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ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル]

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 化学構造式
2642-71-9
CAS番号.
2642-71-9
化学名:
ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル]
别名:
トリアゾチオン;グチオン-エチル;アジンホスエチル;ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル];グサチオンA;エチルグチオン;アジンホス-エチル;アジンホスエチル標準品;アジンホスエチルTRIAZOTION;アジンホスエチル STANDARD;アジンホス-エチル標準品;アジノホスエチル;アジンホスエチル Standard, 100 µg/mL in MeOH;アジンホスエチル Standard, 1000 µg/mL in Hexane
英語化学名:
AZINPHOS-ETHYL
英語别名:
Gutex;Bionex;R 1513;Azinos;B-16259;bay16255;bay16259;sepizinl;Crysthion;ent22,014
CBNumber:
CB3368633
化学式:
C12H16N3O3PS2
分子量:
345.38
MOL File:
2642-71-9.mol

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 物理性質

融点 :
45-47℃
沸点 :
111°C
比重(密度) :
1.43
蒸気圧:
3.2 x 10-4 Pa (20 °C)
貯蔵温度 :
0-6°C
外見 :
Solid
水溶解度 :
4.5 mg l-1(20 °C)
BRN :
297468
CAS データベース:
2642-71-9(CAS DataBase Reference)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T+,N
Rフレーズ  24-28-50/53
Sフレーズ  28-36/37-45-60-61
RIDADR  2783
WGK Germany  3
RTECS 番号 TD8400000
国連危険物分類  6.1(a)
容器等級  II
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 P264, P270, P301+P310, P321, P330,P405, P501
H311 皮膚に接触すると有毒 急性毒性、経皮 3 危険 P280, P302+P352, P312, P322, P361,P363, P405, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P391 漏出物を回収すること。
P501 内容物/容器を...に廃棄すること。

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 価格 もっと(7)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-8141A-1-01 アジンホスエチル Standard
Azinphos-ethyl Standard, 1000 ug/mL in Hexane
2642-71-9 1mL ¥7400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-201N アジンホス-エチル標準品
Azinphos-ethyl Standard
2642-71-9 10mg ¥12800 2018-12-26 購入
関東化学株式会社(KANTO) 49826-07 アジンホスエチル標準品
Azinphos‐ethyl standard
2642-71-9 250mg ¥12000 2018-12-13 購入
Sigma-Aldrich Japan 45332 アジノホスエチル PESTANAL?, analytical standard
Azinphos-ethyl PESTANAL?, analytical standard
2642-71-9 250mg ¥14400 2018-12-25 購入
林純薬工業株式会社 99045332 アジンホスエチルTriazotion
Azinphos ethyl Triazotion
2642-71-9 250mg ¥14400 2018-12-15 購入

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 化学特性,用途語,生産方法

外観

白色~わずかにうすい黄色、結晶性粉末~粉末

溶解性

エタノール及びアセトンに溶け、水にほとんど溶けない。

化学的特性

Azinphos-ethyl forms colorless, clear crystals. It is insoluble in water, but soluble in most organic solvents. As an acaricide, azinphos-ethyl is used for the control of pests, such as, spider mites, aphids, caterpillars, potato bug, beetles, bollweevils, whitefl ies, bollworms, thrips, and other biting and sucking insects. Human exposures to azinphos-ethyl occur through absorption from the gastrointestinal tract, through the intact skin, and by inhalation of fi ne spray mist and dusts.
Azinphos-ethyl is a non-systemic organophosphorus insecticide, which is used against a relatively broad spectrum of insects. These include lepidopterous larvae, beetles and their larvae, aphids, jassids, and spider mites on various crops. And also crops of cotton, rice, sugar and fodder beets, fruits such as apples, pears, citrus-fruit, grapes; tobacco. Many countries around the world have stopped the use of this pesticide.

使用

Azinphos-ethyl is used to control both chewing and sucking pests on a wide range of crops.

一般的な説明

Colorless crystals. Used as a non-systemic insecticide with good ovicidal properties and long persistence. Used on cotton, citrus, vegetables, potatoes, tobacco, rice, and cereals to control caterpillars, beetles, aphids, spiders and many other insects. Not registered for use in the U.S.

空気と水の反応

Nearly insoluble in water. What little amount is solubilized will readily hydrolyze.

反応プロフィール

The BPS Pesticide incident in Helena resulted in an explosion and death of three firemen. The burning of a 1,000 pound sack of Azinphos Methyl or the flashing of Maneb which was present on the facility may have caused the explosion. Azinphos Ethyl may behave similarly. At elevated temperatures, AZINPHOS-ETHYL will decompose generating toxic gases.

健康ハザード

The systemic effects of AZINPHOS-ETHYL are similar to parathion. It is an extremely potent systemic toxicant via ingestion, inhalation and skin contact. It may cause death or permanent injury after very short exposure to small quantities.

健康ハザード

Azinphos-ethyl as an organophosphate pesticide is very toxic to animals and humans, inhibiting the cholinesterase enzyme. Occupational workers exposed to azinphos-ethyl show symptoms of poisoning. On exposure through skin contact, inhalation of dust or spray, or accidental ingestion/swallowing, azinphos-ethyl is fatal. The early symptoms of toxicity include, but are not limited to, excessive sweating, headache, miosis, dyspnea, nausea, vomiting and diarrhea, blurred vision, muscle fasciculations, weakness, increased salivation, stomach pains, slurred speech. More severe poisoning leads to respiratory failure due to a combination of bronchorrhea, bronchoconstriction (muscarinic effects), paralysis of the respiratory muscles (nicotinic effects), and respiratory center paralysis (central effects), which all may eventually lead to shortness of breath, brain hypoxia, convulsions, and coma. Oral and dermal exposures to azinphos-ethyl cause a disturbed heart rate with chest pain. Hypotension (low blood pressure) may be observed, although hypertension (high blood pressure) is not uncommon. Exposed and poisoned occupational workers show respiratory symptoms, such as dyspnea, pulmonary edema, respiratory depression, and respiratory paralysis.
Reports have shown that azinphos-ethyl causes the inhibition of acetylcholinesterase activity in plasma, erythrocytes, the brain and sub-maxillary gland. Studies have indicated that multiple doses of azinphos-ethyl in low doses cause the plasma activity of rats and dogs to fall rapidly to a stable level, while the activity of the erythrocyte acetylcholinesterase falls more gradually.

健康ハザード

A highly toxic substance by all routes ofentry, especially ingestion and skin contact;inhalation hazard may be low because ofvery low vapor pressure [2.2* 10 -7 torr at20 °C (68 °F)]; the systemic effects are sim-ilar to parathion and azinphos methyl; thetoxic effects are nausea followed by vomit-ing, abdominal pain, diarrhea, salivation, andsecretion of excessive mucus in mouth andnose; headache, giddiness, weakness, slur-ring of speech, tightness in the chest, tear-ing, eye muscle pain and blurring of vision,breathing difficulty, convulsion, and coma(Gosselin 1976); ingestion of a small quan-tity can be fatal.
Oral LD50 (rat): 7 mg/kg.

火災危険

(Non-Specific -- Organophosphorus Pesticide, n.o.s.) When heated to decomposition, AZINPHOS-ETHYL emits very toxic fumes of sulfur, phosphorus and nitrogen oxides. Container may explode in heat of fire.

安全性プロファイル

Poison by ingestion, inhalation, skin contact, and intraperitoneal route. A cholinesterase inhibitor type of insecticide. When heated to decomposition it emits toxic fumes of SOx, POx,, and NOx. See also PARATHION.

代謝経路

Although the metabolism of azinphos-ethyl has been studied much less than that of azinphos-methyl, the biotransformations which have been reported appear to be totally analogous.

Degradation

Azinphos-ethyl is rapidly hydrolysed in alkaline and acid media but is fairly stable under neutral conditions. The DT50 values at pH values 4, 7 and 9 were 3 hours, 270 days and 11 days, respectively (PM). The photolytic degradation of 1% azinphos-ethyl in chloroform solution irradiated in a Pyrex photoreactor at λ> 313 nm was investigated by Abdou ef al. (1987) who purified the products by silica gel column chromatography and identified them by MS and 1H NMR spectroscopy. Four metabolites were identified: 3-methylbenzazimide (2), benzazimide (3), both of which were identified by Liang and Lichtenstein (1972) as photolysis products of azinphos-methyl. Two additional products also identified were N-methylanthranilic acid (4) and the rearranged phosphate triester, O,O-diethyl O-(3-methylbenzo[d-l,2,3]-triazine-4-yl) phosphate (5) (Scheme 1).

予防処置

Azinphos-ethyl is an organophosphorus compound that inhibits cholinesterase enzymes. It is very toxic and occupational workers should be very careful during use, storage, and waste disposal of it.

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 上流と下流の製品情報

原材料

準備製品


ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 生産企業

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2642-71-9(ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル])キーワード:


  • 2642-71-9
  • S-(3,4-DIHYDRO-4-OXOBENZO[D]-[1,2,3]-TRIAZINE-3-YLMETHYL)O,O-DIETHYL PHOSPHORODITHIOATE
  • R 1513
  • O,O-DIETHYL-S-[4-OXO-1,2,3-BENZO TRIAZIN-3-[4H]-YLMETHYL]PHOSPHORODITHIOATE
  • ,3-benzotriazin-4(3h)-one
  • 3,4-Dihydro-4-oxo-3-benzotriazinylmethyl O,O-diethyl phosphorodithioate
  • Benzotriazine derivative of an ethyl dithiophosphate
  • benzotriazinederivativeofanethyldithiophosphate
  • Bionex
  • Cotnion-ethyl-methyl
  • Crysthion
  • ENT 22,014
  • ent22,014
  • Ethyl azinphos
  • Ethyl Gusathion
  • Ethyl Guthion
  • ethylazinphos
  • ethylgusathion
  • Ethyl-gusathion
  • ethylguthion
  • Gusathion A
  • GUTHION ETHYL
  • COTNION-ETHYL
  • O,O-diethyl 3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl phosphorodithioate
  • AZINPHOS-ETHYL PESTANAL, 250 MG
  • GUTHION ETHYL, 100MG, NEAT
  • azinphos-ethyl (bsi, iso)
  • azinphosethyl (esa)
  • AZINPHOS-ETHYL STANDARD
  • Azinphos ethyl: (Ethyl guthion)
  • azinphos-ethyl (ISO) O,O-diethyl 4-oxobenzotriazin-3-ylmethyl phosphorodithioate
  • トリアゾチオン
  • グチオン-エチル
  • アジンホスエチル
  • ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル]
  • グサチオンA
  • エチルグチオン
  • アジンホス-エチル
  • アジンホスエチル標準品
  • アジンホスエチルTRIAZOTION
  • アジンホスエチル STANDARD
  • アジンホス-エチル標準品
  • アジノホスエチル
  • アジンホスエチル Standard, 100 µg/mL in MeOH
  • アジンホスエチル Standard, 1000 µg/mL in Hexane
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