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1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル)

1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) 化学構造式
15263-52-2
CAS番号.
15263-52-2
化学名:
1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル)
别名:
1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル);パダン;1,3-ビス(カルバモイルチオ)-2-(ジメチルアミノ)プロパン·塩酸塩;ベゲトックス;パダン4G;カルタップ塩酸塩;カルタップ
英語化学名:
Cartap hydrochloride
英語别名:
ntd2;Cadan;Carta;Padan;patap;kartap;Cardan;vegetox;padan4g;Cartapp
CBNumber:
CB3191392
化学式:
C7H16ClN3O2S2
分子量:
273.8
MOL File:
15263-52-2.mol

1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) 物理性質

比重(密度) :
1.4008 (rough estimate)
蒸気圧:
Negligible
屈折率 :
1.6100 (estimate)
外見 :
neat
酸解離定数(Pka):
7.61 (base)
水溶解度 :
ca. 200 g l-1 (20 °C, pH 5)
BRN :
5157539
EPAの化学物質情報:
Carbamothioic acid, S,S'-(2-(dimethylamino)- 1,3-propanediyl) ester, monohydrochloride(15263-52-2)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn;N,N,Xn
Rフレーズ  21/22-50/53
Sフレーズ  2-36/37-60-61
RIDADR  2771
WGK Germany  3
RTECS 番号 FD1225000
国連危険物分類  6.1(b)
容器等級  III
絵表示(GHS)
注意喚起語 Warning
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H302 飲み込むと有害 急性毒性、経口 4 警告 P264, P270, P301+P312, P330, P501
H312 皮膚に接触すると有害 急性毒性、経皮 4 警告 P280,P302+P352, P312, P322, P363,P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P501 内容物/容器を...に廃棄すること。

1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) 価格 もっと(2)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
Sigma-Aldrich Japan 45995 カルタップ塩酸塩 PESTANAL?, analytical standard
Cartap hydrochloride PESTANAL?, analytical standard
15263-52-2 100mg ¥26800 2018-12-25 購入
林純薬工業株式会社 99045995 カルタップ塩酸塩
Cartap hydrochloride
15263-52-2 100mg ¥26800 2018-12-15 購入

1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) MSDS


Cartap hydrochloride

1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) 化学特性,用途語,生産方法

使用

Cartap hydrochloride is used to control sucking and chewing insects (particularly Lepidoptera and Coleoptera), at almost all stages of development, on many crops including rice, potatoes, cabbage and other vegetables. It is also used on soya, peanuts, sunflower, maize, sugar beet, wheat, pearl barley, pome, stone and citrus fruit, vines, tea, chestnuts, ginger, cotton and sugar cane.

农业用途

Insecticide: Cartap hydrochloride is used to control chewing and sucking insects on many crops, including rice, potatoes, cabbage and other vegetables, soy beans, peanuts, sunflowers, maize, sugar beet, wheat, pearl barley, pome fruit, stone fruit, citrus fruit, vines, chestnuts, ginger, tea, cotton, and sugar cane. Not currently registered in the U.S. or registered for use in EU countries. There are approximately 15 global suppliers.

製品名

CADAN®; CALDAN®; KRITAP®; NTD 2®; PADAN®; PATAP®; SANVEX®; THIOBEL®; TI1258®; VEGETOX®

代謝経路

Nereistoxin, 4-N,N-dimethylamino-1,2-dithiolane, is produced from cartap hydrochloride as a main product through photoreaction under UV irradiation in aqueous and methanolic solutions, and on glass and silica gel surfaces. Cartap hydrochloride is also oxidized with N-bromosuccinimide (NBS) to give nereistoxin.

Degradation

Cartap hydrochloride was hydrolysed to dihydronereistoxin (2) when automatically titrated with sodium hydroxide solution and subsequently oxidised to nereistoxin (3) (see Scheme 1). The hydrolysis was a base catalysed pseudo-first-order reaction with a half-life of 10 minutes at pH 7 and 25 °C. Nereistoxin was so stable that no degradation was observed after 24 hours at 100 °C and with pH in the range 1-4. The DT50 s of nereistoxin at 100 °C and at the higher pH values of 7/10 and 12.3 were 26,20 and 7.9 hours, respectively. It was predicted that nereistoxin (3) would be hydrolysed by alkali to the 3-mercaptopropanesulfenic acid (4) which would be oxidised to the sulfinic acid (5) and thence to the sulfonic acid (6) (Asahi and Yoshida, 1977).
An aqueous solution of unlabelled cartap hydrochloride was exposed to sunlight for a period of 5 days. Analysis was by IR, UV and MS methods. Three products were isolated after irradiation and the major of these was identified as a polymer of nereistoxin (7) and represented 80% of applied dose. The polymer (7) was not toxic to fish (Oryzias latips).
Cartap was hydrolysed to nereistoxin (3) via dihydronereistoxin (2). Nereistoxin (3) was converted into the polymer (7) probably after photolytic formation of a nereistoxin diradical as shown in Scheme 1 (Obayashi and Asaka, 1983).

1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) 上流と下流の製品情報

原材料

準備製品


1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル) 生産企業

Global( 72)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21714 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20672 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30002 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28236 58
BOC Sciences
1-631-619-7922
1-631-614-7828 inquiry@bocsci.com United States 20115 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35440 58
Shanghai T&W Pharmaceutical Co., Ltd. +86 21 61551611
+86 21 50676805 contact@trustwe.com China 9920 58
Nanjing Sunlida Biological Technology Co., Ltd. 025-58378339;025-57798810
025-57019371 sales@sunlidabio.com China 3818 55
TianJin Alta Scientific Co., Ltd. +86-022-6537-8550
+86-022-2532-9655 contact@altascientific.com China 2775 58

15263-52-2(1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル))キーワード:


  • 15263-52-2
  • 1,3-dicarbamoylthio-2-(n,n-dimethylamino)propanemonohydrochloride
  • 1,3-propanedithiol,2-(dimethylamino)-,dicarbamate(ester),monohydrochlorid
  • 2-(dimethylamino)-1,3-propanedithioldicarbamatehydrochloride
  • 2-dimethylamino-1,3-bis(carbamoylthio)propanemonohydrochloride
  • carbamicacid,thio-,s,s’-(2-(dimethylamino)trimethylene)ester,monohydrochlo
  • carbamothioicacid,s,s’-(2-(dimethylamino)-1,3-propanediyl)ester,monohydro
  • cartapmonohydrochloride
  • dihydronereistoxindicarbamate
  • thiocarbamicacid-s,s-(2-(dimethylamino)trimethylene)estermonohydrochloride
  • vegetox
  • Cadan
  • Carta
  • CARTAP HYDROCHLORIDE PESTANAL, 100 MG
  • Padan
  • CADAN(R) HYDROCHLORIDE
  • CARTAP HYDROCHLORIDE
  • PADAN(R)
  • S,S'2-DIMETHYLAMINOTRIMETHYLENE BIS-(THIOCARBAMATE) HYDROCHLORIDE
  • SUNTAP(R)
  • SUNVEX(R)
  • VEGETOX(R) HYDROCHLORIDE
  • 1,3-bis(carbamoylthio)-2-(n,n-dimethylamino)propanemonohydrochloride
  • 1,3-bis(carbamoylthio)-2-(n,n-dimethylamino)-propanmonohydrochloride
  • kartap
  • neristoxindicarbamatemanohydrochloride
  • ntd2
  • padan4g
  • patap
  • s,s’-(2-(dimethylamino)trimethylene)bis(thiocarbamate)monohydrochloride
  • S,S'-[2-(dimethylamino)-1,3-propanediyl] dicarbamothioate hydrochloride
  • 1,4-ジヒドロ-2,6-ジメチル-4-(3-ニトロフェニル)-3,5-ピリジンジカルボン酸3-メチル5-(2-ブロモエチル)
  • パダン
  • 1,3-ビス(カルバモイルチオ)-2-(ジメチルアミノ)プロパン·塩酸塩
  • ベゲトックス
  • パダン4G
  • カルタップ塩酸塩
  • カルタップ
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