンゼン;ベンゼンジアゾアニリド;ベンゼンアゾアニリン;1,3-ジフェニルトリアゼン;ジアゾアミノビスベンゼン
英語化学名:
Diazoaminobenzene
英語别名:
DAAB;Cellofor;cellofor(czech);Diazoaminobenzen;Diazoaminobenzol;DIAZOAMINOBENZENE;anilinoazobenzene;benzeneazoaniline;Benzene azoanilide;benzenediazoanilide
CBNumber:
CB2344713
化学式:
C12H11N3
分子量:
197.24
MOL File:
136-35-6.mol

ジアゾアミノベンゼン 物理性質

融点 :
96°C
沸点 :
324.34°C (rough estimate)
比重(密度) :
1.1793 (rough estimate)
蒸気圧:
>1 Pa
屈折率 :
1.6500 (estimate)
貯蔵温度 :
Store below +30°C.
溶解性:
0.5g/l insoluble
酸解離定数(Pka):
1.00±0.30(Predicted)
水溶解度 :
499.8mg/L(room temperature)
InChIKey:
ALIFPGGMJDWMJH-UHFFFAOYSA-N
CAS データベース:
136-35-6(CAS DataBase Reference)
EPAの化学物質情報:
1-3-Diphenyltriazine (136-35-6)

安全性情報

主な危険性  E,Xn
Rフレーズ  1-5-20/21/22-36/37/38
Sフレーズ  15-26-27-36/37/39
WGK Germany  WGK 3 highly water endangering
RTECS 番号 XY2625000
国連危険物分類  IRRITANT
HSコード  29270000
有毒物質データの 136-35-6(Hazardous Substances Data)
消防法 危-5-II

ジアゾアミノベンゼン 価格 もっと(4)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01W0232-5328 1,3-ジフェニルトリアゼン 95.0+%
1,3-Diphenyltriazene 95.0+%
136-35-6 5g ¥4400 2021-03-23 購入
富士フイルム和光純薬株式会社(wako) W01W0232-5328 1,3-ジフェニルトリアゼン 95.0+%
1,3-Diphenyltriazene 95.0+%
136-35-6 25g ¥9100 2021-03-23 購入
東京化成工業 D0136 ジアゾアミノベンゼン >97.0%(T)
Diazoaminobenzene >97.0%(T)
136-35-6 500g ¥79600 2021-03-23 購入
東京化成工業 D0136 ジアゾアミノベンゼン >97.0%(T)
Diazoaminobenzene >97.0%(T)
136-35-6 25g ¥9100 2021-03-23 購入

ジアゾアミノベンゼン 化学特性,用途語,生産方法

外観

黄色~褐色の結晶又は結晶性粉末

解説

1,3-diphenyltriazene.C12H11N3(197.24).C6H5N=NNH-C6H5.アニリンに塩化ベンゼンジアゾニウムを作用させると生成する.淡黄色の結晶.融点99~100 ℃.酸により転位して4-アミノアゾベンゼンを生成する.融点以上に急速に加熱すると爆発する.ゴム加硫剤,重合開始剤に使用される.[CAS 136-35-6]
森北出版「化学辞典(第2版)

用途

有機合成原料。

説明

Diazoaminobenzene (DAAB) is an aromatic amine that is a suspected carcinogen. It is harmful if inhaled, ingested, or absorbed through the skin. It causes skin irritation and severe irritation to eyes. DAAB can be made by diazotizing aniline dissolved in hydrochloric acid with sodium nitrite and then adding a concentrated solution of sodium acetate. DAAB is listed in the US Environmental Protection Agency’s Toxic Substances Control Act Inventory. DAAB has three major use areas: intermediate, complexing agent, and polymer additive. Use as an intermediate is reported in several industry sectors, including organic synthesis, dye manufacture, and agrochemical manufacture (insecticides). DAAB is also a versatile metal complexing agent. A series of metabolism studies in rodents and human liver slices, electron spin resonance spectroscopy studies, short-term dermal toxicity studies in rodents, and acute bone marrow micronucleus studies in mice demonstrated that DAAB is metabolized and shares similar genotoxic and toxicological properties to the known human carcinogen, benzene, and the known rodent carcinogen, aniline.

化学的特性

ochre powder

使用

Diazoaminobenzene is used as a chemical intermediate, complexing agent, and polymer additive (Mathews and De Costa 1999). It has uses associated with organic synthesis and dye and insecticide manufacture (Lewis 1997), and it is an effective dopant for laser ablation (micro-machining) of polymethylmethacrylate (Bolle et al. 1990). Diazoaminobenzene has been identified as a low-level contaminant in the dyes D&C red no. 33, FD&C yellow no. 5 (tartrazine), and FD&C yellow no. 6; all three are permitted for use in drugs and cosmetics, and the latter two are permitted in food (FDA 2010).

使用

DAAB is used as a chemical intermediate, a complexing agent, and as a polymer additive. DAAB has been used to promote adhesion of natural rubber to steel tire cords. It has also been used as a blowing agent in the production of a foamed polymeric material. In addition, DAAB is used in the manufacture of dyes and insecticides. DAAB is also an impurity in certain color additives used in cosmetics, food products, and pharmaceuticals. In addition, it has been reported to show semiconducting properties and to be useful as a dopant for poly methylmethacrylate in semiconductor manufacture.

一般的な説明

Orange solid.

空気と水の反応

Dust can be explosive when suspended in air at specific concentrations. Insoluble in water.

反応プロフィール

1,3-DIPHENYLTRIAZENE is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. 1,3-DIPHENYLTRIAZENE explodes when heated to above 150°C. A mixture of the triazine and acetic anhydride exploded violently upon warming, Ber., 1891, 24, 4160.

健康ハザード

ACUTE/CHRONIC HAZARDS: 1,3-DIPHENYLTRIAZENE may explode if subjected to severe shock or heat.

火災危険

Flash point data for 1,3-DIPHENYLTRIAZENE are not available, however, 1,3-DIPHENYLTRIAZENE is probably combustible.

安全性プロファイル

Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Strongly explosive when shocked or heated to 98'C. Mixture with acetic anhydride explodes when warmed. When heated to decomposition it emits toxic fumes of NOx,.

Carcinogenicity

Diazoaminobenzene is reasonably anticipated to be a human carcinogen based on (1) evidence from studies in experimental animals andwith human tissue demonstrating that diazoaminobenzene is metabolized to benzene, a known human carcinogen, and (2) evidence that diazoaminobenzene causes genetic damage. Studies in rats and mice have shown that the metabolism of diazoaminobenzene to benzene is quantitative. Benzene was listed in the First Annual Report onCarcinogens in 1980 based on human epidemiological studies dem-causes cancer at numerous tissue sites in rodents.

環境運命予測

DAAB is a respiratory tract, skin, and eye irritant. DAAB yields benzene and aniline as metabolites. The proposed metabolic pathway forDAAB is that it is cleaved reductively by liver enzymes or gut flora to form aniline, benzene, and nitrogen. DAAB metabolism also results in the formation of a reactive phenyl radical, which could account for an additional risk of toxicity or carcinogenicity. The erythrocyte and lymphoid systems are major targets of DAAB toxicity. Induction of lymphoid atrophy of the thymus and other lymphoid tissues were observed, as well as methemoglobin formation, accompanying anemia, increased spleen weights, and regenerative hematopoiesis. Analysis of organ weights indicated possible chemical-related effects in the thymus, heart, spleen, kidney, and liver of rats and/or mice. Increases in the incidences of several skin lesions, including hyperplasia of the epidermis and hair follicles, and inflammation in rats and mice and ulceration in female mice were observed.

Toxicity evaluation

DAAB is an aromatic amine that exists as small golden yellow crystals at room temperature. It is insoluble in water (water solubility 0.5 g l-1) but freely soluble in ethyl alcohol, ethyl ether, benzene, pyridine, and hexane. It is stable under normal temperatures and pressures. DAAB melts at 98°C, decomposes at 130°C with major decomposition at 188°C, and explodes at its boiling point of 150°C. When heated to decomposition, it emits toxic fumes of NOx. The decomposition products of DAAB include benzene, o- and p-aminodiphenyl, diphenylamine, and azobenzene.

ジアゾアミノベンゼン 上流と下流の製品情報

原材料

準備製品


ジアゾアミノベンゼン 生産企業

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136-35-6(ジアゾアミノベンゼン)キーワード:


  • 136-35-6
  • benzenediazoanilide
  • 1,3-DIPHENYLTRIAZENE 97+%
  • (1E)-1,3-diphenyltriaz-1-ene
  • 1,3-Diphenyltriazene,95%
  • 1,3-DIPHENYLTRIAZENE FOR SYNTHESIS
  • Benzene azoanilide
  • LABOTEST-BB LT00032424
  • DIAZOAMINOBENZENE
  • Diazoaraino benzene
  • 1,3-DIPHENYLTRIAZ-1-ENE
  • 1,3-DIPHENYLTRIAZENE
  • phenyl-phenyldiazenyl-amine
  • (1E)-1,3-Diphenyl-1-triazene
  • N-phenyldiazenylaniline
  • 1,3-diphenyl-1-triazen
  • 1,3-diphenyl-1-Triazene
  • 1,3-diphenyl-triazen
  • 1,3-Diphenyltriazine
  • anilinoazobenzene
  • benzeneazoaniline
  • Cellofor
  • cellofor(czech)
  • DAAB
  • Diazoaminobenzen
  • diazoaminobenzen(czech)
  • Diazoaminobenzol
  • diazobenzeneanilide
  • n-(phenylazo)-anilin
  • p-diazoaminobenzene
  • Triazene, 1,3-diphenyl-
  • ジアゾアミノベンゼン
  • フェニルアゾアニリン
  • アニリノアゾベンゼン
  • ベンゼンジアゾアニリド
  • ベンゼンアゾアニリン
  • 1,3-ジフェニルトリアゼン
  • ジアゾアミノビスベンゼン
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