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ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル)

ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル) 化学構造式
2303-16-4
CAS番号.
2303-16-4
化学名:
ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル)
别名:
ジアレート;N,N-ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル);ジアラート;アバデックス;ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル);5,2,3-ジクロロアリルジイソプロピルチオカルバミン酸塩;ダイアレート標準品;5,2,3ジクロロアリルジイソプロピルチオカルバミン酸;ダイアレート;ジイソプロピルチオカルバミド酸S‐(2,3‐ジクロロアリル);ダイアレートジアレート;ジアレート STANDARD;ジアラート標準品;ジアレート (95-98%) STANDARD;ジアレート (95-98%) Standard, 1000 µg/mL in Acetonitrile;ジアレート Standard, 100 µg/mL in MeOH
英語化学名:
DIALLATE
英語别名:
DATC;Avadex;cp15336;Diallat;Pyradex;Avadex I;2,3-DCDT;CP 15336;cp15,336;Diallaat
CBNumber:
CB3751152
化学式:
C10H17Cl2NOS
分子量:
270.22
MOL File:
2303-16-4.mol

ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル) 物理性質

融点 :
25-30℃
沸点 :
bp9 150°
比重(密度) :
1.1556 (rough estimate)
屈折率 :
1.6000 (estimate)
闪点 :
>100 °C
貯蔵温度 :
0-6°C
外見 :
Viscous Liquid

安全性情報

主な危険性  Xn,N
Rフレーズ  22-40-50/53
Sフレーズ  25-36/37-60-61
RIDADR  2902
RTECS 番号 EZ8225000
国連危険物分類  6.1(b)
容器等級  III
HSコード  29302000
毒性 LD50 orally in rats: 395 mg/kg (Bailey, White)

ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル) 価格 もっと(6)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-057 ジアレート Standard
Diallate Standard, 100 ug/mL in MeOH
2303-16-4 1mL ¥15500 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSAS-E0623 ジアレート (95-98%) Standard
Diallate (95-98%) Standard, 1000 ug/mL in Acetonitrile
2303-16-4 1mL ¥15500 2018-12-26 購入
関東化学株式会社(KANTO) 49803-24 ダイアレート標準品
Diallate standard
2303-16-4 100mg ¥35000 2018-12-13 購入
林純薬工業株式会社 99052903 ダイアレートジアレート
Diallate
2303-16-4 50mg ¥20000 2018-12-15 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-142S ジアレート Standard
Diallate Standard, 100 ug/mL in MeOH
2303-16-4 1mL ¥15500 2018-12-26 購入

ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル) 化学特性,用途語,生産方法

用途

サトウダイコン,マメ科牧草,ダイズ,トウモロコシ等の除草剤。カラスムギ等のイネ科雑草に効く。カーバメート系除草剤。

農薬用途

除草剤

化学的特性

Diallate is a brown liquid.

使用

Herbicide.

使用

Preemergent, selective herbicide used to control wild oats and blackgrass in barley, corn, flax, lentils, peas, potatoes, soybeans and sugar beets.

一般的な説明

Used as an herbicide.

空気と水の反応

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

反応プロフィール

DIALLATE is a thiocarbamate ester. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

安全性プロファイル

Poison by ingestion. Moderately toxic by skin contact. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cl-, NOx, and SOx. See also CARBAMATES and ALLYL COMPOUNDS.

職業ばく露

A thiocarbamate herbicide. The slow release of poisonous gases from hydrolysis of many thio and dithiocarbamates requires the use of respirators during handling. Poisoning can also occur by ingestion and absorption through the skin. Diallate is potential danger to those involved in the manufacture, formulation and applica- tion of this re-emergence herbicide.

応急処置

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includ- ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi- cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

環境運命予測

Soil. Soil metabolites include 2,3-dichloroallyl alcohol, 2,3-dichloroallyl mercaptan (Hartley and Kidd, 1987) and carbon dioxide (Smith, 1988). The formation of the alcohol occurs via hydrolysis of the ester linkage and transthiolation of the allylic group (Kaufman, 1967). In an agricultural soil, 14CO2 was the only biodegradation identified; however, bound residue and traces of benzene and water-soluble radioactivity were also detected in large amounts (Anderson and Domsch, 1980). The reported half-lives in soil range from 2 to 4 weeks to (Smith and Fitzpatrick, 1970) to approximately 30 days (Hartley and Kidd, 1987). Diallate did not migrate deeper than 5 cm on test field plots (Smith, 1970). In four microbially-active agricultural soils, the half-life was 4 weeks but in sterilized soil the half-life was 20 weeks (Anderson and Domsch, 1976).
Plant. In plants, diallate is metabolized and carbon dioxide is released (Hartley and Kidd, 1987). Diallate undergoes cis/trans isomerization and oxidative cleavage when irradiated at 300 nm forming 2,3-dichloroacrolein and 2-chloroacrolein as products (Ruzo and Casida, 1985).
Photolytic. Irradiation of diallate was also conducted in oxygenated chloroform or water until a 10% conversion was obtained. Products formed included acetaldehyde, 2,3- dichloroacrolein and trace amounts of 2-chloroacrolein (Ruzo and Casida, 1985). Chemical/Physical. Emits toxic fumes of chlorine, nitrogen and sulfur oxides when heated to decomposition (Sax and Lewis, 1987). Though no products were reported, the calculated hydrolysis half-life at 25°C and pH 7 is 6.6 years (Ellington et al., 1988).

輸送方法

UN2992 Carbamate pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

不和合性

hiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitro- gen, hydrogen sulfide, ammonia, and methylamine. Many materials in this group slowly decompose in aqueous solu- tion to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.

廃棄物の処理

Land burial is acceptable for small quantities. Larger quantities can be incinerated . In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル) 上流と下流の製品情報

原材料

準備製品


ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル) 生産企業

Global( 33)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
BEST-REAGENT 400-1166-196 18981987031
028-84555506 QQ:800101999 cdhxsj@163.com China 9903 57
Spectrum Chemical Manufacturing Corp. 021-67601398,18616765336,QQ:3003443155
021-57711696 mkt@spectrumchina.net China 9692 60
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 ; 028-86676798 ; 028-86757656
028-86757656 aikeshiji@163.com China 9760 55
Alta Scientific Co., Ltd. (0086) 22-6537-8550; 185-2256-9193; 185-2256-9194
(0086) 22-2532-9655 contact@altascientific.com China 8318 55
Codow Chemical Co.,Ltd. +86-20-38056109
+86-20-62619665 sales@howeipharm.com China 18340 55
Shandong XiYa Chemical Industry Co., Ltd 4008-626-111
0539-6365991 3229735657@qq.com China 26793 60
Shenzhen Xinyaoxiong Industrial Co. Ltd. 0755-33204565 Sales QQ:2280077800(WeChat)
Advantage suppliers add cooperation QQ:577116998 szxys126@126.com China 54478 58

2303-16-4(ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル))キーワード:


  • 2303-16-4
  • S-2,3-DICHLOROALLYL DIISOPROPYL THIOCARBAMATE
  • S-[2,3-DICHLOROALLYL]-N,N'-DI-ISOPROPYL THIOCARBAMATE
  • 2,3-DCDT
  • 2,3-dichlorallyl-n,n-(diisopropyl)-thiocarbamat
  • 2,3-Dichlorallyl-N,N-(diisopropyl)-thiocarbamate
  • 2,3-dichloro-2-propene-1-thiodiisopropylcarbamate
  • 2,3-Dichloro-2-propene-1-thiol, diisopropylcarbamate
  • 2,3-dichloro-2-propene-1-thiol,diisopropylcarbamate
  • 2-Propene-1-thiol, 2,3-dichloro-, diisopropylcarbamate
  • Avadex
  • Avadex I
  • Avadex II
  • Bis(1-methylethyl) carbamothioic acid, S-(2,3-dichloro-2-propenyl)ester
  • bis(1-methylethyl)carbamothioicacid,s-(2,3-dichloro-2-propenyl)ester
  • Carbamic acid, diisopropylthio-, S-(2,3-dichloroallyl) ester
  • carbamicacid,diisopropylthio-,s-(2,3-dichloroallyl)ester
  • Carbamothioicacid,bis(1-methylethyl)-,S-(2,3-dichloro-2-propenyl)ester
  • CP 15,336
  • CP 15336
  • DIALLATE MIXTURE OF CIS AND TRANS ISOME&
  • DIALLATE, 100MG, NEAT
  • di-allate (bsi,e-iso)
  • diallate (f-iso,wssa)
  • Diallate (95-98%)
  • SEC-2,3-DICHLOROALLYLDIISOPROPYLTHIOCARBAMATE
  • Diallate(cisortrans)
  • di-allate (ISO) S-(2,3-dichloroallyl)-N,N-diisopropylthiocarbamate
  • Diallate Standard
  • Di-allate 100mg [2303-16-4]
  • S-(2,3-dichloroallyl) diisopropylcarbamothioate
  • ジアレート
  • N,N-ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル)
  • ジアラート
  • アバデックス
  • ジイソプロピルチオカルバミド酸S-(2,3-ジクロロアリル)
  • 5,2,3-ジクロロアリルジイソプロピルチオカルバミン酸塩
  • ダイアレート標準品
  • 5,2,3ジクロロアリルジイソプロピルチオカルバミン酸
  • ダイアレート
  • ジイソプロピルチオカルバミド酸S‐(2,3‐ジクロロアリル)
  • ダイアレートジアレート
  • ジアレート STANDARD
  • ジアラート標準品
  • ジアレート (95-98%) STANDARD
  • ジアレート (95-98%) Standard, 1000 µg/mL in Acetonitrile
  • ジアレート Standard, 100 µg/mL in MeOH
  • カーバメート系除草剤
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