ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル]

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 化学構造式
2642-71-9
CAS番号.
2642-71-9
化学名:
ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル]
别名:
トリアゾチオン;グチオン-エチル;アジンホスエチル;ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル];グサチオンA;エチルグチオン;アジンホス-エチル;アジンホスエチル標準品;アジンホスエチルTRIAZOTION;アジンホスエチル STANDARD;アジンホス-エチル標準品;アジノホスエチル;アジンホスエチル Standard, 100 µg/mL in MeOH;アジンホスエチル Standard, 1000 µg/mL in Hexane;アジンホス・エチル;ジチオりん酸O,O-ジエチルS-(4-オキソ-3,4-ジヒドロ-1,2,3-ベンゾトリアジン-3-イルメチル);O,O-ジエチル {[(4-オキソ-3,4-ジヒドロ-1,2,3-ベンゾトリアジン-3-イル)メチル]スルファニル}ホスホノチオアート
英語名:
AZINPHOS-ETHYL
英語别名:
Gutex;R 1513;Azinos;Bionex;B-16259;sepizinl;bay16255;bay16259;Sepizin L;BAY 16255
CBNumber:
CB3368633
化学式:
C12H16N3O3PS2
分子量:
345.38
MOL File:
2642-71-9.mol

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 物理性質

融点 :
45-47℃
沸点 :
111°C
比重(密度) :
1.43
蒸気圧:
3.2 x 10-4 Pa (20 °C)
貯蔵温度 :
0-6°C
水溶解度 :
4.5 mg l-1 (20 °C)
酸解離定数(Pka):
-2.59±0.20(Predicted)
外見 :
個体
BRN :
297468
CAS データベース:
2642-71-9(CAS DataBase Reference)
EPAの化学物質情報:
Azinphos-ethyl (2642-71-9)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T+,N
Rフレーズ  24-28-50/53
Sフレーズ  28-36/37-45-60-61
RIDADR  2783
WGK Germany  3
RTECS 番号 TD8400000
国連危険物分類  6.1(a)
容器等級  II
有毒物質データの 2642-71-9(Hazardous Substances Data)
絵表示(GHS) GHS hazard pictogramsGHS hazard pictograms
注意喚起語 危険
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H311 皮膚に接触すると有毒 急性毒性、経皮 3 危険 GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書き
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 化学特性,用途語,生産方法

外観

白色~わずかにうすい黄色、結晶性粉末~粉末

溶解性

エタノール及びアセトンに溶け、水にほとんど溶けない。

化学的特性

Azinphos-ethyl forms colorless, clear crystals. It is insoluble in water, but soluble in most organic solvents. As an acaricide, azinphos-ethyl is used for the control of pests, such as, spider mites, aphids, caterpillars, potato bug, beetles, bollweevils, whitefl ies, bollworms, thrips, and other biting and sucking insects. Human exposures to azinphos-ethyl occur through absorption from the gastrointestinal tract, through the intact skin, and by inhalation of fi ne spray mist and dusts.
Azinphos-ethyl is a non-systemic organophosphorus insecticide, which is used against a relatively broad spectrum of insects. These include lepidopterous larvae, beetles and their larvae, aphids, jassids, and spider mites on various crops. And also crops of cotton, rice, sugar and fodder beets, fruits such as apples, pears, citrus-fruit, grapes; tobacco. Many countries around the world have stopped the use of this pesticide.

使用

Azinphos-ethyl is used to control both chewing and sucking pests on a wide range of crops.

一般的な説明

Colorless crystals. Used as a non-systemic insecticide with good ovicidal properties and long persistence. Used on cotton, citrus, vegetables, potatoes, tobacco, rice, and cereals to control caterpillars, beetles, aphids, spiders and many other insects. Not registered for use in the U.S.

空気と水の反応

Nearly insoluble in water. What little amount is solubilized will readily hydrolyze.

反応プロフィール

The BPS Pesticide incident in Helena resulted in an explosion and death of three firemen. The burning of a 1,000 pound sack of Azinphos Methyl or the flashing of Maneb which was present on the facility may have caused the explosion. Azinphos Ethyl may behave similarly. At elevated temperatures, AZINPHOS-ETHYL will decompose generating toxic gases.

健康ハザード

The systemic effects of AZINPHOS-ETHYL are similar to parathion. It is an extremely potent systemic toxicant via ingestion, inhalation and skin contact. It may cause death or permanent injury after very short exposure to small quantities.

火災危険

(Non-Specific -- Organophosphorus Pesticide, n.o.s.) When heated to decomposition, AZINPHOS-ETHYL emits very toxic fumes of sulfur, phosphorus and nitrogen oxides. Container may explode in heat of fire.

安全性プロファイル

Poison by ingestion, inhalation, skin contact, and intraperitoneal route. A cholinesterase inhibitor type of insecticide. When heated to decomposition it emits toxic fumes of SOx, POx,, and NOx. See also PARATHION.

代謝経路

Although the metabolism of azinphos-ethyl has been studied much less than that of azinphos-methyl, the biotransformations which have been reported appear to be totally analogous.

予防処置

Azinphos-ethyl is an organophosphorus compound that inhibits cholinesterase enzymes. It is very toxic and occupational workers should be very careful during use, storage, and waste disposal of it.

ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル] 上流と下流の製品情報

原材料

準備製品

2642-71-9(ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル])キーワード:


  • 2642-71-9
  • S-(3,4-DIHYDRO-4-OXOBENZO[D]-[1,2,3]-TRIAZINE-3-YLMETHYL)O,O-DIETHYL PHOSPHORODITHIOATE
  • R 1513
  • O,O-DIETHYL-S-[4-OXO-1,2,3-BENZO TRIAZIN-3-[4H]-YLMETHYL]PHOSPHORODITHIOATE
  • ,3-benzotriazin-4(3h)-one
  • 3,4-Dihydro-4-oxo-3-benzotriazinylmethyl O,O-diethyl phosphorodithioate
  • Azinos
  • AZINPHOS-ETHYL
  • AZINUGEC E
  • BAYER 16259
  • GUSATHION A(R)
  • Phosphordithioicacid,O,O-diethyl-S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl]ester
  • Phosphorodithioic acid, O,O-diethyl ester, S-ester with 3-(mercaptomethyl)-1,2,3-benzotriazin-4(3H)-one
  • Phosphorodithioic acid, O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] ester
  • phosphorodithioicacid,o,o-diethylester,s-esterwith3-(mercaptomethyl)-1,2
  • phosphorodithioicacid,o,o-diethylester,s-esterwith3-(mercaptomethyl)-1,2,
  • phosphorodithioicacid,o,o-diethyls-((4-oxo-1,2,3-benzotriazin-3(4h)-yl)methy
  • phosphorodithioicacid,O,O-diethylS-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl]ester
  • S-(3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl) O,O-diethyl phosphorodithioate
  • s-(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl)o,o-diethylphosphorodith
  • s-(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl)o,o-diethylphosphorodithio
  • S-(3,4-Dihydro-4-oxobenzo [d]-[1,2,3]-triazin-3-ylmethyl) OO-diethyl phosphorodithioate
  • s-3,4-dihydro-4-oxobenzo(d)(1,2,3)triazin-3-ylmethyl)o,o-diethylphosphorodithi
  • Sepizin L
  • sepizinl
  • Triazotion
  • triazotion(russian)
  • 3,4-dihydro-4-oxo-3-benzotriazinylmethylo,o-diethylphosphorodithioate
  • 3-benzotriazin-4(3h)-one
  • 3-diethyloxyphosphinothioylthiomethyl-1,2,3-benzotriazin-4(3h)-one
  • Athyl-gusathion
  • トリアゾチオン
  • グチオン-エチル
  • アジンホスエチル
  • ジチオりん酸O,O-ジエチルS-[(4-オキソ-1,2,3-ベンゾトリアジン-3(4H)-イル)メチル]
  • グサチオンA
  • エチルグチオン
  • アジンホス-エチル
  • アジンホスエチル標準品
  • アジンホスエチルTRIAZOTION
  • アジンホスエチル STANDARD
  • アジンホス-エチル標準品
  • アジノホスエチル
  • アジンホスエチル Standard, 100 µg/mL in MeOH
  • アジンホスエチル Standard, 1000 µg/mL in Hexane
  • アジンホス・エチル
  • ジチオりん酸O,O-ジエチルS-(4-オキソ-3,4-ジヒドロ-1,2,3-ベンゾトリアジン-3-イルメチル)
  • O,O-ジエチル {[(4-オキソ-3,4-ジヒドロ-1,2,3-ベンゾトリアジン-3-イル)メチル]スルファニル}ホスホノチオアート
  • 農薬類,殺虫剤および除草剤など
  • 生活関係標準物質
  • 食料品
  • 有機標準物質
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