トリ-n-オクチルホスフィンオキシド
トリ-n-オクチルホスフィンオキシド 価格
もっと(17)
メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
富士フイルム和光純薬株式会社(wako)
|
W01T02T024 |
酸化トリ-n-オクチルホスフィン
Tri-n-octylphosphine Oxide (TOPO) |
78-50-2 |
25g |
¥15000 |
2024-03-01 |
購入 |
東京化成工業
|
T0504 |
トリ-n-オクチルホスフィンオキシド >95.0%(GC)
Tri-n-octylphosphine Oxide
>95.0%(GC) |
78-50-2 |
25g |
¥2900 |
2023-06-01 |
購入 |
東京化成工業
|
T0504 |
トリ-n-オクチルホスフィンオキシド >95.0%(GC)
Tri-n-octylphosphine Oxide
>95.0%(GC) |
78-50-2 |
100g |
¥7400 |
2023-06-01 |
購入 |
関東化学株式会社(KANTO)
|
40947-25 |
トリ‐n‐オクチルホスフィンオキシド >92.0%(GC)
Tri‐n‐octylphosphine oxide >92.0%(GC) |
78-50-2 |
100g |
¥12000 |
2024-03-01 |
購入 |
関東化学株式会社(KANTO)
|
20760-1A |
トリ‐n‐オクチルホスフィンオキシド 99%
Tri‐n‐octylphosphine oxide 99% |
78-50-2 |
25g |
¥10400 |
2024-03-01 |
購入 |
トリ-n-オクチルホスフィンオキシド MSDS
TOPO
トリ-n-オクチルホスフィンオキシド 化学特性,用途語,生産方法
外観
白色~ほとんど白色粉末~結晶
定義
本品は、自然界に存在する元素(P)である。
化学的特性
white crystalline powder
使用
Trioctylphosphine oxide (TOPO) is most commonly used as the solvent due to its high boiling point and chemical stability, and its ability to prevent particle aggregation via coordination to the NP surface. trioctylphosphine oxide is a frequently used surfactant, starts to decompose at around 425°C.
The industrial applications of trioctylphosphine oxide, make use of its complexing powers with metals and with hydrogen donor organic compounds. Commercial uses as a solvent extraction reagent are in the recovery of uranium from wet process phosphoric acid and in the recovery of byproduct acetic acid and furfural generated during sulphite wood pulping.
TOPO is a widely used chemical compound in nanocrystal synthesis, for the removal of heavy metals, and the removal of toxins in waste water. TOPO is often used as a ligand stabilizer for colloids in traditional thermal decomposition synthetic techniques.
trioctylphosphine oxide became a nearly irreplaceable solvent (mp 51-52°C) for high-temperature preparation of various type of nanocomposites. TOPO has a very high boiling point (411°C) which is an important prerequisite for the homogeneous nucleation and good crystallinity of the nanoparticles.
一般的な説明
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純化方法
Mason, McCarty and Peppard [J Inorg Nuclear Chem 24 967 1962] stirred a 0.1M solution in *benzene with an equal volume of 6M HCl at 40o in a sealed flask for 48hours, then washed the *benzene solution successively with water (twice), 5% aqueous Na2CO3 (three times) and water (six times). The *benzene and water were then evaporated under reduced pressure at room temperature. Zingaro and White [J Inorg Nucl Chem 12 315 1960] treated a pet ether solution with aqueous KMnO4 (to oxidise any phosphinous acids to phosphinic acids), then with sodium oxalate, H2SO4 and HCl (to remove any manganese compounds). The pet ether solution was slurried with activated alumina (to remove phosphinic acids), filtered, evaporated and the residue was recrystallised from pet ether or cyclohexane at -20o. It can also be recrystallised from EtOH. [Beilstein 4 IV 3466.]
トリ-n-オクチルホスフィンオキシド 上流と下流の製品情報
原材料
準備製品
トリ-n-オクチルホスフィンオキシド 生産企業
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トリ-n-オクチルホスフィンオキシド スペクトルデータ(1HNMR、13CNMR、IR1、IR2、IR3、MS、Raman)
78-50-2(トリ-n-オクチルホスフィンオキシド)キーワード:
- 78-50-2
- Trioctylphosphineoxide,99%TOPO
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- TRI-N-OCTYLPHOSPHINOXIDE FOR SYNTHESIS
- Trioctylphosphine oxide ReagentPlus(R), 99%
- Trioctylphosphine oxide technical grade, 90%
- (Oct)3PO
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- Trioctylphosphinoxide for synthesis
- TRIOCTYLPHOSPHINE OXIDE, TECH., 90%
- TRIOCTYLPHOSPHINE OXIDE, REAGENTPLUS, 99%
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