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α-シペルメトリン

α-シペルメトリン 化学構造式
67375-30-8
CAS番号.
67375-30-8
化学名:
α-シペルメトリン
别名:
アルファ-シペルメトリン標準品;α-シペルメトリン;(S)-α-シアノ-3-フェノキシベンジル=3-(2,2-ジクロロビニル)-2,2-ジメチル-cis-シクロプロパンカルボキシラート;Α‐シペルメトリン標準品
英語化学名:
alpha-Cypermethrin
英語别名:
FURY;CCN52;AUZAR;Bcstox;ARRIVO;bestox;Fendana;AMMO(R);concord;dominex
CBNumber:
CB2397557
化学式:
C22H19Cl2NO3
分子量:
416.3
MOL File:
67375-30-8.mol

α-シペルメトリン 物理性質

融点 :
78-81°C
沸点 :
200°C (rough estimate)
比重(密度) :
1.12
蒸気圧:
2.3×10-7Pa (20 °C)
屈折率 :
1.6200 (estimate)
闪点 :
100 °C
貯蔵温度 :
−20°C
外見 :
neat
水溶解度 :
0.01 mg l-1 (25 °C)
BRN :
8444118
安定性::
Stable. Incompatible with strong oxidizing agents.
EPAの化学物質情報:
Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2, 2-dimethyl-, (R)-cyano(3-phenoxyphenyl) methyl ester, (1S,3S)-rel-(67375-30-8)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn,N,T
Rフレーズ  20/22-37-50/53-48/22-25
Sフレーズ  24-36/37/39-60-61-45
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS 番号 GZ1250000
国連危険物分類  6.1(b)
容器等級  III
有毒物質データの 67375-30-8(Hazardous Substances Data)
毒劇物取締法 III
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H301 飲み込むと有毒 急性毒性、経口 3 危険 P264, P270, P301+P310, P321, P330,P405, P501
H335 呼吸器への刺激のおそれ 特定標的臓器毒性、単回暴露; 気道刺激性 3 警告
H373 長期にわたる、または反復暴露により臓器の障 害のおそれ 特定標的臓器有害性、単回暴露 2 警告 P260, P314, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P273 環境への放出を避けること。
P391 漏出物を回収すること。
P501 内容物/容器を...に廃棄すること。

α-シペルメトリン 価格 もっと(4)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-548N α-シペルメトリン
a-Cypermethrin
67375-30-8 10mg ¥15500 2018-12-26 購入
関東化学株式会社(KANTO) 49861-54 α‐シペルメトリン標準品
α‐Cypermethrin standard
67375-30-8 100mg ¥18000 2018-12-13 購入
Sigma-Aldrich Japan 45806 PESTANAL?, analytical standard
α-Cypermethrin PESTANAL?, analytical standard
67375-30-8 100mg ¥20900 2018-12-25 購入
林純薬工業株式会社 99045806 α-シペルメトリン
α-Cypermethrin
67375-30-8 100mg ¥20900 2018-12-15 購入

α-シペルメトリン MSDS


alpha-Cypermethrin

α-シペルメトリン 化学特性,用途語,生産方法

化学的特性

colourless crystals or white powder

化学的特性

alpha-Cypermethrin  is Colorless crystalline solid or viscous yellowish-brown semisolid mass. Mild aromatic odor.

使用

alpha-Cypermethrin  is a synthetic pyrethroid pesticide used in large-scale commercial agricultural applications as well as in consumer products for domestic purposes.

使用

insecticide

使用

Alpha-cypermethrin is used to control a wide range of insects, especially Lepidoptera, in fruit, vines, vegetables, cereals, beans, beets, cotton, ornamentals and forestry and other crops. It is also used for insect control in public health and for ectoparasite control on animals.

农业用途

Insecticide: A U.S. EPA restricted Use Pesticide (RUP) (zeta-Cypermethrin only). Used for the control of a wide range of chewing and sucking insects (particularly Lepidotera, Coleoptera, and Hemiptera) in fruit (including citrus), vegetables, vines, cereals, maize, beet, oilseed rape, potatoes, cotton, rice, soya beans, forestry, and other crops. Control of cockroaches, mosquitoes, flies, and other insect pests in public health; and flies in animal houses. Also used as an animal ectoparasiticide.

製品名

BESTOX®; CONCORD®; DOMINEX®; FASTAC®; FENDONA®; FMC 45497®[C]; NRDC 160®; RENEGADE®; WL-85871® Cypermethrin-s: FURY® (s-isomer); FMC 56701® (s-isomer)

職業ばく露

alpha-Cypermethrin  useds for the control of a wide range of chewing and sucking insects (particularly lepidotera, coleoptera, and hemiptera) in fruit (including citrus), vegetables, vines, cereals, maize, beet, oilseed rape, potatoes, cotton, rice, soya beans, forestry, and other crops. Control of cockroaches, mosquitoes, flies, and other insect pests in public health; and flies in animal houses. Also used as an animal ectoparasiticide. alpha-Cypermethrin  only is a United States Environmental Protection Agency Restricted Use Pesticide (RUP).

代謝経路

Alpha-cypermethrin is composed of two of the four cis-cypermethrin isomers (i.e. two of the eight cypermethrin isomers). These are the lRcisaS and 1ScisaR isomers. The fate of alpha-cypermethrin specifically has been reported for soils, rat and human. Metabolite analysis was conducted in enough detail to indicate that the fate of this mixture is very similar to its fate when presented to biological systems as part of cis-cypermethrin. Thus reference can be made to the cypermethrin entry for details. The structure and Scheme numbering used below refers to the cypermethrin entry.

輸送方法

UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Degradation

Alpha-cypermethrin is stable as a solid but it is readily hydrolysed in solution under alkaline conditions. By analogy with cypermethrin, the rate-determining step in dilute solution is nucleophilic attack by OH-. Half-lives of cis-cypermethrin in river water and sea water at 25 °C were 21 and 24 days, respectively. Major products were 3-(2,2-dichlorovinyl)- 2,2-dimethylcyclopropanecarboxylic acid (2, DCVA), 3-phenoxybenzaldehyde (9, 3PBAl) and a-carbamoyl-3-phenoxybenzyl 3-(2,2- dichlorovinyl)-2,2-dimethylcyclopropanecarboxyltae (the amide 3); minor products were the a-carboxy analogue of 3 (4) and 3-phenoxybenzoic acid (10,3PBA) (see cypermethrin, Schemes la and lb).
Photodecomposition would be expected to be similar to that of cis-cy permethrin.

不和合性

May react violently with strong oxidi- zers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders, or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate.

廃棄物の処理

Do not discharge into drains or sewers. Burn in incinerator specifically designed for pes- ticide disposal or dispose as a Hazardous waste in a landfill approved and licensed for the disposal of pesticides. Consult with environmental regulatory agencies for guid- ance on acceptable disposal practices. Ultimate disposal of the chemical must consider: the material’s impact on air quality; potential migration in soil or water; effects on ani- mal, aquatic, and plant life; and conformance with environ- mental and public health regulations.

α-シペルメトリン 上流と下流の製品情報

原材料

準備製品


α-シペルメトリン 生産企業

Global( 120)Suppliers
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ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
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Hubei Jusheng Technology Co.,Ltd.
86-18871470254
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Haihang Industry Co.,Ltd
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+86 531 8582 1093 export@haihangchem.com CHINA 8921 58
Cangzhou Wanyou New Material Technology Co.,Ltd
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BOC Sciences
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
3B Pharmachem (Wuhan) International Co.,Ltd. 86-21-50328103 * 801、802、803、804 Mobile:18930552037
86-21-50328109 3bsc@sina.com China 15881 69

67375-30-8(α-シペルメトリン)キーワード:


  • 67375-30-8
  • (R,S)-alpha-Cyano-(3-phenoxyphenyl)methyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
  • (R,S)-α-cyano-3-phenoxybenzyl(1R,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
  • Bcstox
  • Fendana
  • OMS 3004
  • Renegade
  • Phenoxybenzyl-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane carboxylate
  • (R)-Cyano-3-phenoxybenzyl (1S,3S)-rel-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane carboxylate
  • Alphaguard
  • Alphacypermethrin - Mixed isomers
  • alpha-Cypermethrin 250mg [67375-30-8]
  • (1S,3S)-(R)-Cyano(3-phenoxyphenyl)Methyl 3-(2,2-dichlorovinyl)-2,2-diMethylcyclopropanecarboxylate
  • alpha-Cypermet
  • Alpha-cypermrthrin
  • RENEGADE(R)
  • (R,S)-ALPHA-CYANO-3-PHENOXYBENZYL-3-(2,2-DICHLOROVINYL)-2,2-DIMETHYLCYCLOPROPANECARBOXYLATE
  • ZETA-CYPERMETHRIN
  • AGROTRINA
  • (+/-)(A)-CYANO-3-PHENOXYBENZYL (+) CIS-TRANS-3-(2,2-DICHLOROVINYL)-2,2-DIMETHYL-CYCLOPROPANE CARBOXYLATE
  • ALPHAMETHRIN
  • ALPHAMETHRIN(R)
  • ALPHA-CYPERMETHRIN
  • AMMO(R)
  • ALFOXYLATE
  • 3-(2,2-DICHLOROETHENYL)-2,2-DIMETHYLCYCLOPROPANECARBOXYLIC ACID CYANO(3-PHENOXYPHENYL)METHYL ESTER
  • [1A(S(R)),3A]-(+/-)-CYANO-(3-PHENOXYPHENYL)METHYL-3-(2,2-DICHLOROVINYL)-2,2-DIMETHYLCYCLOPROPANE CARBOXYLATE
  • CCN52
  • CYANO (3-PHENOXYPHENYL)METHYL-3-(2,2-DICHLOROETHENYL)-2,2-DIMETHYL
  • DOMINEX(R)
  • (1S)-cis-(alphaR)-cypermethrin
  • アルファ-シペルメトリン標準品
  • α-シペルメトリン
  • (S)-α-シアノ-3-フェノキシベンジル=3-(2,2-ジクロロビニル)-2,2-ジメチル-cis-シクロプロパンカルボキシラート
  • Α‐シペルメトリン標準品
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