2-メタクリロイルオキシ-2-メチルアダマンタン
2-メタクリロイルオキシ-2-メチルアダマンタン 物理性質
- 沸点 :
- 301.3±11.0 °C(Predicted)
- 比重(密度) :
- 1.06±0.1 g/cm3(Predicted)
- 屈折率 :
- 1.5050 to 1.5090
- 闪点 :
- 120°C(lit.)
- 貯蔵温度 :
- 2-8°C
- 外見 :
- clear liquid
- 色:
- Colorless to Almost colorless
- 比重:
- 1.06
- Sensitive :
- Heat Sensitive
- InChI:
- InChI=1S/C15H22O2/c1-9(2)14(16)17-15(3)12-5-10-4-11(7-12)8-13(15)6-10/h10-13H,1,4-8H2,2-3H3
- InChIKey:
- FDYDISGSYGFRJM-UHFFFAOYSA-N
- SMILES:
- C(OC1(C)C2CC3CC1CC(C3)C2)(=O)C(C)=C
2-メタクリロイルオキシ-2-メチルアダマンタン 価格
もっと(7)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01COBQH-5307 |
2-Methyl-2-adamantyl methacrylate |
177080-67-0 |
1g |
￥27500 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01COBQH-5307 |
2-Methyl-2-adamantyl methacrylate |
177080-67-0 |
5g |
￥110000 |
2024-03-01 |
購入 |
|
東京化成工業
|
M2260 |
2-メタクリロイルオキシ-2-メチルアダマンタン >97.0%(GC)
2-Methacryloyloxy-2-methyladamantane (stabilized with MEHQ)
>97.0%(GC) |
177080-67-0 |
1g |
￥7200 |
2023-06-01 |
購入 |
|
東京化成工業
|
M2260 |
2-メタクリロイルオキシ-2-メチルアダマンタン >97.0%(GC)
2-Methacryloyloxy-2-methyladamantane (stabilized with MEHQ)
>97.0%(GC) |
177080-67-0 |
5g |
￥27700 |
2023-06-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01FLC237894 |
2-Methyladamantan-2-yl methacrylate |
177080-67-0 |
1g |
￥30000 |
2021-03-23 |
購入 |
2-メタクリロイルオキシ-2-メチルアダマンタン 化学特性,用途語,生産方法
外観
無色～ほとんど無色透明液体
化学的特性
Off-white powder.
主な応用
2-Methacryloyloxy-2-methyladamantane as a guest molecule can be introduced onto the silicon substrate by interacting with β-cyclodextrin (β-CD) to construct supramolecular composite surfaces. After the assembly of hydrophilic guest molecules on the main surface, the wettability, water lubrication and resistance to algal cell adhesion of the supramolecular composite surface were improved. This host-guest interface supramolecule provides a new way to prepare water-based lubrication and antifouling materials
[2].
合成
The synthesis of 2-Methyl-2-adamantylmethacrylate is as follows:Add 3546ml of n-heptane in the 5L four-necked flask equipped with stirring paddle, condenser tube and thermometer, turn on stirring, add 126.3g of 2-methyladamantanol to the system, and slowly add 0.022g polymerization inhibitor tetrachlorobenzoquinone to the reaction, add 110.8g basic ion exchange resin, adjust pH=7-8, cool down to -13°C, slowly add 110.8g vinyl methacrylate dropwise to the reaction system, keep the reaction for 7h, monitor the reaction progress, and take samples for detection After the reaction was completed, 1000 ml of water was added to the reaction system, and the mixture was stirred and extracted for phase separation. The organic phase was dried, concentrated under reduced pressure and evaporated to dryness to obtain 167 g of 2-methyl-2-adamantyl methacrylate (2-Methacryloyloxy-2-methyladamantane) product with a yield of 93.78%.
参考文献
[1] M. Maríc. “Nitroxide‐mediated polymerization of adamantyl‐functional methacrylates for 193 nm photoresists.” Canadian Journal of Chemical Engineering 95 1 (2017): 708–716.
[2] RONGNIAN XU. Promoting Lubricity and Antifouling Properties by Supramolecular-Recognition-Based Surface Grafting[J]. Langmuir, 2018. DOI:10.1021/acs.langmuir.8b02375.
2-メタクリロイルオキシ-2-メチルアダマンタン 上流と下流の製品情報
原材料
準備製品
2-メタクリロイルオキシ-2-メチルアダマンタン 生産企業
Global( 150)Suppliers
177080-67-0(2-メタクリロイルオキシ-2-メチルアダマンタン)キーワード:
- 177080-67-0
- 2-methacryloyloxy-2-methyladamantane
- 2-Methacryloyloxy-2-MethyladaMantane (stabilized with MEHQ)
- 2-Methyl-2-adamantyl Methacrylate
Methacrylic Acid 2-Methyl-2-adamantyl Ester
- 2-Methyl-2-adaMantyl Methacrylte
- 2-Methyl-2-adamantyl methacrylate
- 2-METHYL-2-ADAMANTYL METHACRYL
- 2-MethyladaMantan-2-yl Methacrylate
- 2-Methyl-2-Adamantyl Methacrylate MAMA ArF monomers
- 2-Methyl-2-adamantylmethacrylate 177080-67-0
- 2-Methacryloyloxy-2-methyladamantane 177080-67-0
- 2-Methacryloyloxy-2-methyladamantane(stabilizedwithMEHQ)>
- 2-Propenoic acid, 2-methyl-, 2-methyltricyclo[3.3.1.13,7]dec-2-yl ester
- Methacrylic Acid 2-Methyl-2-adamantyl Ester
- (2-methyl-2-adamantyl) 2-methylprop-2-enoate
- 2-Methyl-2-adamantyl methacrylate (MADMA)
- -Methyl-2-adamantylmethacrylate
- (1r,5R,7S)-2-methyladamantan-2-yl methacrylate
- 2-Ethy1-2-adamantylmethacrylate
- 2-メタクリロイルオキシ-2-メチルアダマンタン
- メタクリル酸2-メチル-2-アダマンチル
- 2-メチルアダマンタン-2-イル 2-メチルプロパ-2-エノアート
- メタクリル酸2-メチルトリシクロ[3.3.1.13,7]デカン-2-イル
- メタクリル酸=2-メチルトリシクロ[3.3.1.13,7]デカ-2-イル
- メタクリル酸2-メチルアダマンタン-2-イル
- 2-メチル-2-アダマンチル=メタクリラート
- 2-メチルアダマンタン-2-オールメタクリラート