リチウムtert-ブトキシド
リチウムtert-ブトキシド 物理性質
- 融点 :
- °C
- 沸点 :
- 68-70 °C
- 比重(密度) :
- 0.89 g/mL at 20 °C
- 闪点 :
- −2 °F
- 貯蔵温度 :
- 2-8°C
- 溶解性:
- トルエン、ヘキサン、テトラヒドロフラン、メチルtert-ブチルエーテルに可溶。
- 外見 :
- 液体
- 色:
- 茶色
- 比重:
- 0.89
- 水溶解度 :
- 激しい反応
- Sensitive :
- Moisture Sensitive
- Hydrolytic Sensitivity:
- 7: reacts slowly with moisture/water
- BRN :
- 3620018
- InChIKey:
- LZWQNOHZMQIFBX-UHFFFAOYSA-N
- CAS データベース:
- 1907-33-1(CAS DataBase Reference)
- EPAの化学物質情報:
- Lithium tert-butoxide (1907-33-1)
安全性情報
- リスクと安全性に関する声明
- 危険有害性情報のコード(GHS)
| 絵表示（GHS） |
|
| 注意喚起語 |
警告 |
| 危険有害性情報 |
| コード |
危険有害性情報 |
危険有害性クラス |
区分 |
注意喚起語 |
シンボル |
P コード |
| H312 |
皮膚に接触すると有害 |
急性毒性、経皮 |
4 |
警告 |
|
P280,P302+P352, P312, P322, P363,P501 |
| H412 |
長期的影響により水生生物に有害 |
水生環境有害性、慢性毒性 |
3 |
|
|
P273, P501 |
|
| 注意書き |
| P273 |
環境への放出を避けること。 |
| P280 |
保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。 |
| P501 |
内容物/容器を．．．に廃棄すること。 |
|
リチウムtert-ブトキシド 価格
もっと(17)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01SRM03-0780 |
リチウムt-ブトキシド, 98+%
Lithium t-butoxide, 98+% |
1907-33-1 |
25g |
￥40000 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01SRM03-0780 |
リチウムt-ブトキシド, 98+%
Lithium t-butoxide, 98+% |
1907-33-1 |
100g |
￥119500 |
2024-03-01 |
購入 |
|
東京化成工業
|
L0253 |
リチウム tert-ブトキシド (約10%テトラヒドロフラン溶液, 約1mol/L)
Lithium tert-Butoxide (ca. 10% in Tetrahydrofuran, ca. 1mol/L)
|
1907-33-1 |
100mL |
￥10900 |
2024-03-01 |
購入 |
|
関東化学株式会社(KANTO)
|
30122-2A |
リチウムｔｅｒｔ‐ブトキシド
Lithium tert‐butoxide |
1907-33-1 |
100g |
￥83900 |
2024-03-01 |
購入 |
|
関東化学株式会社(KANTO)
|
30122-1A |
リチウムｔｅｒｔ‐ブトキシド
Lithium tert‐butoxide |
1907-33-1 |
25g |
￥31400 |
2024-03-01 |
購入 |
リチウムtert-ブトキシド 化学特性,用途語,生産方法
外観
うすい黄色～褐色透明液体
化学的特性
Lithium tert-Butoxide [1907-33-1], LiOC (CH3)3, Mr 80.06, r 0.89 g/cm3, mp 283 ℃ is a colorless compound with good solubility in many organic solvents (e.g. 16 % in hexane). It is commercially available as min. 98 % powder and as a 20 % solution in THF. In organic synthesis it serves as a strong base. As one of the few volatile lithium compounds, it sublimes without decomposition at 110 ℃ in vacuum, and is therefore a suitable raw material for lithium doping in CVD processes.
使用
Lithium tert-butoxide is a mild base used in organic synthesis. It is involved in the alfa-alkylation reaction of ketones with primary alcohols. It is utilized as a catalyst in the reduction of ketones to the corresponding secondary alcohols. It acts as lithium source utilized in the preparation of LixTiyOz thin films. Further, it is used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity.
Biochem/physiol Actions
Enterotoxigenic Escherichia coli causes diarrhea through its heat-labile enterotoxin (LT). The LT is a periplasmic protein composed of one A subunit (LTA, 27 kDa) and five non-covalently associated B subunits (LTB, 11.6 kDa each) forming a ring-like pentamer. LTB has high affinity towards the toxin receptor ganglioside GM1, a glycosphingolipid found ubiquitously on the surface of mammalian cells. Ganglioside GM1 facilitates the delivery of the A subunit to the cytosol of the target cell resulting in persistent synthesis of cAMP and subsequently diarrhea. This characteristic makes LTB a good label for microglial cells (due to the enrichment of ganglioside GM1 on their cell surface). In addition, studies made mostly with animal models demonstrated that recombinant LTB could stimulate strong serum and mucosal immune responses against LT. Other studies have indicated that LTB could be used as a potent mucosal adjuvant.
安全性
Lithium tert-butoxide is dangerous because it catches fire immediately in contact with air. A few precautions will reduce the risk: Use protection when handling hazardous chemicals, always wear lab coats and safety glasses; Because tert-butyl lithium will automatically react with atmospheric moisture, so avoid its exposure to the atmosphere; Don't work alone and remember how to handle an emergency.
リチウムtert-ブトキシド 上流と下流の製品情報
原材料
準備製品
リチウムtert-ブトキシド 生産企業
Global( 341)Suppliers
リチウムtert-ブトキシド スペクトルデータ(FT-IR)
1907-33-1(リチウムtert-ブトキシド)キーワード:
- 1907-33-1
- LITHIUM TERT-BUTOXIDE
- Lithiumtert-butoxid
- Lithium tert-butoxide, 1M solution in hexanes
- 2-methyl-2-propanolithiumsalt
- 2-methyl-2-propanollithiumsalt
- lithiumtert-butanolate
- tert-butoxylithium
- Lithium tert-butoxide, 99.9% (metals basis)
- Lithium tert-butoxide, 2.2M solution in THF
- 1,2,3,4,5,6-Hexachlorocyclohexane (mixed isomers)
- Lithium tert-butoxide2.2M solution in THFAcroSeal§3
- Lithium 1,1-dimethylethanolate
- Lithium 1,1-dimethylethoxide
- Lithium tert-butoxide,99%
- Lithium tert-butoxide (metals basis)
- Lithium tert-butoxide, 1M solution in hexanes, AcroSeal§3
- Lithium tert-butoxide, 2.2M solution in THF, AcroSeal
- Lithium tert-butoxide, 1M solution in hexanes, AcroSeal
- 2-Methyl-1-oxopropan-2-yl lithiuM
- LithiuM tert-butoxide, 0.9M (8 wt.%) solution in 2-MeTHF, AcroSeal
- tert-butylalcohol,lithiumsalt
- Lithium tert-butoxide solution
- Lithiumtbutoxideminoffwhitepowder
- LithiuM tert-butoxi
- LITHIUM TERT-BUTOXIDE-TG
- LithiuM tert-butoxide, 2.2M solution in THF, J&KSeal
- LithiuM Tert-Butoxide SynonyMs: LithiuM 2-Methylpropan-2-olate
- LithiuM tert-butoxide solution 1.0 M in THF
- LithiuM tert-butoxide, 1.0 M solution in hexanes, SpcSeal
- ANTI-LTB(C-TERMINAL) antibody produced in mouse
- リチウム1,1-ジメチルエタノラート
- リチウム=tert-ブトキシド
- tert-ブトキシリチウム
- リチウム1,1-ジメチルエトキシド
- リチウムtert-ブトキシド
- リチウム2-メチル-2-プロパノラート
- リチウム tブトキサイド
- リチウムTERT-ブトキシド,テトラヒドロフラン溶液
- リチウム tert-ブトキシド (約10%テトラヒドロフラン溶液, 約1mol/L)
- リチウムTERT‐ブトキシド
- リチウムTERT‐ブトキシド,テトラヒドロフラン溶液,2.2MOL/L
- 1.0MOL/L リチウムT-ブトキシド・テトラヒドロフラン溶液
- リチウム TERT-ブトキシド, 99.9% (METALS BASIS)
- リチウムTERT-ブトキシド 溶液
- 易熱性エンテロトキシンBサブユニット(LTB) 大腸菌由来
- リチウムt-ブトキシド, 98+%