ChemicalBook
Chinese english Germany Korea

ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル)

ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル) 化学構造式
298-04-4
CAS番号.
298-04-4
化学名:
ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル)
别名:
ジチオりん酸O,O-ジエチルS-[2-(エチルチオ)エチル];ダイシストン;バイエル19639;エチルチオメトン;ジチオりん酸O,O-ジエチル-S-(2-エチルチオエチル);ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル);フルミン;ジスルホトン;チオデメトン;ジチオシストックス;ジチオ-シストックス;エカチンTD;ソルビレックス;ジシストン;ジスルホトン標準品;チオジメトン;O,O-ジエチル-S-2-(エチルチオ)エチルホスホロジチオアート;ジエチル-S-(エチルチオエチル)-ジチオホスフェイト;ジチオりん酸O,O-ジエチル-S-(2-エチルチオエチル) (エチルチオメトン);ジチオりん酸O,O-ジエチル-S-(2-エチルチオエチル) (別名 エチルチオメトン又はジスルホトン)
英語化学名:
DISULFOTON
英語别名:
M-74;S276;Dimaz;Dution;Frumin;ekatine;fruming;NA 2783;B-19639;vuagt1-4
CBNumber:
CB4208774
化学式:
C8H19O2PS3
分子量:
274.4
MOL File:
298-04-4.mol

ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル) 物理性質

融点 :
110-112℃
沸点 :
bp0.01 108°; bp1.5 132-133°
比重(密度) :
1.1445 g/cm3 (20 ºC)
蒸気圧:
7.2 x 10-3 Pa (20 °C)
屈折率 :
1.5501 (589.3 nm 20℃)
闪点 :
133 °C
貯蔵温度 :
0-6°C
外見 :
liquid
水溶解度 :
25 mg l-1 (20 °C)
Merck :
13,3400
BRN :
1709167
CAS データベース:
298-04-4(CAS DataBase Reference)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T+,N
Rフレーズ  27/28-50/53
Sフレーズ  28-36/37-45-60-61
RIDADR  3018
WGK Germany  3
RTECS 番号 TD9275000
国連危険物分類  6.1(a)
容器等級  I
毒性 LD50 in female, male rats (mg/kg): 2.3, 6.8 orally; 6, 15 dermally (Gaines)
消防法 危-4-3-III
安衛法 57,57-2
PRTR法 第1種指定化学物質
毒劇物取締法 I
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 P264, P270, P301+P310, P321, P330,P405, P501
H310 皮膚に接触すると生命に危険 急性毒性、経皮 1, 2 危険 P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P264 取扱い後は皮膚をよく洗うこと。
P264 取扱い後は手や顔をよく洗うこと。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。
P302+P350 皮膚に付着した場合:多量の水と石鹸で優しく洗うこと。
P310 ただちに医師に連絡すること。

ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル) 価格 もっと(11)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-098 ジスルホトン Standard
Disulfoton Standard, 100 ug/mL in MeOH
298-04-4 1mL ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSAS-E0654 ジスルホトン Standard
Disulfoton Standard, 1000 ug/mL in Acetonitrile
298-04-4 1mL ¥11800 2018-12-26 購入
関東化学株式会社(KANTO) 49826-12 ジスルホトン標準品
Disulfoton standard
298-04-4 250mg ¥14000 2018-12-13 購入
Sigma-Aldrich Japan 45460 ジスルホトン PESTANAL?, analytical standard
Disulfoton PESTANAL?, analytical standard
298-04-4 250mg ¥16500 2018-12-25 購入
林純薬工業株式会社 99057318 CS_N-11819-250MG_ジスルホトンエチルチオメトン
CS_N-11819-250MG_Disulfoton Ethylthiometon
298-04-4 250mg ¥9700 2018-12-15 購入

ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル) 化学特性,用途語,生産方法

用途

農薬(殺虫剤)

農薬用途

殺虫剤

化学的特性

Disulfoton is a dark yellowish oil with an aromatic, sulfurous odor. It is soluble in most organic solvents and fatty oils. Disulfoton is a selective, systemic insecticide and acaricide. It is used for seed coating and for soil application to protect from insect attacks, for the control of sucking insects, aphids, leaf hoppers, thrips, beet-fl ies, spider mites, and coffeeleaf miners. Disulfoton has been used extensively in pest control on a variety of crops, such as cotton, tobacco, sugar beets, corn, peanuts, wheat, ornamentals, cereal grains, and potatoes. It is grouped by the US EPA under RUP. Human exposures to disulfoton occur through breathing contaminated air, drinking contaminated water, eating contaminated food, and working in industries that manufacture and formulate the pesticide.

使用

Systemic insecticide and acaricide for control of sucking insects and mites in fruits, vegetables, cotton and forestry nurseries.

使用

Disulfoton is used to control sucking insects and mites in a wide range of crops.

使用

Insecticide.

定義

ChEBI: An organic thiophosphate that is the diethyl ester of S-[2-(ethylsulfanyl)ethyl] dihydrogen phosphorodithioate.

一般的な説明

Disulphoton is a dark yellowish oil with an aromatic, sulphurous odour. It is soluble in most organic solvents and fatty oils. Disulphoton is a selective, systemic insecticide and acaricide. It is used for seed coating and for soil application to protect from insect attacks and for the control of sucking insects, aphids, leafhoppers, thrips, beetflies, spider mites, and coffee-leaf miners. Disulphoton has been extensively used in pest control on a variety of crops such as cotton, tobacco, sugar beets, corn, peanuts, wheat, ornamentals, cereal grains, and potatoes. It is grouped by the U.S. EPA under RUP. Human exposures to disulphoton occur through breathing contaminated air, drinking contaminated water, eating contaminated food, and working in industries that manufacture and formulate the pesticide.

反応プロフィール

Organothiophosphates, such as DISULFOTON, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

健康ハザード

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

健康ハザード

Disulfoton is highly toxic to animals and humans by all routes of exposures, namely, by dermal absorption, through ingestion, and inhalation by the respiratory route. The symptoms of poisoning include blurred vision, fatigue, headache, dizziness, sweating, tearing, and salivation. It inhibits cholinesterase and affects the nervous system function. It does not cause delayed neurotoxicity. Prolonged period of exposures to high concentrations of disulfoton cause harmful effects to the nervous system with symptoms such as narrowing of the pupils, vomiting, diarrhea, drooling, diffi culty in breathing, lung edema, tremors, convulsions, coma, and death. Disulfoton causes no mutagenic or teratogenic effects in laboratory animals. There are no reports indicating that disulfoton causes cancer in animals or humans. The DHHS, the IARC, and the US EPA have not classifi ed disulfoton as to its ability to cause cancer.

火災危険

Combustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

农业用途

Insecticide, Acaricide: All products formulated at greater than 2% disulfoton are classified as Restricted Use Pesticides (RUP). Disulfoton is a selective, systemic organophosphate insecticide and acaricide that is especially effective against sucking insects. It is used to control aphids, leafhoppers, thrips, beet flies, spider mites, and coffee leaf miners. Not approved for use in EU countries. There are 21 global suppliers.

製品名

BAY 19639®; BAYER 19639®; DIMAZ®; DISULFATON®; DI-SYSTON®[C]; DISYSTON®[C]; DISYSTOX®; DITHIODEMETON®; DITHIOSYSTOX®; EKATIN TD®; FRUMIN-AL®; FRUMIN G®; GLEBOFOS®; M-74®; S 276®; SOLVIREX®; THIODEMETON®; THIODEMETRON®

安全性プロファイル

Poison by ingestion, inhalation, skin contact, intraperitoneal, and intravenous routes. Human mutation data reported. When heated to decomposition it emits veq toxic SOx and POx. See also various demeton entries and ESTERS.

環境運命予測

Soil/Plant. Disulfoton was metabolized in soil and plants to the corresponding sulfoxide and sulfone via oxidation of the thioether sulfur atoms (Metcalf et al., 1957; Getzin and Shanks, 1970; Takase et al., 1972; Clapp et al., 1976; Worthing and Hance, 1991), the corresponding phosphorothioate analogs and then to derivatives of O,O-diethyl hydrogen phosphate and 2-ethylthioethyl mercaptan (Worthing and Hance, 1991). Disulfoton is rapidly oxidized in soil to its sulfoxide and sulfone with disulfoton oxon sulfoxide and disulfoton oxon sulfone appearing in small amounts (Szeto et al., 1983). In a Portneuf silt loam soil, the persistence of the sulfoxide and sulfone was 32 and >64 days, respectively (Clapp et al., 1976).
Disulfoton was translocated from a sandy loam soil into asparagus tips. Disulfoton sulfoxide, disulfoton sulfone, disulfoton oxon sulfoxide and disulfoton oxon sulfone were recovered as metabolites (Szeto and Brown, 1982; Szeto et al., 1983). Disulfoton s
Groundwater. According to the U.S. EPA (1986) disulfoton has a high potential to leach to groundwater.
Photolytic. Disulfoton was rapidly oxidized to disulfoton sulfoxide and trace amounts (<5% yield) of disulfoton sulfone when sorbed on soil and exposed to sunlight (half-life 1–4 days) (Gohre and Miller, 1986). The photosensitized oxidation was probably due to the presence of singlet oxygen (Gohre and Miller, 1986; Zepp et al., 1981). The degradation rate was higher in soils containing the lowest organic carbon (Gohre and Miller, 1986). Chemical/Physical. Emits toxic fumes of phosphorus and sulfur oxides when heated to decomposition (Sax and Lewis, 1987; Lewis, 1990).
When fertilizers containing superphosphate and ammonium nitrate were impregnated with disulfoton, the latter chemically degraded to form disulfoton sulfone and disulfoton sulfoxide (Ibrahim et al., 1969).
The reported half-lives for abiotic hydrolysis

代謝経路

Disulfoton is metabolised by an analogous route to phorate. The principal route of disulfoton metabolism in all media is activation via oxidation of the thioether group to the sulfoxide (rapid) and sulfone (slower). Thioether oxidation occurs preferentially to oxidative desulfuration of the P=S group to the oxon, which is usually only present in trace amounts and there is good evidence that the sulfoxide and sulfone oxons arise via disulfoton sulfoxide and sulfone rather than disulfoton oxon. The more polar thiooxidised metabolites are translocated in plants and are responsible for the compound's systemic action.

Degradation

Disulfoton is stable at acidic and neutral pH values but it is hydrolysed in alkaline media.

ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル) 上流と下流の製品情報

原材料

準備製品


ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル) 生産企業

Global( 0)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度

298-04-4(ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル))キーワード:


  • 298-04-4
  • vuagt1-4
  • vuagt1964
  • DISULFOTON, 1GM, NEAT
  • DISULFOTON PESTANAL (O,O-DIETHYL S-(2-(E
  • DISULFOTON, 100MG, NEAT
  • disulfoton (bsi,iso,esa)
  • ethylthiodemeton (jmaf)
  • DISULPHOTON
  • Disulfoton (ISO)
  • disulfoton (ISO) O,O-diethyl 2-ethylthioethyl phosphorodithioate
  • Dution
  • Ekatin TD
  • ekatine
  • ekatintd
  • ENT 23,437
  • ent23,437
  • ent23347
  • ENT-23437
  • Ethyl thiometon
  • Ethylthiodemeton
  • ethylthiometon
  • Ethylthiometon B
  • ethylthiometonb
  • Frumin
  • Frumin AL
  • o,o-diethyls-(2-(ethylthio)ethyl))dithiophosphate
  • o,o-diethyls-(2-eththioethyl)phosphorodithioate
  • o,o-diethyls-(2-eththioethyl)thiothionophosphate
  • o,o-diethyls-(2-ethylmercaptoethyl)dithiophosphate
  • O,O-Diethyl-S-(2-ethylthio-ethyl)-dithiofosfaat
  • ジチオりん酸O,O-ジエチルS-[2-(エチルチオ)エチル]
  • ダイシストン
  • バイエル19639
  • エチルチオメトン
  • ジチオりん酸O,O-ジエチル-S-(2-エチルチオエチル)
  • ジチオりん酸O,O-ジエチルS-(2-エチルチオエチル)
  • フルミン
  • ジスルホトン
  • チオデメトン
  • ジチオシストックス
  • ジチオ-シストックス
  • エカチンTD
  • ソルビレックス
  • ジシストン
  • ジスルホトン標準品
  • チオジメトン
  • O,O-ジエチル-S-2-(エチルチオ)エチルホスホロジチオアート
  • ジエチル-S-(エチルチオエチル)-ジチオホスフェイト
  • ジチオりん酸O,O-ジエチル-S-(2-エチルチオエチル) (エチルチオメトン)
  • ジチオりん酸O,O-ジエチル-S-(2-エチルチオエチル) (別名 エチルチオメトン又はジスルホトン)
  • ジチオリン酸O,O-ジエチル-S-(2-エチルチオエチル)(別名:ジスルホトン)
  • CS_N-11819-250MG_ジスルホトンエチルチオメトン
  • ジスルホトンエチルチオメトン
  • ジスルホトン (100ΜG/MLメタノール溶液)
  • エチルチオメトン標準物質
  • ジスルホトン STANDARD
  • ジスルホトン Standard, 100 µg/mL in MeOH
  • ジスルホトン Standard, 1000 µg/mL in Acetonitrile
  • ジスルホトン Standard, 1000 µg/mL in MeOH
  • ジスルホトン, 1000 µg/mL in Hexane
  • 有機リン系殺虫剤
Copyright 2017 © ChemicalBook. All rights reserved