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亜鉛オキシド

亜鉛オキシド 化学構造式
1314-13-2
CAS番号.
1314-13-2
化学名:
亜鉛オキシド
别名:
亜鉛華;酸化亜鉛;亜鉛オキシド;酸化;酸化亜鉛, NANOTEKR;酸化亜鉛,3N5;透明性亜鉛白;酸化亜鉛(粉末);酸化亜鉛 PURISS. P.A.,ACS REAGENT,≥99.0% (KT);酸化亜鉛 PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,99-100.5% (CALC. FOR DRIED SUBSTANCE);酸化亜鉛, -5ΜM, 99.9%;酸化亜鉛ナノ粒子(20NM);酸化亜鉛,0.02ΜM;酸化亜鉛, ACS;酸化亜鉛、分散液;酸化亜鉛 (99.999%-Zn) PURATREM;酸化亜鉛, 99.99% (metals basis);酸化亜鉛, sintered tablets (99.9%-Zn);酸化亜鉛, 99.7%;亜鉛華軟膏
英語化学名:
Zinc oxide
英語别名:
ZnO;emar;ozlo;xx78;Zinox;azo22;ozide;Rubox;xx203;xx601
CBNumber:
CB3853034
化学式:
OZn
分子量:
81.39
MOL File:
1314-13-2.mol

亜鉛オキシド 物理性質

融点 :
1975 °C
沸点 :
1949.9°C (estimate)
比重(密度) :
5.6
屈折率 :
2.008~2.029
闪点 :
27℃
貯蔵温度 :
Store at +5°C to +30°C.
溶解性:
0.0016g/l insoluble
外見 :
nanopowder
色:
White to pale yellow
比重:
5.61
PH:
7 (50g/l, H2O, 20℃)(slurry)
水溶解度 :
1.6 mg/L (29 ºC)
Merck :
14,10147
安定性::
Stable. Incompatible with magnesium, strong acids.
InChIKey:
XLOMVQKBTHCTTD-UHFFFAOYSA-N
CAS データベース:
1314-13-2(CAS DataBase Reference)
NISTの化学物質情報:
Zinc oxide(1314-13-2)
EPAの化学物質情報:
Zinc oxide (1314-13-2)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  N,Xn,F
Rフレーズ  50/53-20-43-36/38-20/21/22-67-66-10-11
Sフレーズ  60-61-7/9-36/37-26-16
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS 番号 ZH4810000
TSCA  Yes
国連危険物分類  9
容器等級  III
HSコード  28170000
有毒物質データの 1314-13-2(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: > 5000 mg/kg
化審法 一般化学物質
安衛法 57,57-2
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H225 引火性の高い液体および蒸気 引火性液体 2 危険 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H226 引火性の液体および蒸気 引火性液体 3 警告
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 P264, P280, P302+P352, P321,P332+P313, P362
H319 強い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 P264, P280, P305+P351+P338,P337+P313P
H336 眠気やめまいのおそれ 特定標的臓器毒性、単回暴露; 麻酔作用 3 警告 P261, P271, P304+P340, P312,P403+P233, P405, P501
H400 水生生物に強い毒性 水生環境有害性、急性毒性 1 警告 P273, P391, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P240 容器を接地すること/アースをとること。
P241 防爆型の電気機器/換気装置/照明機器/...機器を使 用すること。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P303+P361+P353 皮膚(または髪)に付着した場合:直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P337+P313 眼の刺激が続く場合:医師の診断/手当てを受けること。
P370+P378 火災の場合:消火に...を使用すること。
P391 漏出物を回収すること。
P501 内容物/容器を...に廃棄すること。

亜鉛オキシド 価格 もっと(66)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01W0126-0035 酸化亜鉛 99.0+% (ZnO) (mass/mass) (Titration)
Zinc Oxide 99.0+% (ZnO) (mass/mass) (Titration)
1314-13-2 500g ¥2550 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ALF087812
Zinc oxide, 99.99% (metals basis)
1314-13-2 50g ¥13600 2018-12-26 購入
関東化学株式会社(KANTO) 31579-2A 酸化亜鉛
Zinc oxide
1314-13-2 100g ¥36200 2018-12-13 購入
関東化学株式会社(KANTO) 31579-1A 酸化亜鉛
Zinc oxide
1314-13-2 25g ¥11300 2018-12-13 購入
Sigma-Aldrich Japan 14439 酸化亜鉛
Zinc oxide
puriss., meets analytical specification of Ph. Eur., BP, USP, 99-100.5% (calc. for dried substance)
1314-13-2 100g ¥6000 2018-12-25 購入

亜鉛オキシド MSDS


C.I. pigment white 4

亜鉛オキシド 化学特性,用途語,生産方法

外観

白色の粉末

定義

本品は、直鎖状のモノメチルポリシロキサンであり、次の化学式で表される。

溶解性

水, エタノールに不溶。酸, アルカリに可溶。水及びエタノール(99.5)にほとんど溶けない。希塩酸,希硫酸,希酢酸及び水酸化ナトリウム溶液に溶ける。

用途

原料(医薬、化粧品、塗料、顔料、触媒等)、亜鉛塩製造原料、メッキ材料。

用途

ゴム用補強剤、顔料

用途

一般分析用、原料(医薬、化粧品、蛍光体、ガスセンサー)。

用途

塗料?印刷インキ?化粧品原料、医薬、ゴム加硫促進剤、陶磁器?ガラス原料、洗剤等、合成樹脂、繊維用添加剤、その他無機化学製品、色素(塗料、顔料)、紙用添加剤、その他添加剤、その他電子材料等製品、触媒、メッキ剤

化粧品の成分用途

閉塞剤、表面改質剤、口腔ケア剤、皮膚保護剤、殺菌剤、増量剤、着色剤、紫外線吸収剤.散乱剤

効能

収斂薬, 皮膚保護薬

主な用途/役割

エポキシ樹脂系接着剤、ゴム系接着剤に使用される。

商品名

亜鉛華 (シオエ製薬); 亜鉛華 (マイラン製薬); 亜鉛華 (マイラン製薬); 亜鉛華 (吉田製薬); 亜鉛華 (小堺製薬); 亜鉛華 (日医工); 亜鉛華 (日本ジェネリック); 亜鉛華 (日興製薬); 亜鉛華 (日興製薬); 亜鉛華 (東洋製薬化成); 亜鉛華 (東洋製薬化成); 亜鉛華 (東豊薬品); 亜鉛華軟膏 (小堺製薬); 酸化亜鉛 (三恵薬品); 酸化亜鉛 (丸石製薬); 酸化亜鉛 (健栄製薬); 酸化亜鉛 (司生堂製薬); 酸化亜鉛 (吉田製薬); 酸化亜鉛 (小堺製薬); 酸化亜鉛 (小堺製薬); 酸化亜鉛 (山善製薬); 酸化亜鉛 (日医工); 酸化亜鉛 (日興製薬); 酸化亜鉛 (日興製薬)

使用上の注意

アルゴン封入

化学的特性

Zinc oxide is an amorphous, white or yellowish-white powder. Odorless.

化学的特性

Zinc oxide is yellowish and powder like.

物理的性質

White or yellowish-white powder; odorless; bitter taste; hexagonal crystal; refractive index 2.008; density 5.606 g/cm3; melts at 1,975°C; practically insoluble in water, 1.6 mg/L at about 30°C; soluble in dilute acids, ammonia solu 990 tion, and alkali hydroxides.

使用

Zinc oxide is added to paints as a pigment and mold inhibitor and is known as zinc white when it is used as an oil paint by artists. It is used for cosmetics (ointment to protect nose and lips from ultraviolet sunlight), as a seed treatment, and as a dietary supplement.

使用

Zinc oxide, ZnO, is a reactive white pigment prepared by vaporizing metallic zinc at a temperature of about 900°C in the presence of oxygen. As a pigment, ZnO is basic in nature and can react with certain types of acidic paint resins resulting in the formation of a brittle film on drying. Formation of such films leads to premature failure of paint. For this reason as well as because of its low RI,ZnO cannot compete for the hiding power of TiO2.
Consequently, ZnO is rarely used as the sole pigment in modern coatings, although it finds some use in admixture with other pigments. ZnO is used in exterior house paints as a fungicide and in some can linings as a sulfide scavenger.

使用

Antibiotic

使用

Preparation of zinc standard solutions.

使用

zinc oxide has been used to protect, soothe, and heal the skin. Zinc oxide provides an excellent barrier to the sun and other irritants. It is somewhat astringent, anti-septic, and anti-bacterial. When used in sunscreen preparations, it provides both uVA and uVB protection, and can contribute to and/or increase SPF. At the appropriate particle size, zinc oxide is transparent in the visible light spectrum but opaque in the uVC ranges, thereby avoiding a whitening effect when incorporated into sunscreen preparations. Zinc oxide is included on the FDA’s list of approved sunscreen chemicals. It demonstrates an impressive synergistic effect when combined with organic sunscreens. Zinc oxide is also used when a white color is desired for a product. It is obtained from zinc ore, a commonly found mineral, and is relatively non-allergenic.

製造方法

Zinc oxide is obtained as an intermediate in recovering zinc from minerals (See Zinc, Recovery). The oxide is prepared by vaporizing zinc metal and oxidation of the zinc vapors with preheated air (French process). The oxide can be produced by other processes. Another method involves roasting franklinite and other ores with coal and then oxidizing the product in air.

定義

zinc oxide: A powder, white whencold and yellow when hot, ZnO; r.d.5.606; m.p. 1975°C. It occurs naturallyas a reddish orange ore zincite,and can also be made by oxidizinghot zinc in air. It is amphoteric,forming zincates with bases. It isused as a pigment (Chinese white) and a mild antiseptic in zinc ointments.An archaic name is philosopher’swool.

定義

Zincite is a mineral form of zincoxide, ZnO.

一般的な説明

Crude zinc oxide is a yellow-gray granular solid with no odor. Zinc oxide has a specific gravity of 4.4. Zinc oxide is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Prolonged inhalation of the dust may result in metal fume fever with symptoms of chills, fever, muscular pain, nausea and vomiting.

空気と水の反応

Slowly decomposed(hydrolyzed) in water. Insoluble in water.

反応プロフィール

ZINC OXIDE is insoluble in water. What little solubility Zinc oxide has yields aqueous solutions that are neutral in pH. Intimate mixtures of zinc oxide and chlorinated rubber with or without hydrocarbons or chlorinated solvent react violently, even explosively upon heating [Chem. Trade J., 1962, 151, 672]. Slow addition of zinc oxide to cover the surface of linseed oil varnish caused generation of heat and ignition, [Chem. Trade J., 1933, 92, 278].

危険性

Exposure to zinc oxide fumes from welding and other operations can cause metal fume fever. Its symptoms are chills, fever, cough, and tightness in the chest.

健康ハザード

Exposures to zinc oxide metal fume cause several health disorders. The symptoms of toxicity include, but are not limited to, fever, chills, muscle ache, nausea, fever, dry throat, cough; lassitude (weakness, exhaustion), metallic taste, headache, blurred vision, low back pain, vomiting, malaise (vague feeling of discomfort), chest tightness, dyspnea (breathing diffi culty) and decreased pulmonary function. The overexposure to zinc oxide fumes in workplaces produce symptoms known as metal fume fever or “zinc shakes”; an acute, selflimiting condition. Chronic exposure to zinc oxide may cause respiratory tract irritation with nasopharyngitis and laryngitis.

火災危険

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.

农业用途

Zinc oxide (ZnO) is a zinc fertilizer. It is a white powder when cold and yellow when hot, and contains approximately 78% zinc.
Zinc oxide occurs in nature as a reddish-orange colored zincite, and is made by oxidizing hot zinc in air. It is an amphoteric oxide forming zincates, by reacting with bases and zinc salts with acids. It is used as a white pigment and as a mild antiseptic in ointments. An archaic name of zinc oxide is philosopher's wool.
Foliar applications with zinc oxide reduce the foliage damage. Zinc oxide, applied by way of seed coatings, root dips or tree injections, corrects the zinc deficiency. Dipping potato seeds in 2% zinc oxide suspension overcomes zinc deficiency satisfactorily. A similar method is used for pre-plant dipping of the roots of rice seedlings.

応用例(製薬)

The pharmaceutical and cosmetic industries use ZnO in powders and ointments because of its bactericidal properties. It is also used to form dental cements by its reaction with eugenol.
Zinc oxide is used as a raw material for many products: stearates, phosphates, chromates, bromates, organic dithiophosphates, and ferrites (ZnO, MnO, Fe2O3). It is used as a source of zinc in animal feeds and in electrogalvanization . It is also used for desulfurizing gases.

工業用途

Zinc oxide has many uses. By far the most important is in the rubber industry. Almost half the world’s ZnO is used as an activator for vulcanization accelerators in natural and synthetic rubber. The reactivity of the ZnO is a function of its specific surface area, but is also influenced by the presence of impurities such as lead and sulfates. The ZnO also ensures good durability of the vulcanized rubber, and increases its thermal conductivity. The ZnO content is usually 2–5%.
In paints and coatings, zinc oxide is no longer the principal white pigment, although its superb white color is used by artists. It is used as an additive in exterior paints for wood preservation. It is also utilized in antifouling and anticorrosion paints [2.82]. It improves film formation, durability, and resistance to mildew (having a synergistic effect with other fungicides) because it reacts with acidic products of oxidation and can absorb UV radiation.
In the field of glass, ceramics, and enamels, ZnO is used for its ability to reduce thermal expansion, to lower the melting point, and to increase chemical resistance. It can also be used to modify gloss or to improve opacity.

材料の用途

The highest purity material is calcined with additives such as Bi2O3 and used in the manufacture of varistors. The photoconducting properties of ZnO are used in photoreproduction processes. Doping with alumina causes a reduction in electrical resistance; hence, it can be used in the coatings on the master papers for offset reproduction.
Zinc oxide is used as a catalyst in organic syntheses (e.g., of methanol), often in conjunction with other oxides. It is present in some adhesive compositions.

安全性プロファイル

Moderately toxic to humans by ingestion. Poison experimentally by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by inhalation of freshly formed fumes: metal fume fever with chills, fever, tightness of chest, cough, dyspnea, and other pulmonary changes. Mutation data reported. A s h and eye irritant. Has exploded when mixed with chlorinated rubber. Violent reaction with Mg, linseed oil. When heated to decomposition it emits toxic fumes of ZnO. See also ZINC COMPOUNDS.

職業ばく露

Zinc oxide is primarily used as a white pigment in rubber formulations and as a vulcanizing aid. It is also used as an antiinflammatory agent; in photo copying; paints, chemicals, ceramics, lacquers, and varnishes; as a filler for plastic; in cosmetics; pharmaceuticals, and calamine lotion. Exposure may occur in the manufacture and use of zinc oxide and products, or through its formation as a fume when zinc or its alloys are heated. HC may have been used as a Choking/Pulmonary Agent.

輸送方法

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

不和合性

Incompatible with linseed oil, magnesium. Contact with chlorinated rubber (@ 215C) may cause a violent reaction. Slowly decomposed by water.

亜鉛オキシド 上流と下流の製品情報

原材料

準備製品


亜鉛オキシド 生産企業

Global( 519)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
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1314-13-2(亜鉛オキシド)キーワード:


  • 1314-13-2
  • ZINC OXIDE, 99.9%ZINC OXIDE, 99.9%ZINC OXIDE, 99.9%ZINC OXIDE, 99.9%
  • ZINC OXIDE, 99.999%ZINC OXIDE, 99.999%ZINC OXIDE, 99.999%ZINC OXIDE, 99.999%
  • ZINC OXIDE, REAGENT (ACS)ZINC OXIDE, REAGENT (ACS)ZINC OXIDE, REAGENT (ACS)ZINC OXIDE, REAGENT (ACS)
  • ZINC OXIDE PWD
  • c.i. pigment white 4
  • ZINKOXYD AKTIV
  • Zinc white
  • ZINC OXIDE
  • ZINCI OXIDUM
  • Activox
  • Activox B
  • actox14
  • zincmonoxide
  • zincoid
  • zincoxide(zno)
  • Zincoxide,activated
  • zincoxide,crude(environmentallyhazardoussubstances,solid,n.o.s.)
  • zincoxidefume
  • zincumoxydatum
  • Zink white
  • Zinkoxyd activ
  • Zinox
  • Zinc oxide,edible
  • Zincoxideheavy
  • 93% ZINC OXID
  • ZINC OXIDE (99.7%)
  • ZINC OXIDE 99.7% MIN
  • activated zinc flower
  • activated zinc oxide
  • ZINC OXIDE, 99+%, A.C.S. REAGENT
  • 亜鉛華
  • 酸化亜鉛
  • 亜鉛オキシド
  • 酸化
  • 酸化亜鉛, NANOTEKR
  • 酸化亜鉛,3N5
  • 透明性亜鉛白
  • 酸化亜鉛(粉末)
  • 酸化亜鉛 PURISS. P.A.,ACS REAGENT,≥99.0% (KT)
  • 酸化亜鉛 PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,99-100.5% (CALC. FOR DRIED SUBSTANCE)
  • 酸化亜鉛, -5ΜM, 99.9%
  • 酸化亜鉛ナノ粒子(20NM)
  • 酸化亜鉛,0.02ΜM
  • 酸化亜鉛, ACS
  • 酸化亜鉛、分散液
  • 酸化亜鉛 (99.999%-Zn) PURATREM
  • 酸化亜鉛, 99.99% (metals basis)
  • 酸化亜鉛, sintered tablets (99.9%-Zn)
  • 酸化亜鉛, 99.7%
  • 亜鉛華軟膏
  • 酸化亜鉛 (JP17)
  • 亜鉛華軟膏 (JP17)
  • メチコン
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